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Organic electroluminescent element

A luminescent, organic field technology, applied in the field of organic electroluminescent components

Inactive Publication Date: 2018-12-21
NIPPON STEEL CHEMICALL &MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Patent Document 8 discloses the use of a specific carborane compound as a delayed fluorescent light-emitting material, or the use of biscarbazole compounds as a delayed fluorescent light-emitting material and the use of a carborane compound as a host material in the light-emitting layer, but does not teach Mixing a carborane compound with a specific carbazole compound and using it as a host material for organic layers other than the light-emitting layer and light-emitting layers

Method used

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Examples

Experimental program
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Effect test

Embodiment 1

[0136]On a glass substrate on which an anode made of indium tin oxide (ITO) with a film thickness of 70 nm was formed, a vacuum deposition method was used to obtain a vacuum of 2.0×10 -5 Pa laminates each film. First, on ITO, copper phthalocyanine (CuPC) was formed to a thickness of 30 nm as a hole injection layer. Next, 4,4-bis[N-(1-naphthyl)-N-phenylamino]biphenyl (NPB) was formed as a hole transport layer with a thickness of 15 nm. Next, as the light-emitting layer, compound 1-2 as the first host, compound 2-1 as the second host, and iridium complex [bis(4,6-difluorobenzene] which is a blue phosphorescent material as the guest of the light-emitting layer base)-pyridine-N,C2']iridium picolinate(III)](FIrpic) was co-evaporated from different evaporation sources to form a light-emitting layer with a thickness of 30 nm. At this time, the vapor deposition rate ratio (wt ratio) of the first body, the second body, and FIrpic was 47:47:6. Next, Alq is formed with a thickness of ...

Embodiment 2~21

[0139] In Example 1, organic EL elements (Examples 2 to 7) were produced in the same manner as in Example 1, except that the compounds described in Table 1 were used as the first host of the light-emitting layer.

[0140] In addition, organic EL elements (Examples 8 to 21) were produced in the same manner as in Examples 1 to 7, except that Compounds 2-18 and 2-29 were used as the second host of the light-emitting layer.

[0141] When an external power source was connected to the obtained organic EL element and a DC voltage was applied, an emission spectrum with a maximum wavelength of 475 nm was observed from any organic EL element, and it was found that light emission from FIrpic was obtained. Table 1 shows the characteristics of the produced organic EL elements.

Embodiment 22

[0151] On a glass substrate on which an anode made of ITO with a film thickness of 150 nm was formed, a vacuum degree of 4.0×10 was carried out by a vacuum deposition method. -4 Pa laminates each film. First, CuPc was formed as a hole injection layer with a thickness of 20 nm on ITO, and then NPB was formed as a hole transport layer with a thickness of 20 nm. Next, as the light-emitting layer, compound 1-2 as the first host, compound 2-1 as the second host, and tris(2-phenylpyridine)iridium(III)(Ir(PPy) as the guest of the light-emitting layer 3 ) were co-evaporated from different evaporation sources, and formed with a thickness of 30 nm. At this time, the first body, the second body and Ir(PPy) 3 The evaporation rate ratio of 47:47:6. Next, bis(2-methyl-8-hydroxyquinoline)4-phenylphenolaluminum(III)(BAlq) was formed as a hole blocking layer with a thickness of 10 nm. Next, Alq was formed with a thickness of 40 nm 3 as an electron transport layer. Further, LiF was formed...

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PUM

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Abstract

The purpose of the present invention is to provide an organic EL element which exhibits high driving stability and high luminous efficiency at a low voltage. Provided is an organic electroluminescentelement in which an anode, organic layers and a cathode are laminated on a substrate, wherein a biscarbazole compound (i) represented by general formula (1) and a carborane compound (ii) having one ormore carborane rings and an aromatic group bonded to the carborane ring(s) are contained in at least one of the organic layers. Here, R and R' each denote a hydrogen atom, an aromatic hydrocarbon group, a heterocyclic group, an alkyl group, or the like, m is a number between 1 and 6, and X1 to X3 are each N, C-R' or C-.

Description

technical field [0001] The present invention relates to an organic electroluminescence element (hereinafter, referred to as an organic EL element), and more specifically, to an organic EL element having an organic layer containing a plurality of compounds. Background technique [0002] By applying a voltage to the organic EL element, holes are injected into the light-emitting layer from the anode, and electrons are injected into the light-emitting layer from the cathode, respectively. Furthermore, in the light-emitting layer, the injected holes and electrons recombine to generate excitons. At this time, according to the statistical law of electron spin, singlet excitons and triplet excitons are generated in a ratio of 1:3. It can be said that the internal quantum efficiency has a limit of 25% using a fluorescent light-emitting organic EL element that emits light based on singlet excitons. On the other hand, it is known that a phosphorescent light-emitting type organic EL e...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/50
CPCH10K85/322H10K85/654H10K85/6572H10K50/18H10K50/11H10K2101/10H10K2101/90H10K50/12H10K85/615H10K85/6574H10K85/6576H10K50/15H10K50/16H10K50/171H10K85/342H10K85/344H10K85/346H10K85/348H10K85/371
Inventor 小川淳也池永裕士上田季子多田匡志
Owner NIPPON STEEL CHEMICALL &MATERIAL CO LTD
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