Transformation technology for catalytic diesel
A technology for catalyzing diesel oil and a process, which is applied in the petroleum industry, molecular sieve catalyst, hydrotreating process, etc., can solve the problem of unfavorable hydrogenation conversion to produce high-octane gasoline, strong gasoline component saturation ability, and gasoline product octane loss. big problem
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Embodiment 1
[0043] (1) Configure NaNO 3 Aqueous solution, NaNO 3 Concentration as Na 2 O is calculated as 8g / 100ml;
[0044] (2) NaNO obtained in step 1 3 The aqueous solution was impregnated with industrially produced macroporous alumina powder according to the liquid / solid ratio of 3:1 for 2 hours, and after filtration, it was calcined at 120 °C for 2 hours, and then calcined at 550 °C for 3 hours;
[0045] (3) Take 40 g of alumina obtained in step (2), 80 g of modified Y molecular sieve for industrial production, and 80 g of MoO 3 Mix 20g of nickel nitrate with 20g of nickel nitrate, add 4g / 100ml of dilute nitric acid, mix and roll in a mixer until it can be extruded, extrude and shape on an extruder, dry and roast to obtain catalyst C1.
Embodiment 2
[0047] (1) Configure Mg (NO 3 ) 2 Aqueous solution, Mg(NO 3 ) 2 The concentration is calculated as 4g / 100ml with MgO;
[0048] (2) Mg(NO) obtained in step 1 3 ) 2 The aqueous solution was impregnated with industrially produced macroporous alumina powder according to the liquid / solid ratio of 2:1 for 2 hours, and after filtration, it was calcined at 110 °C for 4 hours and at 500 °C for 4 hours;
[0049] (3) Mix 30 g of alumina obtained in step (2) and 90 g of modified Y molecular sieve for industrial production, add 4 g / 100 ml of dilute nitric acid, mix and roll in a mixer until it can be extruded, and extrude it on an extruder. carrier;
[0050] (4) Configure Mo-Ni impregnation solution, MoO 3 , basic nickel carbonate is added to distilled water to prepare partial Mo-Ni impregnation solution, and MoO is adjusted in the mixed solution according to the oxide of metal salt. 3 23g / 100ml, nickel oxide 8g / 100ml;
[0051] (5) Take the Mo-Ni impregnation solution obtained in...
Embodiment 3
[0053] (1) Configure KNO 3 Aqueous solution, KNO 3 Concentration as Na 2 O is calculated as 10g / 100ml;
[0054] (2) NaNO obtained in step 1 3 The aqueous solution was impregnated with industrially produced macroporous alumina powder according to the liquid / solid ratio of 2:1 for 2 hours, and after filtration, it was calcined at 110 °C for 4 hours and at 500 °C for 4 hours;
[0055] (3) Mix 50 g of alumina obtained in step (2), 100 g of modified Y molecular sieve for industrial production, 25 g of metatungstic acid and 20 g of nickel nitrate, add 4 g / 100 ml of dilute nitric acid, mix and roll in a mixer until it can be extruded Catalyst C3 is obtained by extruding, molding, drying and calcining on an extruder.
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