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High-strength flame-retardant ABS alloy material and preparation method thereof

An alloy material and high-strength technology, applied in the field of high-strength flame-retardant ABS alloy material and its preparation, can solve problems such as poor flame-retardant performance of ABS, achieve stable hydrophobic performance, improve strength and thermal stability, and improve anti-aging performance. Effect

Active Publication Date: 2018-11-13
杭州金州高分子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The purpose of the present invention is to overcome the problem of poor flame retardancy of ABS in the prior art, and provide an ABS alloy material with excellent flame retardancy

Method used

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  • High-strength flame-retardant ABS alloy material and preparation method thereof
  • High-strength flame-retardant ABS alloy material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] A high-strength flame-retardant ABS alloy material, including the following raw materials in parts by weight: 20 parts of acrylonitrile-butadiene-styrene copolymer, 10 parts of polycarbonate, maleic anhydride-styrene-acrylonitrile copolymer phase 3 parts of compatibilizer, 0.1 part of 1010 antioxidant, 15 parts of flame retardant. The flame retardant includes decabromodiphenylethane, antimony trioxide and polytetrafluoroethylene, and the mass ratio of decabromodiphenylethane, antimony trioxide and polytetrafluoroethylene is 1:0.1:0.4.

[0026] A preparation method of a high-strength flame-retardant ABS alloy material, comprising the following steps:

[0027] 1) Add the acrylonitrile-butadiene-styrene copolymer, polycarbonate and compatibilizer in parts by weight of the formula to the mixer and stir for 5 minutes, then add the remaining formula components and continue to stir for 10 minutes to obtain the mixed material ;

[0028] 2) Adding the mixed material into a twi...

Embodiment 2

[0030] A high-strength flame-retardant ABS alloy material, including the following raw materials in parts by weight: 20 parts of acrylonitrile-butadiene-styrene copolymer, 10 parts of polycarbonate, maleic anhydride-styrene-acrylonitrile copolymer phase 3 parts of compatibilizer, 0.1 part of 1010 antioxidant, 15 parts of flame retardant, 20 parts of modified polyurethane resin, 5 parts of glass fiber and 10 parts of modified zeolite. The flame retardant includes decabromodiphenylethane, antimony trioxide and polytetrafluoroethylene, and the mass ratio of decabromodiphenylethane, antimony trioxide and polytetrafluoroethylene is 1:0.1:0.4.

[0031] The preparation method of modified polyurethane resin is:

[0032] Mix 5 parts by weight of hydroxycitric acid, 1 part of methyl trifluoropropyl silicone oil, and 2 parts of ethylene glycol diglycidyl ether, then heat up to 60°C, react for 1 hour, and then add 30 parts of toluene diisocyanate, 10 parts Polyethylene glycol, stirred an...

Embodiment 3

[0039] A high-strength flame-retardant ABS alloy material, comprising the following raw materials in parts by weight: 30 parts of acrylonitrile-butadiene-styrene copolymer, 30 parts of polycarbonate, 4 parts of styrene-based block copolymer compatibilizer , 0.2 parts of 168 antioxidant, 16 parts of flame retardant, 25 parts of modified polyurethane resin, 6 parts of glass fiber and 12 parts of modified zeolite. The flame retardant includes decabromodiphenylethane, antimony trioxide and polytetrafluoroethylene, and the mass ratio of decabromodiphenylethane, antimony trioxide and polytetrafluoroethylene is 1:0.1:0.4.

[0040] The preparation method of modified polyurethane resin is:

[0041]Mix 6 parts by weight of hydroxycitric acid, 1 part of methyl trifluoropropyl silicone oil, and 3 parts of ethylene glycol diglycidyl ether, then heat up to 65°C, react for 1.5 hours, and then add 33 parts of toluene diisocyanate, 12 1 part of polyethylene glycol, stirring and reacting for 4...

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Abstract

The invention relates to the technical field of polymer materials, and discloses a high-strength flame-retardant ABS alloy material and a preparation method of the high-strength flame-retardant ABS alloy material. The ABS alloy material comprises the following raw materials in parts by weight: 20 to 80 parts of an ABS copolymer, 10 to 70 parts of polycarbonate, 3 to 10 parts of a compatibilizer, and 0.1 to 0.5 part of an antioxidant; the components are mixed, subjected to melt blending, extruded, air-dried and granulated to obtain the ABS alloy material. The alloy material disclosed by the invention has high strength and excellent fire resistance.

Description

technical field [0001] The invention relates to the technical field of polymer materials, in particular to a high-strength flame-retardant ABS alloy material and a preparation method thereof. Background technique [0002] ABS (acrylonitrile-butadiene-styrene) material has excellent chemical resistance, mechanical properties and excellent processing performance, so it is widely used in automobiles, home appliances, aviation, ships and other industries. With the continuous demand of products for materials, modified ABS is also appearing more and more in the market. ABS is one of the five major synthetic resin materials. It has excellent impact resistance, heat resistance, low temperature resistance, chemical resistance and electrical properties. It also has the advantages of easy processing, stable product size, and good surface gloss. It is easy to paint. It can also be used for secondary processing such as surface metal spraying, electroplating, welding, hot pressing and bo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L55/02C08L69/00C08L35/06C08L27/18C08L75/08C08L53/02C08K13/02C08K3/22C08K5/03C08K7/26
CPCC08L55/02C08L69/00C08L2201/02C08L2201/08C08L2205/035C08L2205/08C08L35/06C08L27/18C08K13/02C08K3/2279C08K5/03C08L75/08C08K13/06C08K7/26C08L53/02
Inventor 王晓群陈家锋黄珂伟肖敏
Owner 杭州金州高分子科技有限公司
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