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Transformation technology for catalytic diesel

A technology for catalyzing diesel oil and a process, which is applied in the petroleum industry, molecular sieve catalyst, hydrotreating process, etc., can solve the problem of unfavorable hydrogenation conversion to produce high-octane gasoline, strong gasoline component saturation ability, and gasoline product octane loss. big problem

Active Publication Date: 2018-10-09
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this method cannot selectively reduce the hydrogenation saturation of gasoline components, so the octane number loss of gasoline products is relatively large
[0005] EP20110834653 discloses a method for preparing a polycyclic aromatic hydrocarbon hydrogenation conversion catalyst. The catalyst carrier is composed of β molecular sieve and pseudo-boehmite. The active metal components of Group VIB and Group VIII are added by conventional methods, but the catalyst is also Strong saturation ability for gasoline components, which is not conducive to the process of catalytic diesel hydrogenation conversion to produce high-octane gasoline

Method used

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  • Transformation technology for catalytic diesel
  • Transformation technology for catalytic diesel
  • Transformation technology for catalytic diesel

Examples

Experimental program
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Effect test

Embodiment 1

[0043] (1) Configure NaNO 3 Aqueous solution, NaNO 3 Concentration as Na 2 O is calculated as 8g / 100ml;

[0044] (2) NaNO obtained in step 1 3 The aqueous solution was impregnated with industrially produced macroporous alumina powder according to the liquid / solid ratio of 3:1 for 2 hours, and after filtration, it was calcined at 120 °C for 2 hours, and then calcined at 550 °C for 3 hours;

[0045] (3) Take 40 g of alumina obtained in step (2), 80 g of modified Y molecular sieve for industrial production, and 80 g of MoO 3 Mix 20g of nickel nitrate with 20g of nickel nitrate, add 4g / 100ml of dilute nitric acid, mix and roll in a mixer until it can be extruded, extrude and shape on an extruder, dry and roast to obtain catalyst C1.

Embodiment 2

[0047] (1) Configure Mg (NO 3 ) 2 Aqueous solution, Mg(NO 3 ) 2 The concentration is calculated as 4g / 100ml with MgO;

[0048] (2) Mg(NO) obtained in step 1 3 ) 2 The aqueous solution was impregnated with industrially produced macroporous alumina powder according to the liquid / solid ratio of 2:1 for 2 hours, and after filtration, it was calcined at 110 °C for 4 hours and at 500 °C for 4 hours;

[0049] (3) Mix 30 g of alumina obtained in step (2) and 90 g of modified Y molecular sieve for industrial production, add 4 g / 100 ml of dilute nitric acid, mix and roll in a mixer until it can be extruded, and extrude it on an extruder. carrier;

[0050] (4) Configure Mo-Ni impregnation solution, MoO 3 , basic nickel carbonate is added to distilled water to prepare partial Mo-Ni impregnation solution, and MoO is adjusted in the mixed solution according to the oxide of metal salt. 3 23g / 100ml, nickel oxide 8g / 100ml;

[0051] (5) Take the Mo-Ni impregnation solution obtained in...

Embodiment 3

[0053] (1) Configure KNO 3 Aqueous solution, KNO 3 Concentration as Na 2 O is calculated as 10g / 100ml;

[0054] (2) NaNO obtained in step 1 3 The aqueous solution was impregnated with industrially produced macroporous alumina powder according to the liquid / solid ratio of 2:1 for 2 hours, and after filtration, it was calcined at 110 °C for 4 hours and at 500 °C for 4 hours;

[0055] (3) Mix 50 g of alumina obtained in step (2), 100 g of modified Y molecular sieve for industrial production, 25 g of metatungstic acid and 20 g of nickel nitrate, add 4 g / 100 ml of dilute nitric acid, mix and roll in a mixer until it can be extruded Catalyst C3 is obtained by extruding, molding, drying and calcining on an extruder.

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Abstract

The invention discloses a conversion technology for catalytic diesel. The conversion technology comprises the following steps that (1) mixed materials of catalytic cracking diesel and hydrogen enter ahydrogenation reactor for hydrofining reaction; (2) hydrofining reaction effluent directly enters a cracking reactor and is subjected to contact reaction with hydrocracking catalyst beds in the cracking reactor, wherein a hydrocracking reactor is filled with an upper hydrocracking catalyst bed and a lower hydrocracking catalyst bed in a grading manner, a catalyst of the upper bed takes W-Ni and / or Mo-Ni as an active metal component and takes a modified Y molecular sieve and / or alkali metal or alkaline earth metal modified aluminum oxide as a carrier, and a catalyst of the lower bed takes Mo-Co as an active metal component and takes the modified Y molecular sieve and carbon deposit aluminum oxide as a carrier; and (3) the hydrocracking reaction effluent obtained in the step (2) is subjected to separation and fractionation so as to obtain a naphtha component and a diesel component. According to the conversion technology, on the premise that the conversion rate of the catalytic diesel isbetter met, the hydrogenation saturation of a generated gasoline component is reduced, and the octane value of the gasoline component is increased.

Description

technical field [0001] The invention belongs to the technical field of hydroprocessing, and in particular relates to a catalytic diesel hydrogenation conversion process. Background technique [0002] Since the beginning of the new century, with the increasing awareness of people's environmental protection, the increasingly stringent national environmental protection regulations and the rapid development of the national economy, the demand for clean motor fuels in all countries in the world is increasing. Catalytic cracking (FCC) technology is one of the main technological means for the lightening of heavy oil, and it occupies a relatively important position in oil refining enterprises all over the world. The annual processing capacity of catalytic cracking units in my country has exceeded 100 million tons, second only to the United States. In the composition of gasoline and diesel products, catalytic cracked gasoline accounts for about 80%, and catalytic diesel accounts for...

Claims

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Application Information

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IPC IPC(8): C10G67/02B01J29/16
CPCB01J29/166B01J2229/20C10G67/02C10G2300/305C10G2400/02
Inventor 柳伟方向晨杜艳泽王凤来秦波高杭张晓萍
Owner CHINA PETROLEUM & CHEM CORP
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