The invention relates to the technical field of high-performance
polymer materials, in particular to low-
dielectric and high-temperature-resistant modified
cyanate ester resin and a preparation method thereof. Advantages and characteristics of
bisphenol A type
cyanate ester monomers and
bisphenol M type
cyanate ester monomers are combined, and the
dielectric property and the
thermal stability are remarkably improved. Diallyl
bisphenol A is introduced as a
network structure modifier, the phenolic hydroxyl group of the diallyl
bisphenol A adjusts the curing
reaction rate, and the allyl and
bisphenol A structures of the diallyl
bisphenol A finely regulate and control the rigid-flexible balance of a cross-linked network through chemical copolymerization, so that the curing process is controllable and the final
network structure is optimized. Meanwhile, a
toughening system is innovatively designed,
epoxy-terminated liquid
nitrile rubber is adopted for
toughening, stable micron-scale rubber particles are formed in a
resin matrix in a chemical bonding mode, and the
fracture toughness is improved. The modified resin has excellent
dielectric properties,
high heat resistance and a wide
process window, and meets the strict requirements of a new generation of low
observability aircrafts on a bearing-stealth integrated
composite material matrix.