Noctilucent intelligent signboard and manufacture method thereof
A signage, intelligent technology, applied in the field of coatings, can solve the problems of unfavorable energy saving, emission reduction, high cost, etc.
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[0015] The invention provides a preparation method of a luminous visible intelligent signage, the preparation method comprising:
[0016] 1) Perform hydrothermal reaction of manganese salt, sulfide, doped metal salt, active agent, water and chitosan, and filter the filter cake to obtain the hydrothermal product;
[0017] 2) Calcining the hydrothermal product to obtain a fluorescent material;
[0018] 3) Acrylic resin, dodecenylsuccinic acid, propylene glycol, glycidyl methacrylate, octyl acrylate, methyl propylene glycol, styrene, ethylenediamine, formic acid, water, sodium isethionate in ultrasonic Mix under conditions, then add titanium dioxide, diatomaceous earth, and fluorescent materials for stirring to obtain the luminous visible paint;
[0019] 4) Apply the luminous visible paint on the surface of the metal frame, and then dry it naturally to prepare the luminous visible smart signage
[0020] Wherein, the doping metal salt is ruthenium salt and / or rhodium salt, and t...
Embodiment 1
[0032] 1) Manganese salt (manganese nitrate), sulfide (sodium sulfide), doped metal salt (ruthenium nitrate), active agent (iron vanadate), water and chitosan according to 1mmol: 1.5mmol: 0.03mmol: 0.2mmol : 15mL: 1mmol was used in a hydrothermal reaction at 190°C for 3 hours, and the filter cake was filtered to obtain a hydrothermal product;
[0033] 2) Heat the hydrothermal product from 25°C to 230°C at a rate of 0.7°C / min and hold it for 35 minutes, then raise the temperature to 330°C at a rate of 1.2°C / min and hold it for 45 minutes, and finally raise the temperature at a rate of 0.2°C / min to 415°C and heat preservation for 110min, and finally cooled naturally to produce fluorescent materials;
[0034] 3) Acrylic resin, dodecenylsuccinic acid, propylene glycol, glycidyl methacrylate, octyl acrylate, methyl propylene glycol, styrene, ethylenediamine, formic acid, water, sodium isethionate in ultrasonic Mix under the same conditions (ultrasonic frequency is 35KHz, mixing te...
Embodiment 2
[0036] 1) Manganese salt (manganese chloride), sulfide (potassium sulfide), doped metal salt (ruthenium sulfate), active agent (iron vanadate), water and chitosan according to 1mmol: 1mmol: 0.02mol: 0.1mmol : 10mL: 0.8mmol dosage ratio, carry out hydrothermal reaction at 180°C for 2h, filter and take filter cake to obtain hydrothermal product;
[0037] 2) Heat the hydrothermal product from 15°C to 200°C at a rate of 0.6°C / min and hold it for 30 minutes, then raise the temperature to 300°C at a rate of 1.1°C / min and hold it for 40 minutes, and finally raise the temperature at a rate of 0.1°C / min to 410°C and keep it warm for 100min, and finally cool naturally to make fluorescent materials;
[0038] 3) Acrylic resin, dodecenylsuccinic acid, propylene glycol, glycidyl methacrylate, octyl acrylate, methyl propylene glycol, styrene, ethylenediamine, formic acid, water, sodium isethionate in ultrasonic Mix under the same conditions (ultrasonic frequency is 30KHz, mixing temperature...
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