The catalyst for aliphatic mono-olefine hydrosaturation catalyst is formed from active component and carrier, in which active component comprises (wt%) Mo2O3 5-20%, NiO 4-15% and X1 1-5%, in which X1 is one or several kinds selected from B, P and Si, besides, it also can include adjuvant X2, the weight percentage content of X2 is 0-5%, and its carrier is active alumina. Said catalyst is applicable to hydrosaturation of C4-C20 fatty olefines, specially applicable to hydrosaturation of light olefines, such as ethylene, propylene and butylene oligomer gasoline to produce gasoline with high octane value. Its hydrogenation condition includes: temp. is 180-300 deg.C, pressure is 1.5-4.0 MPa, liquid hourly space velocity is 1.0-5.0 h(-1) and mole ratio of hydrogen and olefine is 1.5-2.5.