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A device and method for recovering carbon dioxide from catalytic dry gas

A technology for recovering carbon and dry gas, applied in chemical instruments and methods, processing of gas mixtures, organic chemistry, etc., can solve the problems of high energy consumption, affecting the purity of product gas ethylene, and large investment, so as to reduce equipment investment and energy. consumption effect

Active Publication Date: 2020-09-15
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] To sum up, in order to reduce the propylene content in the product gas when recovering the carbon two components in the catalytic dry gas, the existing catalytic dry gas recovery process requires a propylene refrigeration compressor to provide low-temperature cooling capacity, and requires a A drying system is used to remove moisture in the dry gas to prevent freezing blockage, which requires large investment and high energy consumption, and the product gas contains more ethane and carbon four components, which affects the purity of the product gas ethylene

Method used

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  • A device and method for recovering carbon dioxide from catalytic dry gas
  • A device and method for recovering carbon dioxide from catalytic dry gas
  • A device and method for recovering carbon dioxide from catalytic dry gas

Examples

Experimental program
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Effect test

Embodiment 1

[0068] The second section of catalytic dry gas is compressed to 4MPaG and cooled to 15°C, and then mixed with carbon four (the flow rate is 41t / h (by the carbon four recycled in the step (4) and the newly added carbon four (the flow rate is 1.2t / h) h) maintain the constant flow rate)) contact, the conditions for C4 to contact with catalytic dry gas include: the number of theoretical plates is 40, the pressure is 3.6MPaG, the temperature at the top of the tower is 19°C, and the temperature at the bottom of the tower is 115°C; Conditions include: number of theoretical plates is 40, pressure is 2.1MPaG, tower top temperature is 63 ℃, and tower bottom temperature is 124 ℃; The aromatics (flow rate is 0.04t / h) maintains flow rate constant))) and the condition that coarse carbon dioxide contacts comprises: theoretical plate number is 35, and pressure is 2MPaG, and tower top temperature is 37 ℃, and tower bottom temperature is 80 ℃; Step ( 3) The remaining gasoline-containing compone...

Embodiment 2

[0070] The catalytic dry gas is compressed to 3MPaG in the second section and cooled to 10°C, and then mixed with carbon four (flow rate is 47t / h (through the carbon four recycled in step (4) and newly added carbon four (flow rate is 1.2t / h) h) to maintain constant flow rate)) contact, the conditions for C4 to contact with catalytic dry gas include: the number of theoretical plates is 25, the pressure is 3MPaG, the temperature at the top of the tower is 19°C, and the temperature at the bottom of the tower is 101°C; the conditions for the first rectification Including: the number of theoretical plates is 50, the pressure is 2.7MPaG, the temperature at the top of the tower is 59°C, and the temperature at the bottom of the tower is 136°C; Aromatics (flow rate is 1t / h) keep flow rate constant))) and the condition that thick carbon two contacts comprises: theoretical plate number is 25, and pressure is 1.5MPaG, and tower top temperature is 34 ℃, and tower bottom temperature is 70 ℃;...

Embodiment 3

[0072] The catalytic dry gas is compressed to 5MPaG in the second section and cooled to 15°C, and then mixed with carbon four (flow rate is 37t / h (by carbon four recycled in step (4) and newly added carbon four (flow rate is 1.2t / h) h) keep the flow rate constant)) contact, the conditions for C4 to contact with catalytic dry gas include: the number of theoretical plates is 50, the pressure is 4.2MPaG, the temperature at the top of the tower is 19°C, and the temperature at the bottom of the tower is 124°C; Conditions include: number of theoretical plates is 30, pressure is 2.7MPaG, tower top temperature is 59 DEG C, tower bottom temperature is 136 DEG C; The aromatics (flow rate is 1t / h) maintains flow rate constant))) and the condition of coarse carbon dioxide contact comprises: theoretical plate number is 43, and pressure is 2.5MPaG, and tower top temperature is 42 ℃, and tower bottom temperature is 101 ℃; Step ( 3) The remaining gasoline-containing components in the step (1)...

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Abstract

The invention relates to the field of organic matter recovery from gas and discloses a device and a method for recovering C2 from catalytic dry gas. The device comprises a C4 absorption tower, a C4 desorption tower and a second gasoline absorption tower which are connected sequentially as well as a first gasoline absorption tower and a gasoline stabilization tower which are connected. The method comprises the following steps: C4 is contacted with the catalytic dry gas, so that heavy components of C2 or higher in the catalytic dry gas are absorbed; the absorbed C4 and heavy components of C2 orhigher are subjected to first rectification, and crude C2 and C4 are obtained by separation; gasoline is contacted with crude C2, then heavy components in crude C2 are absorbed, and C2 is further separated out; remaining gasoline-containing components are contacted with unabsorbed light components, C4 entrapped in the light components is absorbed, a mixture of absorbed C4 and gasoline is subjectedto second rectification, and C4 and gasoline are separated and reused to previous steps respectively. With adoption of the method, C2 can be recovered from the catalytic dry gas effectively, and content of propylene, ethane and C4 in a product is lower.

Description

technical field [0001] The invention relates to the field of gaseous organic matter recovery, in particular to a device and method for recovering carbon dioxide from catalytic dry gas. Background technique [0002] Catalytic dry gas comes from the secondary processing of crude oil, such as catalytic cracking, delayed coking and other processes. The dry gas usually contains a large amount of ethylene and ethane components. For example, the molar content of ethane in the catalytic dry gas is about 10-24%, and the molar content of ethylene is about 12-20%. At present, catalytic dry gas is mainly burned as fuel, and its utilization value is low. If the carbon two components in the dry gas are concentrated and the ethylene or ethane in it is recycled, the economic and social benefits are very obvious. One of the ways to utilize the enriched C2 enriched gas is as the raw material for the ethylbenzene plant, but the ethylbenzene plant requires that the propylene content in the ra...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G70/04C10G70/06C07C7/00C07C7/04C07C11/04
CPCC07C7/005C07C7/04C10G70/04C10G70/041C10G70/06C07C11/04
Inventor 邵华伟刘智信李东风胡志彦邹弋罗淑娟
Owner CHINA PETROLEUM & CHEM CORP
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