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Wear-resistant PVC roll material and preparation method thereof

A coil and resin technology, applied in the field of wear-resistant PVC coil and its preparation, can solve the problems of large dimensional change rate of floor heating, increased processing difficulty, pits or damage, etc., to avoid yellowing and improve wear resistance And the characteristics of environmental protection, the effect of high tension

Inactive Publication Date: 2018-06-22
浙江金华天开电子材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] PVC is well known as a very common plastic material, its full name is polyvinyl chloride. In recent years, the development of PVC is mainly used in pipes. It can perfectly replace metal pipes and be installed in every household, but PVC is on the bottom plate. The application of PVC is still in its infancy, and the material has just emerged in recent years, and the PVC on the market is initially granular and then shaped through thermoplastic extrusion and other processes, and then processed into a plate-like structure that can be bent arbitrarily, but There are very high requirements for the wear resistance level. Although the wear resistance of the PVC resin coil with a high proportion (greater than 65%) can reach the T level, the excessively high proportion not only increases the difficulty of processing, but also increases the processing difficulty. The dimensional change rate of the floor heating is relatively large, which cannot meet the standard requirements. After all, coiled materials are used in densely populated areas. This requires more attention to the wear resistance of the surface of the coiled material. If the wear resistance is not good, pits or damage will appear after a long time, which is serious. It affects the use, and most of the PVC coils on the market are multi-layer structures. Among them, the patent number CN200710118914.8 discloses an improved PVC elastic coil floor and its production method. Although a wear-resistant layer is provided, there are technical requirements and The cost of raw materials is relatively high, and it can only be used in some special places, but it cannot be widely promoted

Method used

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  • Wear-resistant PVC roll material and preparation method thereof
  • Wear-resistant PVC roll material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0027] A wear-resistant PVC coiled material, comprising 20 parts of PVC resin, 20 parts of composite resin, 25 parts of TPU resin, 0.5 parts of antioxidant, 15 parts of modified plasticizer, 3 parts of stabilizer, 15 parts of filler, hair 3 parts of foaming agent, composite resin includes: modified ABS resin, inorganic nano-ceramic resin, vinylidene fluoride homopolymer resin, ultra-high molecular weight polyethylene resin, ethylene-vinyl acetate copolymer, and modified ABS resin, inorganic nano Ceramic resin, vinylidene fluoride homopolymer resin, ultra-high molecular weight polyethylene resin, and ethylene-vinyl acetate copolymer are added in a ratio of 5:2:2:6:5;

[0028] Modified plasticizers include 25 parts of dioctyl phthalate, 20 parts of 2-ethylhexyl epoxy stearate, 20 parts of dioctyl azelate, 2-ethyl epoxy soybean oleate by weight 20 parts of hexyl ester, 20 parts of ethylene-n-butyl acrylate-glycidyl ester, white carbon black and red mud as filler, and dichlorodifl...

Embodiment 2

[0032] A wear-resistant PVC coiled material, comprising 25 parts of PVC resin, 20 parts of composite resin, 20 parts of TPU resin, 1 part of antioxidant, 20 parts of modified plasticizer, 5 parts of stabilizer, 15 parts of filler, 6 parts of foaming agent, composite resin includes: modified ABS resin, inorganic nano-ceramic resin, vinylidene fluoride homopolymer resin, ultra-high molecular weight polyethylene resin, ethylene-vinyl acetate copolymer, and modified ABS resin, inorganic Nano-ceramic resin, vinylidene fluoride homopolymer resin, ultra-high molecular weight polyethylene resin, and ethylene-vinyl acetate copolymer are added in a ratio of 6:2:2:6:5;

[0033] Modified plasticizers include 30 parts of dioctyl phthalate, 15 parts of 2-ethylhexyl epoxy stearate, 15 parts of dioctyl azelate, 2-ethyl epoxy soybean oleate by weight 15 parts of hexyl ester, 20 parts of ethylene-n-butyl acrylate-glycidyl ester, the filler is calcium carbonate, and the blowing agent is dichloro...

Embodiment 3

[0037]A wear-resistant PVC coil, comprising 30 parts of PVC resin, 30 parts of composite resin, 20 parts of TPU resin, 1 part of antioxidant, 20 parts of modified plasticizer, 3 parts of stabilizer, 10 parts of filler, 3 parts of foaming agent, composite resin includes: modified ABS resin, inorganic nano-ceramic resin, vinylidene fluoride homopolymer resin, ultra-high molecular weight polyethylene resin, ethylene-vinyl acetate copolymer, and modified ABS resin, inorganic Nano-ceramic resin, vinylidene fluoride homopolymer resin, ultra-high molecular weight polyethylene resin, and ethylene-vinyl acetate copolymer are added in a ratio of 4:2:2:6:6;

[0038] The modified plasticizer includes 25 parts of dioctyl phthalate, 15 parts of 2-ethylhexyl epoxy stearate, 15 parts of dioctyl azelate, 2-ethylhexyl epoxy soybean oleate by weight. 15 parts of hexyl ester, 20 parts of ethylene-n-butyl acrylate-glycidyl ester, white carbon black and calcium carbonate as filler, and dichlorodifl...

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PUM

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Abstract

The invention discloses a wear-resistant PVC roll material comprising PVC resin, composite resin, TPU resin, an antioxidant, a modified plasticizer, a stabilizer, a filling agent and a foaming agent;the composite resin comprises modified ABS resin, inorganic nano-ceramic resin, vinylidene fluoride homopolymer resin, ultra-high molecular weight polyethylene resin and ethylene-vinyl acetate copolymer; and the modified plasticizer comprises the components according to the weight ratio: dioctyl phthalate, 2-ethylhexyl epoxystearate, dioctyl azelate, epoxybean oleic acid 2-ethylhexyl ester and ethylene butyl acrylate-glycidyl ester. The prepared wear-resistant PVC roll material has the effects of use convenience, high wear resistance and higher environment friendliness.

Description

technical field [0001] The invention relates to a PVC floor material which can be used for trains, office buildings and hospitals, in particular to a wear-resistant PVC coiled material and a preparation method thereof. Background technique [0002] A large number of PVC transparent coils are used in public places with super high flow of people, which have very high requirements for wear resistance. Among them, they are mainly used in high-end office buildings for floor boards, which can increase friction and reduce cracking. It is used in hospitals or some public places with dense traffic. When food or some difficult-to-clean compounds drip on the bottom plate, it can be easily wiped off with a rag, which is very convenient and can maintain a long-term cleaning effect. [0003] PVC is well known as a very common plastic material, its full name is polyvinyl chloride. In recent years, the development of PVC is mainly used in pipes. It can perfectly replace metal pipes and be i...

Claims

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Application Information

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IPC IPC(8): C08L75/04C08L27/06C08L55/02C08L27/16C08L23/06C08L23/08C08K13/02C08K5/12C08K5/1515C08K3/36C08K3/26C08J9/14E04F15/10
CPCC08J9/0023C08J9/0061C08J9/0066C08J9/147C08J2203/144C08J2327/06C08J2375/04C08J2427/06C08J2475/04C08K3/36C08K5/12C08K5/1515C08K13/02C08K2003/265E04F15/105
Inventor 姜煌庭姜干张英姿吴通文胡沛
Owner 浙江金华天开电子材料有限公司
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