Unlock instant, AI-driven research and patent intelligence for your innovation.

A resin for improving the adhesion of water-based nano coatings

A nano-coating and adhesion technology, used in resins and coatings to improve the adhesion of water-based nano-coatings, and in the field of improving the adhesion of metal surfaces. The effect of anti-corrosion, salt spray resistance chemical anti-corrosion, and comprehensive performance improvement

Active Publication Date: 2020-11-03
SHENYANG RES INST OF CHEM IND +2
View PDF2 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Water-based nano anti-corrosion coatings have excellent mechanical strength and anti-corrosion properties, but due to the poor adhesion of coatings on metals, this excellent anti-corrosion coating cannot be widely used. Due to the poor affinity of water-based nano-materials to metals, In addition, the formation of inorganic particles further reduces the contact area between the paint film and the metal, so the current water-based nano anti-corrosion coating has poor adhesion on the metal surface, which seriously affects its application in the field of metal anti-corrosion.
[0003] Generally, substances that improve adhesion are surfactants containing polyhydroxyl and carboxyl groups or resins containing polyhydroxyl and carboxyl groups. However, in water-based nano-systems, additives containing hydroxyl and carboxyl groups cannot coexist with isocyanates, and the isocyanate system will appear during storage. Thickening, decrease of NCO content, skinning, agglomeration, etc.
The addition of polyhydroxyl surface active substances will also lead to uncontrollable reaction speed after the two components are mixed, resulting in undesirable paint film problems such as exothermic reaction, rapid temperature rise in the system, and excessive foaming, and has no effect on the metal adhesion of the water-based nano system. any lifting effect

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A resin for improving the adhesion of water-based nano coatings
  • A resin for improving the adhesion of water-based nano coatings
  • A resin for improving the adhesion of water-based nano coatings

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Preparation method of adhesion enhancing resin

[0036] Take 67 parts of JF-PE-3020 alkyd resin, 20 parts of phthalates, 10 parts of MDI-50 isocyanate monomer, and 3 parts of DY-12 (dibutyltin dilaurate). 60°C, after reacting for 1h, let it stand to room temperature.

[0037] The preparation method of the novel hybrid resin of water-based nano-coating adhesion performance is as follows, and concrete formula is shown in Table 1:

[0038] Table 1

[0039]

[0040]

[0041] 1) Put 50 parts of TDI-HDI mixed polymer into the dispersion kettle, add 21 parts of phthalates, 15 parts of modified JF-PE-3020 resin, and 0.2 parts of triethyl phosphate catalyst in sequence, and stir for 10 minutes; Add 0.2 parts of BYK-2151, 0.4 parts of TEGO-410, 0.2 parts of TEGO-900 in sequence, and stir for 10 minutes;

[0042] 2) Add 3 parts of carbon black and 10 parts of bentonite to the above slurry, and disperse at 1000-2000r for 1-2 hours until the slurry is stable; obtain component...

Embodiment 2

[0047] The difference from Example 1 is:

[0048] Preparation method of adhesion enhancing resin

[0049] Take 67 parts of Niax Polyol-D560 resin, 20 parts of phthalates, 10 parts of MDI-50 isocyanate monomer, 3 parts of DY-12 (dibutyltin dilaurate) and mix well, then heat to 60°C, After reacting for 1 h, let stand to room temperature.

[0050] The preparation method of the novel mixed resin of water-based nano paint adhesion performance is as follows, specifically

[0051] 1) Put 50 parts of TDI-HDI mixed multimer into the dispersion kettle, add 21 parts of phthalates, 15 parts of modified Niax Polyol-D560 resin, 0.2 parts of triethyl phosphate catalyst in turn, and stir for 10 minutes; Add 0.2 parts of BYK-2151, 0.4 parts of TEGO-410, 0.2 parts of TEGO-900, and stir for 10 minutes;

[0052] 2) Add 3 parts of carbon black and 10 parts of bentonite to the above slurry, and disperse at 1000-2000r for 1-2 hours until the slurry is stable; obtain component A after filtration; ...

Embodiment 3

[0055] The difference from Example 1 is:

[0056] Preparation method of adhesion enhancing resin

[0057] Take 67 parts of PPG-1000 resin, 20 parts of phthalate, 10 parts of MDI-50 isocyanate monomer, and 3 parts of DY-12 (dibutyltin dilaurate). Let stand to room temperature after 1h.

[0058] The preparation method of the novel mixed resin of water-based nano paint adhesion performance is as follows, specifically

[0059] 1) Put 50 parts of TDI-HDI mixed polymer into the dispersion kettle, add 21 parts of phthalates, 15 parts of modified PPG-1000 resin, and 0.2 parts of triethyl phosphate catalyst in sequence, and stir for 10 minutes; then add 0.2 parts of BYK-2151, 0.4 parts of TEGO-410, 0.2 parts of TEGO-900, stirred for 10 minutes;

[0060] 2) Add 3 parts of carbon black and 10 parts of bentonite to the above slurry, and disperse at 1000-2000r for 1-2 hours until the slurry is stable; obtain component A after filtration;

[0061] 3) Dissolve 40 parts of potassium silic...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
adhesivityaaaaaaaaaa
modulusaaaaaaaaaa
Login to View More

Abstract

The invention relates to a waterborne nanometer anti-corrosion coating, in particular to resin for improving the adhesive force of a waterborne nanometer coating and a method for improving adhesive force on the metal surface. The resin for improving the adhesive force of the waterborne nanometer coating is resin or modified resin, wherein the resin is one or more of polyester, polyether, vinyl ester; the modified resin is one or more of modified polyester, modified polyether, modified vinyl ester. The invention further relates to a modification method of adhesive force-reinforced resin; a compound made by the mixed resin is used for testing of the adhesive force property on the metal surface as well as a coating mode.

Description

technical field [0001] The invention relates to a water-based nano anticorrosion coating, in particular to a resin and a coating for improving the adhesion of the water-based nano coating and a method for improving the adhesion of a metal surface. Background technique [0002] Water-based nano anti-corrosion coatings have excellent mechanical strength and anti-corrosion properties, but due to the poor adhesion of coatings on metals, this excellent anti-corrosion coating cannot be widely used. Due to the poor affinity of water-based nano-materials to metals, In addition, the formation of inorganic particles further reduces the contact area between the paint film and the metal, so the current water-based nano anti-corrosion coating has poor adhesion on the metal surface, which seriously affects its application in the field of metal anti-corrosion. [0003] Generally, substances that improve adhesion are surfactants containing polyhydroxyl and carboxyl groups or resins containi...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C09D175/14C09D175/04C09D5/08C09D5/18C09D7/61C09D7/63
CPCC09D5/08C09D5/18C09D7/61C09D7/63C09D175/08C09D175/14C08K13/02C08K5/12C08K3/04C08K3/346
Inventor 吴井龙张宇孔凡厚胥维昌张学龙王新滕赟
Owner SHENYANG RES INST OF CHEM IND