Self-repaired material for cable sheath and preparation method
A self-healing material and cable sheathing technology, used in cable/conductor manufacturing, circuits, electrical components, etc., can solve the problems of poor polymer fluidity, less repair times, and short service life, and achieve good protection and repair efficiency. High and fluid effect
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Embodiment 1
[0033] Mix 45kg of nano-calcium silicate powder, 50kg of nano-calcium aluminate powder with 5kg of hyperbranched polyphenylene, knead in a kneader to obtain modified nanoparticles; then mix the modified nanoparticles with polyvinylidene fluoride fibers The raw materials were placed in an oven and heated and dried at 108°C for 12 hours to remove residual moisture; the container containing 56kg of dimethylformamide was placed in a constant temperature water bath at 90°C, and after the temperature was constant, 7kg of modified nanoparticles were added and 2kg of polyvinylpyrrolidone, stirred at a high speed of 250r / min, and ultrasonically dispersed by 40Hz ultrasonic waves for 18min, then added 35kg of fiber raw materials, stirred for 8h to obtain a stable and uniform casting solution, and then transferred the casting solution Put it into the reaction kettle and let it stand at a temperature of 70°C for 12 hours; then use a hollow fiber spinning machine to extrude the casting solu...
Embodiment 2
[0036]Mix 42kg of nano-calcium silicate powder, 55kg of nano-calcium aluminate powder with 3kg of hyperbranched polysiloxane, knead in a kneader to obtain modified nanoparticles; then mix the modified nanoparticles with ethylene-ethylene Alcohol copolymer fiber raw materials were placed in an oven and heated and dried at 106°C for 11 hours to remove residual moisture; the container containing 60kg of dimethylformamide was placed in a constant temperature water bath at 85°C, and after the temperature was constant, 6kg of dimethylformamide was added Modified nanoparticles and 2kg of polyvinylpyrrolidone were stirred at a high speed of 200r / min, and 40Hz ultrasonic waves were used for ultrasonic dispersion for 16min, then 32kg of fiber raw materials were added, and a stable and uniform casting solution was obtained after stirring for 8h. The casting liquid was transferred to the reaction kettle, and stood at a temperature of 68°C for 13 hours; then, the hollow fiber spinning machi...
Embodiment 3
[0038] The nanometer calcium silicate powder of 48kg, the nanometer calcium aluminate powder of 47kg are mixed with the hyperbranched polyether-imide of 5kg, carry out kneading in kneader, obtain modified nanoparticle; Then modify nanoparticle and The polyethersulfone fiber raw materials were placed in an oven and heated and dried at 110°C for 13 hours to remove residual moisture; the container containing 53kg of dimethylformamide was placed in a constant temperature water bath at 95°C, and after the temperature was constant, 7kg of dimethylformamide was added Modified nanoparticles and 3kg of polyvinylpyrrolidone were stirred at a high speed of 300r / min, and 50Hz ultrasonic waves were used for ultrasonic dispersion for 17min, then 37kg of fiber raw materials were added, and a stable and uniform casting solution was obtained after stirring for 10h. The casting solution was transferred to the reaction kettle and allowed to stand at a temperature of 75°C for 11 h; then the castin...
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