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Anticorrosion and anti-rust waterborne acrylic coating and preparation method thereof

A water-based acrylic, anti-corrosion and anti-rust technology, applied in anti-corrosion coatings and other directions, can solve the problems of waste of resources and energy, poor storage stability, poor salt spray resistance, etc., and achieve the effect of fast curing speed, low cost and good hydrophobicity

Inactive Publication Date: 2018-01-12
LINFEN TIE HUAN PAINT IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the anti-rust and anti-corrosion coatings used in China are solvent-based coatings. The biggest disadvantage of these coatings is that they pollute the environment, are flammable and explosive, harmful to the human body, and waste a lot of resources and energy.
At present, the VOC content of solvent-based coating products in the market is as high as 50% to 60%, and the annual emission of VOC is nearly 200,000 tons, which not only pollutes the environment but also wastes energy. Therefore, the development of water-based anti-corrosion coatings will be a priority for the domestic and foreign coatings industry focus
[0003] The base materials of water-based anti-corrosion coatings widely used in the market are: water-based acrylic, water-based alkyd resin, water-based epoxy coatings, etc. Among them, water-based acrylic coatings are suitable for film-forming of various water-based coatings because of their excellent weather resistance and convenient construction. The most cost-effective polymer among substances, but there are three major problems in ordinary water-based acrylic paints: ①Poor salt spray resistance, generally no more than 120h; Contact, flash rust ③ Poor storage stability, poor anti-corrosion performance, how to solve these three problems will be the key to the promotion of water-based acrylic coatings in the chemical industry

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] An anti-corrosion and anti-rust water-based acrylic paint, the acrylic resin is prepared from the following raw materials according to the following weight percentages: 50g of acrylic acid, 62g of n-butyl acrylate, 1%~10% of methyl methacrylate, 5%~ of hydroxyethyl acrylate 20%, 2-ethylhexyl acrylate 60g, isobornyl methacrylate 100g, Veova10 90g, alicyclic acrylate 100g, chain extender 10g, initiator 18g, triethylamine 10g, water 500g.

[0024] In the present invention, the initiator is one or more mixtures of benzoyl peroxide, tert-butyl peroxybenzoate and di-tert-amyl peroxide; the chain extender is trimethylol One or both of propane and dodecanethiol.

[0025] The preparation process of a kind of anticorrosion antirust waterborne acrylic paint among the present invention is as follows:

[0026] ①Mix methyl methacrylate, hydroxyethyl acrylate, 2-ethylhexyl acrylate, isobornyl methacrylate, vinyl tert-carbonate Veova10, cycloaliphatic acrylate, 14g initiator, 5g chain...

Embodiment 2

[0031] A kind of anticorrosion antirust water-based acrylic paint, its acrylic resin is formulated by the following weight percentages by following raw material: Acrylic acid 45g, n-butyl acrylate 70g, acrylate-2-ethylhexyl 50g, isobornyl methacrylate 90g, Veova10 107g, alicyclic acrylate 110g, initiator 18g, triethylamine 10g, water 500g.

[0032] The initiators described in the present invention are benzoyl peroxide and di-tert-amyl peroxide.

[0033] The preparation process of a kind of anticorrosion antirust waterborne acrylic paint among the present invention is as follows:

[0034] ①Mix 2-ethylhexyl acrylate, isobornyl methacrylate, Veova10, cycloaliphatic acrylate and 14g initiator, dissolve evenly and set aside;

[0035] ②Mix acrylic acid, n-butyl acrylate and 4g initiator, dissolve evenly and set aside;

[0036] ③Put toluene into the reactor, heat it to reflux and maintain reflux, start to drop the mixture obtained in step ①, control the rate of addition, make the m...

Embodiment 3

[0039] A kind of anticorrosion antirust waterborne acrylic paint, its acrylic resin is formulated by following raw material by following weight percentage: Acrylic acid 45g, n-butyl acrylate 180g, 2-2-ethylhexyl acrylate 225g, isobornyl methacrylate 225g, Veova 10 00g, alicyclic acrylate 135g, initiator 18g.

[0040] The initiators described in the present invention are benzoyl peroxide and di-tert-amyl peroxide.

[0041] The preparation process of a kind of anticorrosion antirust waterborne acrylic paint among the present invention is as follows:

[0042] ①Mix 2-ethylhexyl acrylate, isobornyl methacrylate, Veova10, cycloaliphatic acrylate and 14g initiator, dissolve evenly and set aside;

[0043] ②Mix acrylic acid, n-butyl acrylate and 4g initiator, dissolve evenly and set aside;

[0044] ③Put toluene into the reactor, heat it to reflux and maintain reflux, start to drop the mixture obtained in step ①, control the rate of addition, make the mixture obtained in step ① drop wit...

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PUM

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Abstract

The invention relates to the technical field of chemical industry and in particular relates to anticorrosion and anti-rust waterborne acrylic coating. Aiming at solving the technical problems, the invention provides the waterborne acrylic coating with excellent anticorrosion performance, good anti-rust effect and good stable performance. By adopting the technical scheme, the anticorrosion and anti-rust waterborne acrylic coating is characterized in that acrylic resin is prepared from the following raw materials in percentage by weight: 1 percent to 10 percent of acrylic acid, 5 percent to 20 percent of n-butyl acrylate, 1 percent to 10 percent of methyl methacrylate, 5 percent to 20 percent of hydroxyethyl acrylate, 1 percent to 10 percent of 2-ethylhexyl acrylate, 40 percent to 60 percentof isobornyl methacrylate, 5 percent to 50 percent of vinyl versatate Veova10, 10 percent to 50 percent of alicyclic acrylate, 0.1 percent to 20 percent of a chain extender, 0.5 percent to 5 percentof an initiator and 30 percent to 50 percent of water; the raw materials are prepared into waterborne acrylic resin with the Tg of -10 DEG C to 80 DEG C.

Description

technical field [0001] The present invention relates to the field of chemical engineering, in particular to an anti-corrosion and anti-rust water-based acrylic paint. Background technique [0002] The 21st century is a century of green and environmental protection. Resource saving, energy saving, and pollution-free are the main development directions of the world's coatings. At present, most of the anti-rust and anti-corrosion coatings used in China are solvent-based coatings. The biggest disadvantage of these coatings is that they pollute the environment, are flammable and explosive, harmful to the human body, and waste a lot of resources and energy. At present, the VOC content of solvent-based coating products in the market is as high as 50% to 60%, and the annual emission of VOC is nearly 200,000 tons, which not only pollutes the environment but also wastes energy. where the focus is. [0003] The base materials of water-based anti-corrosion coatings widely used in the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/10C09D5/08C08F220/18C08F220/06C08F220/14C08F220/28C08F218/00C08F220/10
Inventor 邓茂红程远丁金山曹丽丽王俊强赵灵霞张欣
Owner LINFEN TIE HUAN PAINT IND
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