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Lithium sulfur battery positive electrode paste preparation method

A cathode slurry, lithium-sulfur battery technology, used in electrode manufacturing, battery electrodes, lithium batteries, etc., can solve the problems of lithium-sulfur battery capacity attenuation, easy uneven dispersion, poor cycle performance, etc., to inhibit migration and easy to mix. Even, avoid bleed effect

Active Publication Date: 2018-05-29
ZHEJIANG FOREVER NEW ENERGY TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, compared with lithium-ion batteries, at present, lithium-sulfur batteries have serious capacity decay, poor cycle performance and poor stability.
For example, the Chinese patent application (publication number: CN106410116A) discloses a method for preparing a positive electrode of a lithium-sulfur battery. A slurry is prepared by simultaneously mixing and stirring a solvent, a positive electrode active material, a conductive agent, a dispersant, and a binder. Form a porous structure with nanopore, mesopore, and micropore structure composition levels, so as to accommodate the volume change of the sulfur cathode material, inhibit the pulverization of sulfur particles, and adsorb polysulfide intermediates to improve the performance of the lithium-sulfur battery cathode. However, this method It takes a long time to prepare the slurry, and it is easy to disperse unevenly

Method used

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  • Lithium sulfur battery positive electrode paste preparation method

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Experimental program
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Effect test

Embodiment 1

[0026] The lithium-sulfur battery positive electrode slurry of this embodiment is prepared by the following method:

[0027] Select the raw material according to the mass percentage ratio of each component of the lithium-sulfur battery positive electrode slurry, take the sum of the mass of the sulfur positive electrode active material, conductive agent, dispersant and binder as the total mass (according to 100%), select 0.8g sulfur element , 0.1g acetylene black and 0.06g sodium carboxymethyl cellulose (CMC) were added into a mixing mixer to carry out stirring and dry-blending processing, so that the time of stirring and dry-blending processing was 20min, and after the dry-blending finished, a corresponding powdery mixture was obtained;

[0028] Then, add solvent deionized water to the powder mixture in three batches, specifically add 0.226g deionized water for the first premixing treatment, stir and mix for 30min, after stirring evenly, then add 0.678g deionized water Water i...

Embodiment 2

[0031] The lithium-sulfur battery positive electrode slurry of this embodiment is prepared by the following method:

[0032] Select the raw material according to the mass percentage ratio of each component of the lithium-sulfur battery positive electrode slurry, take the sum of the mass of the sulfur positive electrode active material, conductive agent, dispersant and binder as the total mass (according to 100%), select 0.9g sulfur element , 0.05g of earthy graphite and 0.03g of sodium alginate are added into a mixing mixer for stirring and dry-blending treatment, wherein, the sulfur element is preliminarily pulverized so that its particle size is 100nm, and the time for stirring and dry-blending treatment is 20min. After mixing, the corresponding powdery mixture is obtained;

[0033] Then, add solvent deionized water to the powder mixture in batches, specifically add 0.226g deionized water for the first premixing treatment, stir and mix for 30min, after stirring evenly, then ...

Embodiment 3

[0036] The lithium-sulfur battery positive electrode slurry of this embodiment is prepared by the following method:

[0037] Select raw materials according to the mass percentage ratio of each component of the lithium-sulfur battery positive electrode slurry, take the sum of the mass of the sulfur positive electrode active material, conductive agent, dispersant and binder as the total mass (according to 100%), select 0.6g sulfur element , 0.1g of BP2000 and 0.1g of sodium alginate were added to a mixing mixer for stirring and dry-blending treatment, wherein the sulfur element was pre-pulverized to make the particle size 300nm, and the time for stirring and dry-blending treatment was 20min, and the dry-blended After the end, the corresponding powdery mixture is obtained;

[0038] Then, add solvent deionized water to the powder mixture in batches, specifically add 0.226g deionized water for the first premixing treatment, stir and mix for 30min, after stirring evenly, then add 0....

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Abstract

The invention belongs to the technical field of battery positive electrode material preparation and provides a lithium sulfur battery positive electrode paste preparation method in order to solve problems of difficulty in dispersion and poor cycle stability. The method includes steps: selecting raw materials according to mass percent ratios of components in positive electrode paste, subjecting sulfur positive electrode active substances, a conductive agent and a solid dispersing agent to dry mixing in advance to obtain a powder mixture; adding a solvent into the powder mixture, and well mixingto obtain premixed paste; adding an adhesive into the premixed paste, and mixing to form lithium sulfur battery positive electrode paste. By combination of dry mixing and stage addition of the solvent prior to addition of the adhesive, local agglomeration can be avoided, uniformity in paste mixing and mixing time saving are realized, and paste stability is improved. By adoption of the adhesive and the dispersing agent with special functional groups, polysulfide migration can be inhibited, and charge-discharge and cycle performances can be improved.

Description

technical field [0001] The invention relates to a preparation method of a lithium-sulfur battery positive electrode slurry, belonging to the technical field of battery positive electrode material preparation. Background technique [0002] Lithium-sulfur battery is a kind of lithium battery with sulfur element as the positive electrode of the battery, and the theoretical discharge specific capacity of elemental sulfur can reach 1675mAh / g, which is much higher than that of lithium-ion batteries widely used in commerce. Therefore, the sulfur cathode active material is currently the cathode material with the highest specific capacity, and lithium has the smallest relative atomic mass and the most negative standard electrode potential among metal elements. Therefore, lithium-sulfur batteries have high theoretical discharge voltage, high theoretical discharge specific capacity, and high theoretical specific energy, which are expected to meet the long-term development requirements ...

Claims

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Application Information

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IPC IPC(8): H01M4/36H01M4/38H01M4/62H01M4/04H01M10/052
CPCH01M4/04H01M4/364H01M4/38H01M4/628H01M10/052H01M2004/028Y02E60/10
Inventor 张芳芳赵亚刘桐桐杨冬生翟博刘俊军
Owner ZHEJIANG FOREVER NEW ENERGY TECH CO LTD