A high-voltage positive electrode sheet and its preparation method
A high-voltage, positive electrode technology, applied in the direction of electrode manufacturing, battery electrodes, electrode collector coating, etc., can solve the problems of ignoring the design of positive electrodes, achieve high-current charging and discharging, high conductivity efficiency, and improve charging and discharging efficiency effect
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Embodiment 1
[0029] A high-voltage positive electrode sheet, comprising a positive electrode current collector and a positive electrode slurry layer coated on the surface of the positive electrode current collector, the positive electrode slurry layer is composed of 92.5wt% positive active material, 5.5wt% composite conductive agent and 2wt% The binder is prepared by carbonization treatment, and the composite conductive agent is composed of 68wt% cellulose, 30wt% graphene and 2wt% aluminum powder.
[0030] Wherein, the length of the cellulose is 30 μm, the diameter is 200 nm, the average particle size of the graphene is 55 nm, the BET surface area is 600 m2 / g, and the particle size of the aluminum powder is 40 nm.
[0031] Wherein, the binder is polyvinylidene fluoride.
[0032] Wherein, the positive electrode active material is LiNi x co y mn z o 2 , where x=0.3, y=0.5, z=0.2.
[0033] Wherein, the particle size distribution D50 of the positive electrode active material is 13 μm.
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Embodiment 2
[0045] A high-voltage positive electrode sheet, comprising a positive electrode current collector and a positive electrode slurry layer coated on the surface of the positive electrode current collector, the positive electrode slurry layer is composed of 87wt% positive active material, 10wt% composite conductive agent and 3wt% viscose The composite conductive agent is prepared by carbonizing the binder, and the composite conductive agent is composed of 57wt% cellulose, 40wt% graphene and 3wt% aluminum powder.
[0046] Wherein, the length of the cellulose is 10 μm, the diameter is 100 nm, the average particle size of the graphene is 10 nm, the BET surface area is 800 m2 / g, and the particle size of the aluminum powder is 30 nm.
[0047] Wherein, the binder is polyvinylidene fluoride.
[0048] Wherein, the positive electrode active material is LiNi x co y mn z o 2 , where x=0.26, y=0.44, z=0.3.
[0049] Wherein, the particle size distribution D50 of the positive electrode act...
Embodiment 3
[0062] A high-voltage positive electrode sheet, including a positive electrode current collector and a positive electrode slurry layer coated on the surface of the positive electrode current collector, the positive electrode slurry layer is composed of 98wt% positive electrode active material, 1wt% composite conductive agent and 1wt% viscose The composite conductive agent is prepared by carbonizing the binder, and the composite conductive agent is composed of 79wt% cellulose, 20wt% graphene and 1wt% aluminum powder.
[0063] Wherein, the length of the cellulose is 50 μm, the diameter is 300 nm, the average particle size of the graphene is 100 nm, the BET surface area is 400 m2 / g, and the particle size of the aluminum powder is 49 nm.
[0064] Wherein, the binder is polyvinylidene fluoride.
[0065] Wherein, the positive electrode active material is LiNi x co y mn z o 2 , where x=0.33, y=0.61, z=0.6.
[0066] Wherein, the particle size distribution D50 of the positive elec...
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