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Technology for preparing wallpaper base layer from modified calcium carbonate as filler

A calcium carbonate, modified technology, applied in the field of papermaking, can solve the problems of poor antistatic performance, easy to form aggregates, uneven dispersion of high polymers, etc., to increase the friction coefficient, reduce the reaction time, and enhance the interface effect Effect

Inactive Publication Date: 2018-01-19
广西华洋矿源材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] In order to improve the quality of the existing wallpaper base formula, some flame retardants or heat stabilizers are added. When molding, the quality of the products is unstable.
At the same time, as the number of times of wallpaper increases, the shrinkage and deformation of the later products will become larger, and the wallpaper will become wet when it meets water, and the base layer of the wallpaper will be easily corroded. The overall quality of the wallpaper is deteriorated, thereby reducing the service life of the wallpaper, which shows that in order to further improve the surface quality of the wallpaper base layer and improve the service life of the wallpaper, filling the modified wallpaper base layer with inorganic fillers has become an effective choice.
[0004] In the paper industry, calcium carbonate is used as a filler for paper products, which can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of paper, and reduce the cost of paper, but its surface has strong hydrophilic properties. Hydroxyl, showing strong alkalinity, this hydrophilic and oleophobic property makes the hydrophilicity of calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion inside the polymer, resulting in two materials The direct application effect is not good, and calcium carbonate is used as a filler, its acid resistance, corrosion resistance and other properties need to be further improved

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] 1. Preliminary preparation

[0029] Preparation of modified calcium carbonate:

[0030] (1) light calcium carbonate is added to water, is mixed with the calcium carbonate suspension that concentration is 40%, heats 15min while stirring in the water bath of 70 ℃, standby;

[0031] (2) Add cationic starch into water to prepare a starch suspension with a concentration of 50%, stir at 80°C for 10 minutes, and then gelatinize at 92°C for 20 minutes;

[0032] (3) Adjust the pH value of the gelatinized starch solution to 8 with NaOH solution with a concentration of 5%, then add a sodium stearate solution with a concentration of 10%, and mix and stir at 80°C and 200r / min for 20min to form a compound thing, spare;

[0033] (4) the complex obtained in step (3) is added to the calcium carbonate suspension obtained in step (1) and mixed to obtain a mixed emulsion, and the mass ratio of the complex to the calcium carbonate suspension is 30:100, and Add 10% dispersant relative to ...

Embodiment 2

[0041] 1. Preliminary preparation

[0042] Preparation of modified calcium carbonate:

[0043] (1) light calcium carbonate is added to water, is mixed with the calcium carbonate suspension that concentration is 55%, heats 20min while stirring in the water bath of 80 ℃, for subsequent use;

[0044](2) Add cationic starch into water to prepare a starch suspension with a concentration of 65%, stir at 85°C for 15 minutes, and then gelatinize at 95°C for 30 minutes;

[0045] (3) Adjust the pH value of the gelatinized starch solution to 10 with a NaOH solution with a concentration of 8%, then add a sodium stearate solution with a concentration of 15%, and mix and stir at 90°C and 250r / min for 30min to form a compound thing, spare;

[0046] (4) the complex obtained in step (3) is added to the calcium carbonate suspension obtained in step (1) and mixed to obtain a mixed emulsion, and the mass ratio of the complex to the calcium carbonate suspension is 30:120, and Add 15% dispersant...

Embodiment 3

[0054] 1. Preliminary preparation

[0055] Preparation of modified calcium carbonate:

[0056] (1) light calcium carbonate is added to water, is mixed with the calcium carbonate suspension that concentration is 42%, heats 16min while stirring in the water bath of 72 ℃, standby;

[0057] (2) Add cationic starch into water to prepare a starch suspension with a concentration of 52%, stir at 81°C for 11 minutes, and then gelatinize at 93°C for 22 minutes;

[0058] (3) Adjust the pH value of the gelatinized starch solution to 9 with a NaOH solution with a concentration of 6%, then add a sodium stearate solution with a concentration of 11%, and mix and stir at 82°C and 210r / min for 22min to form a compound thing, spare;

[0059] (4) the complex obtained in step (3) is added to the calcium carbonate suspension obtained in step (1) and mixed to obtain a mixed emulsion, and the mass ratio of the complex to the calcium carbonate suspension is 30:105, and Add 11% dispersant relative t...

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PUM

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Abstract

The invention belongs to the technical field of papermaking and provides a technology for preparing a wallpaper base layer from modified calcium carbonate as filler. The technology comprises steps asfollows: (1), wood pulp is soaked in water at the temperature of 90-95 DEG C for 1.5-3 h and then is subjected to beating, and paper pulp subjected to beating is obtained; (2), modified calcium carbonate as the filler is added to the paper pulp subjected to beating and is stirred uniformly, and mixed pulp is obtained; (3), a coupling agent, a sizing agent and a hardening agent are added to the mixed pulp, water is added for dilution, the components are mixed and stirred for 30-45 min, and wallpaper base layer pulp is obtained; (4), the wallpaper base layer pulp is added to pulp molding equipment for compression molding, the upper mold temperature is 70-85 DEG C, the lower mold temperature is 60-75 DEG C, mold pressure is 1250-1300 Mpa, mold-closing pressure maintaining is performed for 20-45 s, and the wallpaper base layer is obtained. The preparation technology is simple, the prepared wallpaper base layer is not prone to deformation, corrosion can be avoided, and the service life is longer.

Description

technical field [0001] The invention belongs to the technical field of papermaking, and in particular relates to a process for preparing a wallpaper base layer by using modified calcium carbonate as a filler. Background technique [0002] Wallpaper is a special paper used to decorate walls. There are many types of wallpaper, such as coated wallpaper, film-coated wallpaper, embossed wallpaper, etc. Usually, the base paper produced by bleached chemical wood pulp is used as the base layer. After processing in different processes, such as coated Cloth, printing, embossing or plastic-coated surface, finally cut and packaged before leaving the factory, because it has a certain strength, beautiful appearance and good water resistance, it is widely used in residential, office, hotel interior decoration, etc. [0003] In order to improve the quality of the existing wallpaper base formula, some flame retardants or heat stabilizers are added, and the product has the problem of unstable...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H17/67D21H17/69D21H21/14D21H21/16D21H21/38
Inventor 李文康张宸宇欧西江
Owner 广西华洋矿源材料有限公司
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