A kind of waterborne acrylic resin antistatic coating and preparation method thereof

A water-based acrylic and acrylic resin technology, which is applied in conductive coatings, fireproof coatings, polyurea/polyurethane coatings, etc., can solve problems such as unsatisfactory research results, immature theory of modified conductive fillers and polymers, etc.

Active Publication Date: 2020-10-23
广东鑫皇冠新材料有限公司
View PDF5 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

How to reduce resistivity and improve thermal-oxidative aging performance is an important research content in this field, but the theory of modified conductive fillers and polymers is relatively immature, and the research results are not satisfactory

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of waterborne acrylic resin antistatic coating and preparation method thereof
  • A kind of waterborne acrylic resin antistatic coating and preparation method thereof
  • A kind of waterborne acrylic resin antistatic coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Present embodiment proposes a kind of waterborne acrylic resin antistatic coating, and described coating comprises following component by weight percentage:

[0021]

[0022] The modified acrylic resin is formed by reacting methacrylic acid, ethyl acrylate, butyl acrylate, n-butanol and modified substances under the action of an initiator. The modified substance is organosilicon and epoxy resin, the organosilicon is acryltrimethoxysilane, and the epoxy resin can be selected from E-51, E-44, E-20 and E-12. The initiator is azobisisobutyronitrile or benzoyl peroxide. In the present invention, the modified acrylic resin adopts a free radical polymerization mechanism. First, the α-H atom on the ortho-carbon of the acid bond in the epoxy resin and the H atom on the tertiary carbon atom are relatively active. Under the action, free radicals are formed, and monomer free radicals are also present at the same time; organosilicon monomers containing double bonds and acrylic a...

Embodiment 2

[0036] On the basis of embodiment 1, the present embodiment proposes a kind of waterborne acrylic resin antistatic coating, increases copper powder on the raw material component, and described coating comprises following component by weight percentage:

[0037]

[0038]

[0039] Present embodiment also provides a kind of preparation method of waterborne acrylic resin antistatic paint, comprises the following steps:

[0040] (1) each component is taken by weight, for subsequent use;

[0041] (2) Add deionized water, thickener, a little dispersant and defoamer to the prepared graphene, mix and stir, ultrasonicate for 1.5h at a power of 375W, and then centrifugally mix at 5500 rpm 55min, then continue to add dispersant, continue ultrasonication for 1.5h, centrifuge and mix for 55min, repeat 4-5 times to obtain a mixed dispersion.

[0042] (3) After the mixture obtained in step (2) is left to stand until the foam completely disappears, add modified acrylic resin and polyure...

Embodiment 3

[0045] On the basis of embodiment 1, the present embodiment proposes a kind of waterborne acrylic resin antistatic coating, and described coating comprises following component by weight percentage:

[0046]

[0047]

[0048] Present embodiment also provides a kind of preparation method of waterborne acrylic resin antistatic paint, comprises the following steps:

[0049] (1) each component is taken by weight, for subsequent use;

[0050] (2) Add deionized water, thickener, a little dispersant and defoamer to the prepared graphene, mix and stir, ultrasonicate for 2h at a power of 350W, and then centrifuge and mix at 5000 rpm for 60min , and then continue to add the dispersant, continue to sonicate for 2h, centrifuge and mix for 60min, repeat 4-5 times to obtain a mixed dispersion.

[0051] (3) After the mixture obtained in step (2) is left to stand until the foam completely disappears, add modified acrylic resin and polyurethane to the mixed dispersion, heat to 70°C, and ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses an aqueous acrylic resin antistatic paint and a preparation method thereof. The paint comprises the following components by weight percentage: 40 to 60 parts of modified acrylic resin, 5 to 15 parts of graphene, 10 to 20 parts of polyurethane, 10 to 30 parts of deionized water, 3 to 5 parts of a thickener, 3 to 5 parts of a dispersant, and 3 to 5 parts of a defoamer. Through organosilicon and epoxy resin modified acrylic resin, the solvent resistance, high and low temperature resistance, and oxidative aging resistance of acrylic resin can be greatly improved, the raw material matrix for preparing the antistatic paint is excellent and stable, after mixing with the graphene to prepare the paint, no agglomeration occurs, the stability is higher, the electrical conductivity is better, and the excellent characteristics of the polymer are maintained, the paint also has the conductive properties of graphene, has good anti-oxidation aging performance, and has the advantages of high efficiency, energy saving, environmental protection and no pollution.

Description

technical field [0001] The invention relates to the field of coatings, in particular to a water-based acrylic resin antistatic coating and a preparation method thereof. Background technique [0002] In daily life, many materials are prone to static electricity accumulation during use, resulting in vacuuming, electric shocks, etc. leading to vicious accidents, such as static electricity can cause production obstacles, explosions, and fires. In order to eliminate the harm caused by static electricity, the preparation of antistatic coatings has become a research hotspot, and antistatic coatings are becoming more and more popular in daily life. How to reduce resistivity and improve thermal-oxidative aging performance is an important research content in this field, but the theory of modifying conductive fillers and polymers is relatively immature, and the research results are not satisfactory. Contents of the invention [0003] For the technical problems existing in the prior ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Patents(China)
IPC IPC(8): C09D151/08C09D175/04C09D5/24C09D5/38
CPCC08K2003/085C08L2201/08C08L2205/035C09D5/18C09D5/24C09D5/38C09D151/08C08L75/04C08K3/042C08K3/08
Inventor 谭贺洵申国辉陆卫尧
Owner 广东鑫皇冠新材料有限公司
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap