Zinc-air battery and preparation method thereof
A zinc-air battery and electrolyte technology, which is applied to fuel cell-type half-cells and primary cell-type half-cells, etc., can solve the problems of complex production process, low efficiency, and failure to realize industrialization of zinc-air batteries, and achieves Low price, easy operation and high yield
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Embodiment 1
[0033] A zinc-air battery includes a positive pole, a negative pole and an electrolyte; the positive pole and the negative pole are solid.
[0034] The positive electrode includes polytetrafluoroethylene, conductive agent and carbon, and its mass ratio is: polytetrafluoroethylene: conductive agent: carbon is 23:18:59.
[0035] Positive electrode preparation:
[0036] Prepare the positive electrode slurry: dissolve the above-mentioned amount of polytetrafluoroethylene in water, then add the conductive agent to make it fully mixed, and finally add the active material, mix and stir evenly to make the positive electrode slurry;
[0037] Coating positive electrode sheet: Coat the prepared positive electrode slurry on the upper and lower surfaces of a 0.1mm nickel mesh, and use waterproof Teflon to insulate both sides of the dust-free paper, roll flattened, and bake at 150°C for 50 minutes to obtain the positive pole.
[0038] The negative electrode includes sodium carboxymethyl c...
Embodiment 2
[0045] A zinc-air battery includes a positive pole, a negative pole and an electrolyte; the positive pole and the negative pole are solid.
[0046] The positive electrode includes polytetrafluoroethylene, conductive agent and active material (lithium manganate and carbon), and its mass ratio is: polytetrafluoroethylene: conductive agent: active material (lithium manganate and carbon) is 25:15:60.
[0047] Positive electrode preparation: the preparation method is the same as in Example 1, except that the roll is flattened and then baked at 200° C. for 20 minutes.
[0048] The negative electrode includes sodium carboxymethyl cellulose and zinc, wherein calculated by mass ratio, sodium carboxymethyl cellulose: zinc is 10:90.
[0049] Negative electrode preparation: The preparation method is the same as in Example 1, except that after coating the negative electrode, it is baked at 110° C. for 30 minutes to obtain the negative electrode.
[0050] Electrolyte: Prepared by mixing po...
Embodiment 3
[0053] A zinc-air battery includes a positive pole, a negative pole and an electrolyte; the positive pole and the negative pole are solid.
[0054] The positive electrode includes polytetrafluoroethylene, conductive agent and active material (lithium manganate and manganese dioxide), and its mass ratio is: polytetrafluoroethylene: conductive agent: active material (lithium manganate and manganese dioxide) is 25:20 :55.
[0055] Positive electrode preparation: the preparation method is the same as in Example 1, except that the roll is flattened and then baked at 150° C. for 60 minutes.
[0056] The negative electrode includes sodium carboxymethyl cellulose and zinc, wherein calculated by mass ratio, sodium carboxymethyl cellulose: zinc is 25:75.
[0057] Negative electrode preparation: The preparation method is the same as in Example 1, except that after coating the negative electrode, it is baked at 110° C. for 30 minutes to obtain the negative electrode.
[0058] Electrolyt...
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