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Composite electrode and battery

A composite electrode and battery technology, applied in the direction of battery electrodes, alkaline storage batteries, alkaline storage battery electrodes, etc., can solve the difficult problem of graphene agglomeration and other problems, and achieve inhibition of branch crystal growth, increase utilization rate, and large conductive area Effect

Active Publication Date: 2018-09-18
ZINERGY SHENZHEN LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method is prepared by ball milling, which is difficult to solve the problem of graphene agglomeration, thus failing to improve the utilization rate of graphene.

Method used

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Experimental program
Comparison scheme
Effect test

preparation example Construction

[0033] The application provides a kind of preparation method of composite graphene / zinc electrode, comprises the following steps:

[0034] Mix zinc particles, graphene, carbon nanohorns and binders in a certain ratio to obtain a slurry with a certain viscosity. The slurry is coated on the current collector and dried to obtain a composite graphene / zinc electrode.

[0035] An embodiment of the present invention provides a method for preparing a zinc / silver oxide battery, comprising the following steps:

[0036] Silver oxide, carbon conductive agent and binder are mixed to obtain a paste with a certain viscosity. The slurry is coated on the current collector and dried to obtain a silver oxide electrode, which is used as the positive electrode of the zinc / silver oxide battery.

[0037] A graphene / zinc electrode is used as the negative electrode. The positive electrode, the separator and the negative electrode are superimposed, injected with an electrolyte, and packaged to form ...

example 1

[0059] 1. Preparation of carbon nanohorns:

[0060] Carbon nanohorn aggregates were obtained by rapid condensation of carbon atoms under the condition of no catalyst. The average diameter of the obtained single carbon nanohorn is about 3-5 nm, and the average length is about 30-50 nm. The average diameter of the obtained carbon nanohorn aggregates is about 60-120 nm.

[0061] 2. Preparation of reduced graphene:

[0062] Graphene oxide was prepared by the modified Hummers method, followed by thermal reduction treatment of graphene oxide. The dried graphene oxide sheet was placed on a heating platform at about 350 °C and heated rapidly to cause a rapid reduction reaction to generate reduced graphene rGO. 1 g of dried graphene oxide sheets yielded approximately 0.33 g of rGO. During the reduction reaction, the functional groups of graphene oxide disappear to generate CO 2 , CO and H 2 O gas. Graphene oxide is exfoliated during the generation of these gases, resulting in ve...

example 2

[0070] Carbon nanohorn aggregates were obtained by rapid condensation of carbon atoms under the condition of no catalyst. The average diameter of the obtained single carbon nanohorn is about 3-5 nm, and the average length is about 30-50 nm. The average diameter of the obtained carbon nanohorn aggregates is about 60-120 nm.

[0071]Graphene oxide was prepared by the modified Hummers method, followed by thermal reduction treatment of graphene oxide. The dried graphene oxide sheet was placed on a heating platform at about 350 °C and heated rapidly to cause a rapid reduction reaction to generate reduced graphene rGO. 1 g of dried graphene oxide sheets yielded approximately 0.33 g of rGO. During the reduction reaction, the functional groups of graphene oxide disappear to generate CO 2 , CO and H2O gases. Graphene oxide is exfoliated during the generation of these gases, resulting in very low-density rGO sheets. Although the oxygen-containing functional groups partially disappe...

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Abstract

The invention provides a composite electrode and a battery. The composite electrode comprises zinc particles, reduced graphene, and carbon nano horns, and the zinc particles, reduced graphene, and carbon nano horns are adhered on a current collector through an adhesive. Furthermore, the invention provides a battery. The battery comprises a negative electrode, namely the aforementioned composite electrode. The battery also comprises a silver oxide positive electrode, a diaphragm arranged between the silver oxide positive electrode and the negative electrode, and electrolyte. The composite electrode and battery have the advantages that the carbon nano horns can prevent the agglomeration of graphene, thus the utilization rate of graphene is increased; the carbon nano horns / graphene compositestructure can provide a large conductive area; the zinc negative electrode can effectively inhibit the growth of branch crystals during the cycling charge-discharge process, and the cycle life of thezinc / silver oxide battery is prolonged.

Description

technical field [0001] The invention relates to a battery, in particular to a composite electrode and a battery. Background technique [0002] In recent years, due to the rapid development of IoT (Internet of things, Internet of Things), the demand for high-performance batteries is increasing day by day. Zinc-based batteries have attracted more and more attention due to their low cost. Zinc-based batteries usually have better compatibility with aqueous electrolytes, making them more environmentally friendly and safer. In addition, high electrode potential, low density, low overpotential, and high rate discharge capability are also unique advantages of zinc-based batteries over other electrochemical energy storage devices. Zinc can be paired with a variety of different cathode materials to form several battery types, including zinc-manganese, zinc / silver oxide, nickel / zinc, and zinc / air batteries. Divided from the cycle of use, zinc-based batteries include primary batterie...

Claims

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Application Information

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IPC IPC(8): H01M4/24H01M4/36H01M4/42H01M4/62H01M10/24B82Y40/00
CPCB82Y40/00H01M4/244H01M4/364H01M4/42H01M4/625H01M4/628H01M10/24Y02E60/10
Inventor 普里帖斯·希亚拉聂赞相郑富林杜国庆
Owner ZINERGY SHENZHEN LTD