Technology for preparing wallpaper base layer from modified calcium carbonate as filler
A calcium carbonate, modified technology, applied in the field of papermaking, can solve the problems of poor antistatic performance, easy to form aggregates, uneven dispersion of high polymers, etc., to increase the friction coefficient, reduce the reaction time, and enhance the interface effect Effect
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Embodiment 1
[0028] 1. Preliminary preparation
[0029] Preparation of modified calcium carbonate:
[0030] (1) light calcium carbonate is added to water, is mixed with the calcium carbonate suspension that concentration is 40%, heats 15min while stirring in the water bath of 70 ℃, standby;
[0031] (2) Add cationic starch into water to prepare a starch suspension with a concentration of 50%, stir at 80°C for 10 minutes, and then gelatinize at 92°C for 20 minutes;
[0032] (3) Adjust the pH value of the gelatinized starch solution to 8 with NaOH solution with a concentration of 5%, then add a sodium stearate solution with a concentration of 10%, and mix and stir at 80°C and 200r / min for 20min to form a compound thing, spare;
[0033] (4) the complex obtained in step (3) is added to the calcium carbonate suspension obtained in step (1) and mixed to obtain a mixed emulsion, and the mass ratio of the complex to the calcium carbonate suspension is 30:100, and Add 10% dispersant relative to ...
Embodiment 2
[0041] 1. Preliminary preparation
[0042] Preparation of modified calcium carbonate:
[0043] (1) light calcium carbonate is added to water, is mixed with the calcium carbonate suspension that concentration is 55%, heats 20min while stirring in the water bath of 80 ℃, for subsequent use;
[0044](2) Add cationic starch into water to prepare a starch suspension with a concentration of 65%, stir at 85°C for 15 minutes, and then gelatinize at 95°C for 30 minutes;
[0045] (3) Adjust the pH value of the gelatinized starch solution to 10 with a NaOH solution with a concentration of 8%, then add a sodium stearate solution with a concentration of 15%, and mix and stir at 90°C and 250r / min for 30min to form a compound thing, spare;
[0046] (4) the complex obtained in step (3) is added to the calcium carbonate suspension obtained in step (1) and mixed to obtain a mixed emulsion, and the mass ratio of the complex to the calcium carbonate suspension is 30:120, and Add 15% dispersant...
Embodiment 3
[0054] 1. Preliminary preparation
[0055] Preparation of modified calcium carbonate:
[0056] (1) light calcium carbonate is added to water, is mixed with the calcium carbonate suspension that concentration is 42%, heats 16min while stirring in the water bath of 72 ℃, standby;
[0057] (2) Add cationic starch into water to prepare a starch suspension with a concentration of 52%, stir at 81°C for 11 minutes, and then gelatinize at 93°C for 22 minutes;
[0058] (3) Adjust the pH value of the gelatinized starch solution to 9 with a NaOH solution with a concentration of 6%, then add a sodium stearate solution with a concentration of 11%, and mix and stir at 82°C and 210r / min for 22min to form a compound thing, spare;
[0059] (4) the complex obtained in step (3) is added to the calcium carbonate suspension obtained in step (1) and mixed to obtain a mixed emulsion, and the mass ratio of the complex to the calcium carbonate suspension is 30:105, and Add 11% dispersant relative t...
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