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Preparation method of fuel cell anode catalyst

A fuel cell and catalyst technology, applied in battery electrodes, circuits, electrical components, etc., can solve problems such as increased process complexity and material costs, decreased carrier interface adsorption stability, and decreased battery life, achieving good synergistic effects and improving Electrocatalytic performance and the effect of improving the utilization rate

Inactive Publication Date: 2017-12-22
HENAN NORMAL UNIV
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Problems solved by technology

[0004] When carbon materials are used as supports, it is often necessary to introduce a modifier on the surface of the support to exert an anchoring effect on the active components of the catalyst, thereby improving the dispersion of the active components of the catalyst on the surface of the support. It is easy to attenuate in the medium, which makes the adsorption stability of the carrier interface decrease, resulting in a decrease in battery life
And this method of introducing modifiers will also increase process complexity and material costs

Method used

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  • Preparation method of fuel cell anode catalyst
  • Preparation method of fuel cell anode catalyst
  • Preparation method of fuel cell anode catalyst

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Embodiment 1

[0021] 0.01g of melamine and 0.01g of pyrophosphoric acid and 40mL of deionized water were dispersed and mixed uniformly by ultrasonic to form a solution, then 0.1g of ferric chloride was added and stirred and mixed uniformly to obtain a suspension; the obtained suspension was transferred to a high-pressure reactor sealed in a medium, reacted at 150°C for 6h, and cooled naturally to room temperature after the reaction; washed the obtained product with deionized water until the filtrate became colorless, put it in a vacuum drying oven at 80°C and dried to constant weight, and then 2 Calcined at 800°C for 4 hours under the atmosphere to obtain phosphorus, nitrogen, and iron co-doped carbon material; disperse 40 mg of the obtained phosphorus, nitrogen, and iron co-doped carbon material in 20 mL of ethylene glycol, and ultrasonically stir for 2 hours to obtain a dispersion; Add 2.5mL 20mM PdCl to the dispersion 2 aqueous solution and 20 mg CuSO 4 ·5H 2 O, stir until mixed evenly...

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Abstract

The invention discloses a preparation method of a fuel cell anode catalyst and belongs to the technical field of preparation of fuel cell nano-composite catalysts. The method specifically comprises steps of preparation of a phosphorus, nitrogen and iron co-doped carbon material carrier, loading of a palladium-copper alloy active component on the carrier and the like, and the carrier and the alloy active component have a good synergistic effect. The phosphorus, nitrogen and iron co-doped carbon material plays important roles in improving the activity of the catalyst as a novel fuel cell catalyst carrier, on one hand, copper plays a role in assisting catalysis as transition metal, the activity of the noble metal catalyst is improved, on the other hand, the dosage of noble metal is reduced, and the cost of the fuel cell catalyst is reduced, so that the catalyst has broad application prospects.

Description

technical field [0001] The invention belongs to the technical field of fuel cell catalyst preparation, and in particular relates to a preparation method of a fuel cell anode catalyst. Background technique [0002] Fuel cells have the advantages of high operating efficiency and low emissions, and are recognized as clean energy conversion systems. However, the high cost of fuel cells restricts its commercialization process, which is one of the most important key issues in this field. Catalyst is an important part of fuel cell, and its cost accounts for about 50% of the whole fuel cell. The most commonly used catalysts are noble metal catalysts, but the reserves of noble metals are limited and expensive. At the same time, the kinetics of noble metal catalysts in the anodic oxidation reaction are slow and the stability is poor. Therefore, improving performance and reducing cost are urgent problems to be solved for fuel cell catalysts. [0003] According to the surface effect ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/88H01M4/92
CPCH01M4/88H01M4/921H01M4/925H01M4/926Y02E60/50
Inventor 张庆房立白正宇赖小伟杨林黄茹梦李珊珊衡金梦
Owner HENAN NORMAL UNIV
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