Iron-doped diamond dilute magnetic semiconductor and preparation method thereof
A technology of dilute magnetic semiconductor and diamond, applied in the field of iron-doped diamond and its preparation, can solve the problems of sensitive growth parameters, complex diamond growth conditions, etc., and achieves the effects of low deposition pressure, adjustable microwave power, and accelerated deposition
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Embodiment 1
[0030] A method for preparing an iron-doped diamond dilute magnetic semiconductor, the specific steps are as follows:
[0031] 1) Substrate pretreatment: use diamond suspension to ultrasonically clean the substrate (silicon wafer) to increase the surface energy of the substrate and facilitate diamond nucleation;
[0032] 2) Preparation of precursor solution: Iron acetylacetonate was used as iron source, absolute ethanol was used as carbon source, and 0.1 g of iron acetylacetonate was dissolved in 400 ml of absolute ethanol in a conical flask to obtain a precursor solution;
[0033] 3) Device preparation: In the deposition chamber of the microwave plasma chemical vapor deposition device, place the silicon wafer at the center above the substrate stage, vacuum the chamber (to a vacuum degree of 10-100Pa), and pass through the chamber to Inject hydrogen, adjust the microwave power and the pressure in the vacuum chamber, and excite and generate plasma. The process parameters used a...
Embodiment 2
[0038] A method for preparing an iron-doped diamond dilute magnetic semiconductor, the specific steps are as follows:
[0039]1) Substrate pretreatment: use diamond suspension to ultrasonically clean the substrate (silicon wafer) to increase the surface energy of the substrate and facilitate diamond nucleation;
[0040] 2) Preparation of precursor solution: Iron acetylacetonate was used as iron source, absolute ethanol was used as carbon source, and 0.2 g of iron acetylacetonate was dissolved in 400 ml of absolute ethanol in the Erlenmeyer flask to obtain a precursor solution;
[0041] 3) Device preparation: In the deposition chamber of the microwave plasma chemical vapor deposition device, place the silicon wafer at the center above the substrate stage, vacuum the chamber (to a vacuum degree of 10-100Pa), and pass through the chamber to Inject hydrogen, adjust the microwave power and the pressure in the vacuum chamber, and excite and generate plasma. The process parameters us...
Embodiment 3
[0046] A method for preparing an iron-doped diamond dilute magnetic semiconductor, the specific steps are as follows:
[0047] 1) Substrate pretreatment: use diamond suspension to ultrasonically clean the substrate (silicon wafer) to increase the surface energy of the substrate and facilitate diamond nucleation;
[0048] 2) Preparation of precursor solution: Iron acetylacetonate was used as iron source, absolute ethanol was used as carbon source, and 0.2 g of iron acetylacetonate was dissolved in 400 ml of absolute ethanol in the Erlenmeyer flask to obtain a precursor solution;
[0049] 3) Device preparation: In the deposition chamber of the microwave plasma chemical vapor deposition device, place the silicon wafer at the center above the substrate stage, vacuum the chamber (to a vacuum degree of 10-100Pa), and pass through the chamber to Inject hydrogen, adjust the microwave power and the pressure in the vacuum chamber, and excite and generate plasma. The process parameters u...
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