High-performance water-based rust-transfer paint resin and water-based rust-transfer paint
A high-performance, water-based technology, used in epoxy resin coatings, coatings, anti-corrosion coatings, etc., can solve problems such as slow drying speed, and achieve the effects of improved adhesion, good weather resistance, and easy use.
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Embodiment 1
[0033] Embodiment 1 self-made epoxy resin preparation
[0034] Prepare raw materials according to Table 2.
[0035] Table 2 Synthetic formula of epoxy ester
[0036] serial number raw material Quantity (grams) 1 Epoxy E-12 resin 67.9 2 Linoleic Acid 11.4 3 Tetrabutylammonium bromide 0.95 4 Ethylene glycol butyl ether 19.75 total 100
[0037] Synthesis process: Add the formula amount of epoxy resin, linolenic acid, and catalyst into the reaction kettle, raise the temperature to 120°C and keep it warm, the system will turn light yellow, and the viscosity will gradually increase. Measure the acid value after 2 hours, when the acid value is ≦1 mgKOH / g, slowly add ethylene glycol butyl ether, stir evenly, cool down to 80°C, and filter for later use.
Embodiment 2
[0038] Example 2 Preparation of Modified Acrylic Resin
[0039] Prepare raw materials according to Table 3.
[0040] Table 3 waterborne acrylic resin formula
[0041] components Quantity (grams) Methyl methacrylate 28.8 Butyl acrylate 15.1 Silicone monomer 1 Phosphate monomer 1 Organofluorine monomer 5 2-Ethylhexyl Acrylate EHA 9.1 Butyl methacrylate 5.1 acrylic acid 7.6 Benzoyl peroxide 1.5 n-dodecanethiol 1.5 Ethylene glycol butyl ether 24.3 total 100
[0042] Synthesis process: Weigh 28.8g of methyl methacrylate, 15.1g of butyl acrylate, 9.1g of 2-ethylhexyl acrylate, 5.g of butyl methacrylate, 7.6g of acrylic acid, 1g of ethylene Alkyl triisopropoxysilane, 1g alkyl phosphate acrylate, 5g trifluoroethyl acrylate, 1.5g n-dodecanethiol, 1.5g benzoyl peroxide, mix evenly. Weigh 24.3g of ethylene glycol butyl ether and add it to a four-necked flask, raise the temperature to 105°C, take 1 / 3 ...
Embodiment 3
[0043] The preparation of embodiment 3 water-based rust-transferring paint resins
[0044] Epoxy esters and water-based acrylic resins synthesized in Examples 1 and 2 with a mass ratio of 50:50, and a zinc oxide catalyst of 0.15% of the total mass was added.
[0045] Synthesis process: Take 500 grams of epoxy ester resin and water-based acrylic resin, 1.5 grams of zinc oxide catalyst, add them to a 2-liter four-necked flask and heat in an oil bath, raise the temperature to 110°C, keep it warm for 30 minutes, then raise the temperature to 120°C, and react until the acid value to the specified value, then lower the temperature to 80°C, then neutralize with dimethylethanolamine at a neutralization degree of 100%, add water to a solid content of 40%, and filter the material to obtain WBD-88 water-based rust-removing paint resin .
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