A kind of phase change microcapsule heat insulation emulsion, its coating and its preparation method
A technology of phase change microcapsules, thermal insulation, applied in its coating and its preparation, phase change microcapsule thermal insulation emulsion field, to achieve the effect of improving thermal insulation effect and good thermal insulation effect
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[0045] The preparation method of the phase change microcapsule type thermal insulation emulsion of the present invention comprises the following steps:
[0046] (1) Preparation of seed emulsion
[0047]A1. Pre-emulsification: At normal temperature and pressure, mix 0.05-2 parts of cellulose, 0.05-2 parts of polyvinyl alcohol and 5-20 parts of water in an emulsification tank, fully stir and dissolve at a dispersion speed of 500RPM, and add 1 -10 parts of liquid paraffin are dispersed at 2500-3000RPM for 20min, then add 0.5-10 parts of alkyl methacrylate, 0.5-5 parts of carboxyl-containing vinyl monomer, 0.05-5 parts of cross-linking monomer and 0.05-1 part Initiator, dispersed at 3500RPM for 10min to make pre-emulsion;
[0048] B1. Polymerization: add 10-20 parts of water into the reactor, raise the temperature to 85-90°C, stir for 10-30min, then add the pre-emulsion obtained in step A1, the reaction temperature is 85-95°C, and the reaction time is 15-60min;
[0049] (2) Prep...
Embodiment 1
[0057] The phase-change microcapsule type thermal insulation emulsion of the present invention comprises cellulose, polyvinyl alcohol, liquid paraffin, alkyl methacrylate, carboxyl-containing vinyl monomer, cross-linking monomer, initiator, oxidizing agent, reducing agent, water, the contents of the above components are calculated in parts by mass: 0.1 part of cellulose, 0.1 part of polyvinyl alcohol, 20 parts of liquid paraffin, 1 part of alkyl methacrylate, and 1 part of carboxyl-containing vinyl monomer , 0.1 part of crosslinking monomer, 0.1 part of initiator, 0.1 part of oxidizing agent, 0.1 part of reducing agent, 40 parts of water.
[0058] The cellulose is selected from hydroxymethylcellulose.
[0059] The polyvinyl alcohol is selected from BP17.
[0060] The liquid paraffin is selected from C15 normal alkanes.
[0061] The alkyl methacrylate is selected from methyl methacrylate.
[0062] The carboxyl-containing vinyl monomer is selected from acrylic acid.
[0063]...
Embodiment 2
[0077] The phase-change microcapsule type thermal insulation emulsion of the present invention comprises cellulose, polyvinyl alcohol, liquid paraffin, alkyl methacrylate, carboxyl-containing vinyl monomer, cross-linking monomer, initiator, oxidizing agent, reducing agent, water, the contents of the above components are calculated in parts by mass: 0.5 parts of cellulose, 1 part of polyvinyl alcohol, 25 parts of liquid paraffin, 5 parts of alkyl methacrylate, and 2 parts of carboxyl-containing vinyl monomers , 1 part of cross-linking monomer, 0.5 part of initiator, 0.2 part of oxidizing agent, 0.2 part of reducing agent, 45 parts of water.
[0078] The cellulose is selected from hydroxymethylcellulose.
[0079] The polyvinyl alcohol is selected from BP05.
[0080] The liquid paraffin is selected from C16 normal alkanes.
[0081] The alkyl methacrylate is selected from ethyl methacrylate.
[0082] The carboxyl-containing vinyl monomer is selected from methacrylic acid.
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