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Regeneration method for activated carbon or carbon-based catalyst

A carbon-based catalyst, activated carbon technology, applied in catalyst regeneration/reactivation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problem of selective biodegradation, high investment and operating costs, secondary environmental pollution, etc. problems, to achieve the effect of short regeneration time, low investment and operation cost, and protection of the ecological environment

Inactive Publication Date: 2018-11-30
CHENGDU EN SHAIN TECH INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The physical method has high regeneration efficiency and a wide range of applications, but it consumes a lot of energy in regeneration, and the investment and operating costs are high; the biological regeneration method uses domesticated bacteria to analyze the organic matter adsorbed on activated carbon and carbon-based catalysts, and further digest and decompose them. The biological process is simple and easy, with low investment and operating costs, but it takes a long time, is greatly affected by water quality and temperature, has low efficiency, and the biodegradation is selective and incomplete; chemical cleaning methods often A large amount of acid, alkali or organic solvent is required. The essence of activation is to transfer pollutants to the cleaning agent without completely eliminating them, causing secondary pollution to the environment

Method used

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  • Regeneration method for activated carbon or carbon-based catalyst

Examples

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Effect test

Embodiment 1

[0040] Take 50g of saturated coconut shell activated carbon, and measure its methylene blue value to be 130; soak it in 100mL water, add NaOH to adjust the pH to be greater than 12, aerate with an appropriate amount of ozone, and adjust the ventilation to make coconut shell activated carbon in the form of a fluidized bed Float up and down in the water, stop the aeration after keeping the reaction for 2 hours, take out the coconut shell activated carbon and wash it clean, measure its methylene blue value to 226, calculate the activation rate to be 74%, and achieve the activation effect.

Embodiment 2

[0042] Take 50g of the carbon-based catalyst after repeated use, measure its initial COD removal capacity of 55.39% for the test water with COD=594mg / L, then soak it in 100mL water, add NaOH to adjust the pH to greater than 12, and aerate with an appropriate amount of ozone to adjust the ventilation Make the carbon-based catalyst float up and down in the water in the form of a fluidized bed, stop the aeration after the reaction residence time is 1h, take out the carbon-based catalyst and rinse it clean, and the activated carbon-based catalyst is used to catalyze the ozone oxidation of COD=594mg / L Test water, the COD removal rates measured by multiple parallel tests are: 85.86%, 84.85%, 90.57%, 88.89%, 90.07%. Average value = 88.5mg / L, the COD removal rate of the tested water sample was increased from 55.39% to 88.5% under the action of the catalyst, which proves that the catalyst activity has been significantly improved.

[0043] Regeneration and activation mechanism of activa...

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Abstract

The invention discloses a regeneration method for activated carbon or a carbon-based catalyst. The method comprises the following steps that the methylene blue value of inactivated activated carbon ismeasured, or ozone degradation is catalyzed by a carbon-based catalyst to decrease the COD (chemical oxygen demand), and the removal rate of COD (chemical oxygen demand) is measured; the inactivatedactivated carbon or the carbon-based catalyst is soaked into a NaOH solution; ozone is introduced into the NaOH solution; the activated carbon or the carbon-based catalyst is taken out from the NaOH solution and is washed thoroughly with clean water, and then dehydrating and drying are carried out so as to obtain the regenerated activated carbon or the regenerated carbon-based catalyst; and the methylene blue value of the obtained regenerated activated carbon is measured and is compared with the original measured methylene blue value, the activation effect of the activated carbon is evaluated,or ozone degradation is catalyzed by the obtained regenerated carbon-based catalyst to decrease the COD (chemical oxygen demand), the removal rate of the COD (chemical oxygen demand) is measured andis compared with the original measured removal rate of the COD (chemical oxygen demand), and the activation effect of the carbon-based catalyst is evaluated. The method has the advantages of being good in activation effect, short in time and high in activation efficiency.

Description

technical field [0001] The invention relates to the field of chemical industry and environmental protection, in particular to a method for regenerating activated carbon or carbon-based catalysts. Background technique [0002] Activated carbon or carbon-based catalysts are widely used in environmental protection and have achieved considerable results. However, activated carbon needs to be replaced after adsorption saturation or catalytic deactivation of carbon-based catalysts. A large number of replaced activated carbon or carbon-based catalysts are treated by physical desorption or chemical means. Afterwards, the activity can be restored and reused. [0003] Existing regeneration technologies usually include: physical regeneration, biological regeneration, chemical cleaning, etc. [0004] Among them, high-temperature steam desorption and high-temperature rotary kiln secondary roasting are most commonly used, and the activation temperature is greater than 800°C. The physica...

Claims

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Application Information

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IPC IPC(8): B01J38/02B01J38/64B01J20/34B01J20/20
CPCB01J20/3416B01J20/3475B01J20/3483B01J38/02B01J38/64
Inventor 贾巧冯海波杨敏吴华
Owner CHENGDU EN SHAIN TECH INC
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