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Photocatalytic reaction gel membrane

A technology of photocatalytic reaction and gel film, applied in the direction of physical/chemical process catalyst, organic compound/hydride/coordination complex catalyst, chemical instrument and method, etc. problems, to achieve the effect of reducing blocking effect, good light transmission, and maximizing the lighting effect

Inactive Publication Date: 2019-01-04
DONGHUA UNIV
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Using ultraviolet light as the excitation light source, the TiO 2 The photogenerated electrons on the photoanode surface of the membrane turntable are transferred to the cathode surface of the turntable, and the photogenerated electrons react with the saturated dissolved oxygen on the cathode turntable surface to generate H 2 o 2 , the indirect oxidation of organic matter and TiO 2 The photogenerated holes on the surface of the film photoanode rotating disk directly oxidize the organic matter, which improves the degradation efficiency. The rotation of the rotating disk accelerates the exchange and renewal of the electrode surface and the main solution. 2 When the turntable rotates quickly, it is easy to fall off, and the TiO 2 It has a certain hindering effect on light, which hinders its further promotion and application

Method used

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Effect test

Embodiment 1

[0034] A photocatalytic reaction gel film, such as figure 1 As shown, it is mainly composed of a polymer hydrogel film with a water absorption rate of 92% and a photocatalytic reaction system. The content of the photocatalytic reaction system in the photocatalytic reaction gel film is 2.47wt%, and the polymer hydrogel film contains adsorption site, the adsorption site adsorbs the photocatalytic reaction system and fixes it in the pores, and the polymer hydrogel film contains non-strongly adsorbed polar groups-COO - ,-COO -A non-strongly adsorbed polar group area is formed, in which the polymer hydrogel film is made of sodium alginate, and the photocatalytic reaction system is mainly composed of nano-silver and free alkyl chains of ammonium oleate complexes and adsorbed on nano- The alkyl chains of the ammonium oleate complexes on the silver surface are interpenetrated to form a coating layer. The coating layer is wrapped on the surface of nano-silver. The average particle siz...

Embodiment 2

[0036] A photocatalytic reaction gel film, mainly composed of a polymer hydrogel film with a water absorption rate of 91% and a photocatalytic reaction system, the content of the photocatalytic reaction system in the photocatalytic reaction gel film is 2.40wt%, and the polymer water The gel film contains adsorption sites, which absorb the photocatalytic reaction system and fix it in the pores. The polymer hydrogel film contains non-strongly adsorbed polar groups-COO - ,-COO - A non-strongly adsorbed polar group region is formed, in which the polymer hydrogel film is made of potassium alginate, and the photocatalytic reaction system is mainly composed of nano-silver and the alkyl chain of free ammonium oleate complex and adsorbed on the nano- The alkyl chains of ammonium oleate complexes on the silver surface are interpenetrated to form a coating layer, the coating layer is wrapped on the surface of nano-silver, the average particle size of nano-silver is 9nm, and the surface o...

Embodiment 3

[0038] A photocatalytic reaction gel film, mainly composed of a polymer hydrogel film with a water absorption rate of 90% and a photocatalytic reaction system, the content of the photocatalytic reaction system in the photocatalytic reaction gel film is 2.38wt%, and the polymer water The gel film contains adsorption sites, which absorb the photocatalytic reaction system and fix it in the pores. The polymer hydrogel film contains non-strongly adsorbed polar groups-COO - ,-COO - A non-strongly adsorbed polar group region is formed; among them, the polymer hydrogel film is made of sodium carboxymethyl cellulose, and the photocatalytic reaction system is mainly composed of nano-silver and free ammonium oleate complexes with alkyl chains and The alkyl chains of the ammonium oleate complex adsorbed on the surface of nano-silver are interpenetrated to form a wrapping layer. The wrapping layer is wrapped on the surface of nano-silver. The average particle size of nano-silver is 18nm. T...

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Abstract

The invention relates to a photocatalytic reaction gel membrane. The gel membrane comprises a photocatalytic reaction site and a polar group, an area in the periphery of the photocatalytic reaction site is a strong adsorption polar group area, an area outside the strong adsorption polar group area is a non-strong adsorption polar group area, and charges of the strong adsorption polar group area and non-strong adsorption polar group area are both positive or negative; the potential of the strong adsorption polar group area is higher than that of the non-strong adsorption polar group area, and the strong adsorption polar group area is composed of strong adsorption polar groups or formed by gathering weak adsorption polar groups, wherein the weak adsorption polar groups and the polar groups of the non-strong adsorption polar group areas are the same polar groups. The photocatalytic reaction gel membrane can be reused and has high catalytic efficiency and low energy consumption, a supported catalyst is unlikely to fall off, and a high industrial popularization value is achieved.

Description

technical field [0001] The invention belongs to the field of polymer composite materials and relates to a photocatalytic reaction gel film. Background technique [0002] In recent years, with the rapid development of my country's economy and the continuous growth of population, a large number of pollutants have been discharged into surface water ecosystems such as rivers and lakes, resulting in the destruction of the ecological environment of the river basin and seriously restricting the sustainable development of the economy and society. affect people's quality of life. Sewage treatment technology and its engineering application have become an essential part of maintaining sustainable social and economic development. Various sewage treatment processes based on physical, chemical and biological principles continue to emerge. For organic industrial wastewater with high toxicity and refractory biodegradation, photocatalytic degradation technology based on chemical principles h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J35/02B01J31/06B01J31/26B01J31/38C02F1/30C02F101/30
CPCC02F1/30B01J31/06B01J31/26B01J31/38C02F2101/30C02F2305/10B01J35/59B01J35/39
Inventor 孙宾纪晓寰朱美芳曾婷江晓泽胡余宗
Owner DONGHUA UNIV
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