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Preparation method of waterborne fluorosilicon resin anticorrosive paint

A technology of water-based fluorosilicone and anti-corrosion coatings, applied in anti-corrosion coatings, coatings, etc., can solve problems such as poor water resistance and corrosion resistance, heavy anti-corrosion, and automotive topcoats that have not yet been water-based, achieving excellent mechanical properties and simple preparation process Effect

Inactive Publication Date: 2018-09-07
INST OF APPLIED CHEM JIANGXI ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the performance of domestically developed water-based anti-corrosion coatings is still lower than that of similar solvent-based anti-corrosion coatings, and there are still application defects that need to be overcome, such as poor water and corrosion resistance and high construction requirements. Second, the automotive topcoat has not yet been water-based, and related products have been sold abroad. At present, the water-based automotive refinish paint market is almost occupied by foreign products; in the petrochemical field, the anti-corrosion treatment of equipment is particularly important.
Anti-corrosion materials are required to have various characteristics such as heavy-duty anti-corrosion, high temperature resistance, and penetration resistance, as well as flexibility, resistance to sudden temperature changes, resistance to sudden stress changes, and bonding performance under high temperature. It is difficult to use traditional anti-corrosion coatings Meet the harsh working environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] Add 100.0 grams of water-based silicone resin emulsion, 50.0 grams of water-based silicone-modified acrylic resin emulsion, and 30 grams of water-based fluorosilicone resin emulsion into a 500ML three-necked bottle, place it on an electric stirrer, raise the temperature to 50°C, and stir at this temperature After 1.5 hours, the water-based resin matrix was obtained and cooled to room temperature for use.

[0015] Accurately weigh 10.0 grams of alumina powder, 10.0 grams of zinc oxide powder, 3.0 grams of rutile titanium dioxide, 3.5 grams of mica powder, 2.0 grams of silica powder and 1.5 grams of hollow glass microspheres, and mix them uniformly to obtain functional fillers. It was poured into the above-mentioned resin matrix, and then 50.0 g of diluent deionized water was added to start stirring. After stirring and mixing for 2.0 hours, the discharge was stopped to obtain the target product.

Embodiment 2

[0017] Add 100.0 grams of water-based silicone resin emulsion, 35.0 grams of water-based silicone modified acrylic resin emulsion, and 45 grams of water-based fluorosilicone resin emulsion into a 500ML three-necked bottle, place it on an electric heating stirrer, raise the temperature to 50°C, and stir at this temperature After 1.5 hours, the water-based resin matrix was obtained and cooled to room temperature for use.

[0018] Accurately weigh 10.0 grams of alumina powder, 8.0 grams of zinc oxide powder, 5.0 grams of rutile titanium dioxide, 3.5 grams of mica powder, 2.5 grams of silica powder and 2.0 grams of hollow glass microspheres, and mix them uniformly to obtain functional fillers. It was poured into the above-mentioned resin matrix, and then 50.0 g of diluent deionized water was added to start stirring. After stirring and mixing for 2.0 hours, the discharge was stopped to obtain the target product.

Embodiment 3

[0020] Add 100.0 grams of water-based silicone resin emulsion, 60.0 grams of water-based silicone-modified acrylic resin emulsion, and 20 grams of water-based fluorosilicone resin emulsion into a 500ML three-necked bottle, place it on an electric heating stirrer, raise the temperature to 50°C, and stir at this temperature After 1.5 hours, the water-based resin matrix was obtained and cooled to room temperature for use.

[0021] Accurately weigh 10.0 grams of alumina powder, 6.0 grams of zinc oxide powder, 4.0 grams of rutile titanium dioxide, 3.0 grams of mica powder, 1.5 grams of silica powder and 3.5 grams of hollow glass microspheres, and mix them uniformly to obtain functional fillers. It was poured into the above-mentioned resin matrix, and then 45.0 g of diluent deionized water was added to start stirring. After stirring and mixing for 2.0 hours, the discharge was stopped, and the target product could be obtained.

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PUM

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Abstract

The invention relates to a preparation method of waterborne fluorosilicon resin anticorrosive paint. The method comprises the following steps that (1) waterborne silicon resin emulsion, waterborne organosilicone modified acrylic resin emulsion and waterborne fluorosilicon resin emulsion are uniformly mixed to prepare a resin base body; (2) aluminum oxide powder, zinc oxide powder, rutile titaniumdioxide, mica powder, silicon micro powder and hollow glass microbeads are added into a high-speed stirring machine; the mixture is stirred and mixed into a functional filler in the high-speed stirring machine for use; (3) a certain quantity of resin base bodies, functional filling materials and diluents are fully stirred by the high-speed stirring machine and are then prepared into the waterbornefluorosilicon resin anti-corrosion paint with good dispersion. The product prepared by the method has the characteristics of green effect, no toxicity, environment-friendly effect, temperature resistance, anticorrosion, excellent mechanical property and the like. The preparation process is simple and convenient; the product can be widely applied to industries of petrochemical engineering, machinery and building and the like.

Description

technical field [0001] The invention relates to a preparation method of a water-based fluorosilicone resin anticorrosion coating, which belongs to the technical field of functional resin-based composite materials. Background technique [0002] During the process of manufacturing, construction, drying and curing of coatings, the volatile organic compounds emitted into the air are one of the important environmental pollutants and seriously threaten human health. At present, the world's coatings are developing in the direction of low pollution and pollution-free. Environmentally friendly coatings such as water-based, powderized, solvent-free, high-solid and radiation-cured coatings account for more than 70% of all coatings. In the coatings industry, the output of anti-corrosion coatings is the second largest type of coatings after architectural coatings. In recent years, affected by factors such as petroleum resources and environmental protection regulations on volatile organi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/04C09D133/04C09D183/08C09D5/08C09D7/61C09D7/20
Inventor 董晓娜游胜勇付建平孙复钱夏俊
Owner INST OF APPLIED CHEM JIANGXI ACAD OF SCI
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