Phosphogypsum water hard road material and preparation method thereof

A technology of road materials and gypsum water, which is applied in the field of road engineering construction, can solve problems such as damage to soil structure and connection, poor crack resistance, pollution, etc., and achieve high orderly arrangement, high water erosion resistance, and high chemical stability. Effect

Active Publication Date: 2018-05-29
湖北恒沁环保科技有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the effective utilization rate of phosphogypsum in China is less than 10%. Only a very small amount of phosphogypsum is used to produce building materials, and the remaining huge amount of phosphogypsum is piled up as solid waste. Harmful heavy metal chemicals such as arsenic, cadmium, and mercury pollute the environment
In cement-stabilized soil, cement, as a hydraulic material, produces colloids when it meets water. These colloids cannot form a unified whole in the soil, and will also destroy the structure and connection of the soil itself, resulting in a large number of unstable spaces. Under the intrusion and temperature changes, it will become very fragile, so the road base formed by cement stabilized soil is very easy to crack and has poor crack resistance

Method used

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  • Phosphogypsum water hard road material and preparation method thereof
  • Phosphogypsum water hard road material and preparation method thereof

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Experimental program
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Effect test

Embodiment 1

[0043] Embodiment 1: a kind of phosphogypsum hydraulic road material, described road material is made of the raw material of following percentage by weight: phosphogypsum 78%, lime 6% cement 15.2%, curing agent 0.8%, described curing agent is made of the following substances Aqueous solution configured according to mass fraction:

[0044] Cationic Chelate 3%

[0045] Nano Zirconia 0.03%

[0046] Ethylenediamine 0.1%

[0047] Quinoline Oxide 0.1%

[0048] Manganese Sulfate 4%

[0049] Triethanolamine 1%

[0050] Calcium chloride 0.5%

[0051] The balance is water,

[0052] Wherein, the cationic chelate is a metal ion chelate formed by chelating magnesium ions and ethylenediaminetetraacetic acid (EDTA).

Embodiment 2

[0053] Embodiment two: a kind of phosphogypsum hydraulic road material, described road material is made of the raw material of following percentage by weight: phosphogypsum 77%, steel slag 8%, cement 14.3%, curing agent 0.7%, described curing agent consists of the following Aqueous solution composed of substances according to mass fraction:

[0054] Cationic Chelate 4%

[0055] Nano Zirconia 0.035%

[0056] Ethylenediamine 0.15%

[0057] Manganese Sulfate 4%

[0058] Naphthalenesulfonic acid formaldehyde condensate 3%

[0059] Sodium Fluoride 0.5%

[0060] Sodium Alkylbenzene Sulfonate 1%

[0061] The balance is water,

[0062] Wherein, the cationic chelate is a metal ion chelate formed by chelating magnesium ions and aminotriacetic acid (NTA).

Embodiment 3

[0063] Embodiment three: a kind of phosphogypsum hydraulic road material, described road material is made of the raw material of following percentage by weight: phosphogypsum 80%, aluminum slag 5%, lime 1%, cement 13.4%, curing agent 0.6%, so The aqueous solution in which the curing agent is configured by the following substances according to the mass fraction:

[0064] Cationic Chelate 5%

[0065] Nano Zirconia 0.01%

[0066] Nano Titanium Dioxide 0.01%

[0067] Ethylenediamine 0.05%

[0068] Paraformaldehyde 0.07%

[0069] Quinoline Oxide 0.1%

[0070] Manganese Sulfate 2%

[0071] Chromium Sulfate 3%

[0072] Naphthalenesulfonic acid formaldehyde condensate 2%

[0073] Polyvinyl alcohol 0.8%

[0074] Dimethylaniline 2%

[0075] Calcium nitrate 0.8%

[0076] Sodium Alkylbenzene Sulfonate 1%

[0077] The balance is water,

[0078] Wherein, the cationic chelate is a metal ion chelate formed by chelating calcium ions and ethylenediaminetetraacetic acid (EDTA).

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Abstract

The invention provides a phosphogypsum water hard road material and a preparation method thereof. The road material is prepared from the following raw materials by weight percent: 77 to 88 percent ofphosphogypsum, 0 to 8 percent of alkaline mineral waste residue, 0 to 6 percent of lime, 4 to 16 percent of cement, and 0.2 to 0.8 percent of curing agent, wherein the curing agent is prepared from the following raw materials by weight percent: 1 to 5 percent of cationic chelate, 0.01 to 0.035 percent of nano oxide, 0.1 to 0.2 percent of cross-linking agent, 0 to 0.4 percent of quinoline oxide, and 1 to 5 percent of metal salts, and the curing agent also comprises a water reducing agent, a curing accelerant and an anti-seepage agent. The phosphogypsum is used for producing the road material which can substitute the traditional road basic layer and road water stabilizing layer; and by integrating the road basic layer and the road water stabilizing layer, convenience in construction can be realized, the environmental pollution can be reduced, and waste can be converted into treasure; and a formed road layer is high in cracking resistance, unlikely in corrosion and long in service life.

Description

technical field [0001] The invention relates to the field of road engineering construction, in particular to a phosphogypsum hydraulic road material and a preparation method thereof. Background technique [0002] The highway construction industry is the basic industry of the economy and plays a vital role in the development of the national economy. At present, my country's highways are far ahead of the sum of other modes of transportation in terms of passenger traffic, freight volume, and passenger turnover. However, with the rapid development of roads, especially expressway construction, the problem of premature destruction of large areas of roads is also very prominent. Many newly-built or recently overhauled national and provincial roads have experienced serious early damage, which is far behind the design service life. Reasons for premature failure of concrete pavement include design, construction and use reasons. [0003] Phosphogypsum is a solid waste discharged dur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/04
CPCC04B28/04C04B2111/0075C04B2201/50C04B22/064C04B22/144C04B24/121C04B24/122C04B22/142C04B22/124C04B24/125C04B22/06C04B18/142C04B24/123C04B22/126C04B24/226C04B24/16C04B18/141C04B24/2623C04B24/26
Inventor 段恒张沁寰
Owner 湖北恒沁环保科技有限责任公司
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