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Decorating paper and preparation method thereof

A decorative paper and monomer technology, applied in papermaking, paper coating, textiles and papermaking, etc., can solve problems such as insufficient adhesion, water marks on decorative paper, loss of ink, etc.

Active Publication Date: 2018-05-22
天津华彩顺成装饰材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing patent document with an authorized announcement date of 2010.12.29 and an authorized announcement number of CN101613472B discloses a method for preparing a polyamide resin for water-based ink. The phenomenon of "water marks" will occur. The reason for the phenomenon of "water marks" is: water marks are a kind of imaging. From the perspective of ink, it is its transferability. Water marks are the appearance. The real meaning is that the ink has no transfer
The light printing pressure and direct ink transfer method of the flexographic printing process determine that the ink cannot be sheared and thinned during the ink roller pouring process. If there is obvious shear thinning, it is difficult for the ink to adhere to the screen completely. On the anilox roller, the process of the anilox roller transferring the ink to the printing plate will also further lose part of the ink due to insufficient cohesion of the ink, resulting in the final ink detaching from the printing plate and adhering to the substrate. Adhesion is not enough, resulting in "water streak" phenomenon on decorative paper

Method used

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  • Decorating paper and preparation method thereof
  • Decorating paper and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1a

[0028] Preparation of modified polyamide resin: in a nitrogen atmosphere, 31.3g of polyamide resin, 24.5g of n-propanol and 24.5g of absolute ethanol were configured into solution A; 8.0g of methyl methacrylate monomer, 4.8g maleic acid monomer, 4.5g trans-1-octen-1-yl boronic acid monomer and 0.065g dibenzoyl peroxide were made into solution B; 0.005g dibenzoyl peroxide Make solvent C with 4.43g of methyl ethyl ketone; under nitrogen atmosphere and 85°C, add solution B dropwise to solution A for 1 hour, keep warm for 1 hour, then add solution C dropwise three times , with an interval of 1 hour each time, and after the total reaction time reaches 5 hours, the modified polyamide resin is precipitated by precipitation method-flocculation. Wherein the good solvent is n-propanol, and the poor solvent is petroleum ether.

[0029] Preparation of water-based ink: mix 40g of modified polyamide resin and 1g of triethylamine evenly, slowly add 5g of water to the aminated resin under ro...

Embodiment 2a

[0031] Preparation of modified polyamide resin: in a nitrogen atmosphere, 28g of polyamide resin, 21g of n-propanol and 28g of absolute ethanol are configured into solution A; 9.0g of methyl methacrylate monomer, 4g of cis-butyl Dibenzoyl peroxide of 0.01 g and dibenzoyl peroxide of 0.01 g and butanone of 4.43 g are made into solvent C: Under the condition of nitrogen atmosphere and 90°C, add solution B dropwise to solution A for 1.5 hours, keep warm for 1.5 hours, then add solution C three times with an interval of 1 hour, the total reaction After the time reaches 6 hours, the modified polyamide resin is precipitated by precipitation method-flocculation. Wherein the good solvent is n-propanol, and the poor solvent is petroleum ether.

[0032] Preparation of water-based ink: Mix 45g of modified polyamide resin and 0.5g of triethylamine evenly, slowly add 3g of water to the aminated resin under room temperature and high-speed stirring, and continue stirring at high speed to obta...

Embodiment 3a

[0034] Preparation of modified polyamide resin: in a nitrogen atmosphere, 35g of polyamide resin, 28g of n-propanol and 21g of absolute ethanol were configured into solution A; 7.0g of methyl methacrylate monomer, 6g of cis-butyl Dibenzoyl peroxide of 0.007g dibenzoyl peroxide and 0.007g of dibenzoyl peroxide and 4.43g of methyl ethyl ketone is made into solvent C; Under the condition of atmosphere and 80°C, add solution B dropwise to solution A for 1.25 hours, keep warm for 1.25 hours, then add solution C three times with an interval of 1 hour, and the total reaction time is 5.5 hours Finally, the modified polyamide resin is precipitated out by precipitation method-flocculation. Wherein the good solvent is n-propanol, and the poor solvent is petroleum ether.

[0035] Preparation of water-based ink: Mix 55g of modified polyamide resin and 0.75g of triethylamine evenly, slowly add 4g of water to the aminated resin under room temperature and high-speed stirring, and continue st...

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PUM

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Abstract

The invention relates to decorating paper, which is obtained by printing water-based ink on base paper. The water-based ink is prepared from the following components in parts by mass: 40 to 50 parts of modified polyamide resin, 40 to 50 parts of color paste, 0.5 to 1 part of triethylamine, 3 to 5 parts of water, 0.5 to 2.0 parts of silicon dioxide aerogel and 0.7 to 2.3 parts of an adjuvant. The modified polyamide resin is prepared by mixing a reactant monomer comprising alcohol-soluble polyamide resin, a methyl methacrylate monomer, a maleic acid monomer and a vinyl organic boric acid monomercontaining carbon-carbon double bonds and an initiator in a nitrogen atmosphere and performing graft copolymerization reaction, the weight ratio of the alcohol-soluble polyamide resin, the methyl methacrylate monomer, the maleic acid monomer and the vinyl organic boric acid monomer containing the carbon-carbon double bonds is (28-35):(7-9):(4-6):(4-5), and the weight of the initiator is 0.2 to 0.25 percent of the weight of the alcohol-soluble polyamide resin. The invention also provides a preparation method for the decorating paper. According to the decorating paper, occurrence of a 'water wave' phenomenon can be effectively avoided.

Description

technical field [0001] The invention relates to the technical field of printing, more specifically, it relates to a decorative paper and a preparation method thereof. Background technique [0002] Ink is a paste-like colloid formed by uniformly dispersing and mixing colorants, binders, additives and other substances. It is mainly composed of pigments as the dispersed phase and binders as the continuous phase. The pigments give the ink its color, and the binder provides the necessary transfer properties of the ink. The binder is the heart of the ink, which can make the colorant (pigment) grind and disperse evenly on the dispersion equipment; make the pigment adhere firmly to the substrate, and make the ink have the necessary gloss, drying performance and printability. The main properties of the ink, such as fluidity, viscosity, drying performance and printing adaptability, all depend on the binder, so the binder is the key to the quality of the ink. [0003] According to t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H19/20C09D11/106C09D11/03C08F283/04C08F230/06C08F222/02C08F220/14
CPCC08F283/04C09D11/03C09D11/106D21H19/20C08F230/06
Inventor 乐东平
Owner 天津华彩顺成装饰材料有限公司
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