High-efficient and economical Cr-Al-Si co-cementation technology for steel
A chromium-aluminum and co-infiltration technology is applied in the field of energy-saving and efficient preparation of chromium-aluminum-silicon composite infiltration layer, which can solve the problems of difficult control, increased energy consumption, and increased process cost, etc., to increase diffusion channels, improve electrical conductivity, and improve infiltration speed effect
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Embodiment 1
[0009] Infiltration material: 45 steel; chromium-aluminum-silicon co-infiltration agent composition: chromium donor (high carbon ferrochrome, content 1%), aluminum supply agent (aluminum powder, content 2%), process stabilizer (iron powder, content 2%), silicon donor and filler (silicon carbide, content 93%); activator (ammonium chloride powder, content 1%); anti-sintering agent (charcoal powder, content 1%). Control experiment penetration agent formula: 1% high-carbon ferrochrome powder, 2% aluminum powder, 95% silicon carbide powder, 1% ammonium chloride and 1% charcoal powder.
[0010] The sample is placed between two parallel plate-shaped electrodes in the infiltration tank, and the two electrodes are respectively connected to a 50Hz AC power supply with a continuously adjustable voltage in the range of 0-250V by wires. Seal them together in a soaking tank, place them in a furnace from room temperature to 800°C, apply an alternating current of 2A between the two electrodes...
Embodiment 2
[0013] Material to be infiltrated: 45 steel; chromium-aluminum-silicon co-infiltration agent composition: chromium donor (high carbon ferrochrome, content 5%), aluminum donor (aluminum powder, content 0.5%), process stabilizer (iron powder, content is 1%), silicon donor and filler (silicon carbide, content is 91.5%); activator (ammonium chloride powder, content is 1%); anti-sintering agent (charcoal powder, content is 1%).
[0014] The co-infiltration method and device are the same as in Example 1. The co-infiltration temperature is 800°C, the holding time is 4 hours, and the electric field is 0.5A. The comparative experiment is the conventional chromium-aluminum-silicon co-infiltration with the same infiltration agent and no electric field.
[0015] A chromium-aluminum-silicon co-infiltrated layer of ~108 μm was obtained on the sample with the applied electric field, and the main phase of the infiltrated layer was Fe 3 Si,Al 0.3 Fe 3 Si 0.7 and CrFe 8 Si, while under th...
experiment example 3
[0017] Material to be infiltrated: 45 steel; chromium-aluminum-silicon co-infiltration agent composition: chromium donor (high carbon ferrochrome, content 5%), aluminum donor (aluminum powder, content 0.5%), process stabilizer (iron powder, content is 10%), silicon donor and filler (silicon carbide, content is 82.5%); activator (ammonium chloride powder, content is 1%); anti-sintering agent (charcoal powder, content is 1%). The infiltration agent in the comparative experiment does not contain iron powder (replaced by an equal amount of silicon carbide).
[0018] The co-infiltration method and device are the same as in Example 1. The co-infiltration temperatures were 750°C and 900°C respectively, the holding time was 6 hours, and the electric field current was 2A.
[0019] After co-infiltration at 750 °C, XRD analysis shows that the surface layer of the sample treated with no iron powder infiltration agent is mainly Fe 3 Si phase, while the surface layer of the experimental s...
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