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Cold-resistant acrylic emulsion leather auxiliary agent and preparation method thereof

An acrylic emulsion and leather technology, which is applied in leather surface treatment, small raw hide/big raw hide/leather/fur treatment, small raw hide/large raw hide/leather skin/fur chemical treatment, etc. To solve problems such as twists and turns, to achieve the effect of improving gloss, good cold resistance, twists and turns, and excellent hand feeling

Inactive Publication Date: 2019-01-04
广州麦吉高分子新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, the main component of leather auxiliaries is mostly acrylic emulsion. After the acrylic emulsion on the market is formed into a film, it can be used normally at room temperature without any problem. It is easy to cause the coating to break when wearing it.

Method used

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  • Cold-resistant acrylic emulsion leather auxiliary agent and preparation method thereof

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Effect test

Embodiment 1

[0026] A kind of cold-resistant acrylic emulsion leather auxiliary agent, the components of the leather auxiliary agent and the parts by weight of each component are: 1000 parts of butyl acrylate, 1 part of isooctyl acrylate, 1 part of methyl methacrylate, ethyl acrylate 120 parts, 2400 parts of water, 20 parts of ammonia water, 20 parts of lauryl sulfate, 1 part of preservative, 0.1 part of persulfate, 0.1 part of sodium hydrosulfite, 0.1 part of tert-butyl hydroperoxide, 20 parts of zinc oxide. Zinc oxide is nanoscale. Preservatives are commonly used preservatives, for example: kathon LX150 and the like.

Embodiment 2

[0028] A cold-resistant acrylic emulsion leather auxiliary, the components of the leather auxiliary and the parts by weight of each component are: 1300 parts of butyl acrylate, 150 parts of isooctyl acrylate, 1 part of acrylic acid, 50 parts of ethyl acrylate, water 2800 parts, 30 parts of sodium hydroxide solution, 30 parts of sodium dodecylbenzenesulfonate, 10 parts of preservatives, 5 parts of azobisisobutyronitrile, 2 parts of sodium hydroxide, 2 parts of tert-butyl hydroperoxide, oxidation 30 parts of zinc.

Embodiment 3

[0030] A cold-resistant acrylic emulsion leather auxiliary agent, the components of the leather auxiliary agent and the parts by weight of each component are: 1500 parts of butyl acrylate, 150 parts of methyl methacrylate, 50 parts of acrylic acid, 10 parts of ethyl acrylate, 3500 parts of water, 50 parts of ammonia water, 60 parts of lauryl sulfate, 25 parts of preservatives, 10 parts of persulfate, 0.1-10 parts of sodium hydrosulfite, 8 parts of tert-butyl hydroperoxide, and 35 parts of zinc oxide.

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Abstract

The invention relates to a cold-resistant acrylic emulsion leather auxiliary agent and a preparation method thereof, and relates to the technical field of leather auxiliary agents. The leather auxiliary agent is prepared from, by weight, 1,000-2,360 parts of mixed monomers, 0-375 parts of polymerized monomers, 2,400-3,500 parts of water, 20-50 parts of alkali liquor, 20-60 parts of emulsifier, 0-30 parts of preservative, 0.1-10 parts of initiator, 0.1-10 parts of sodium dithionite, 0.1-10 parts of tert-butyl hydroperoxide and 20-40 parts of zinc oxide. The invention further provides the preparation method of the leather auxiliary agent. The leather auxiliary agent prepared by means of the preparation method has good cold and bending resistance, leather treated by the leather auxiliary agent has the advantages that the glossiness, gloss retention performance, plasticity, dry rub resistance, wet rub resistance, flexibility and water resistance of the leather are improved, and the treatedleather can keep excellent hand feeling. In addition, the preparation method is simple, easy to operate, stable in process and suitable for mass industrial production.

Description

Technical field: [0001] The invention relates to the technical field of leather auxiliary agents, in particular to a cold-resistant acrylic emulsion leather auxiliary agent and a preparation method thereof. Background technique: [0002] Leather auxiliaries are mainly used for leather modification, especially in the process of polishing and ironing of various front leathers and buffed leathers. Leather auxiliaries can firmly bond the coating to the leather surface and improve High-temperature ironing resistance of leather, and leather auxiliaries must keep leather products in a stable state and excellent characteristics in various environments. [0003] At present, the main component of leather auxiliaries is mostly acrylic emulsion. After the acrylic emulsion on the market is formed into a film, it can be used normally at room temperature without any problem. That is, when wearing and using, the coating is prone to breakage. After several experiments, the present inventio...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/08C09D7/61C09D7/20C08F220/18C08F220/14C14C11/00
CPCC08F220/18C08F220/1804C08K2003/2296C08K2201/011C09D7/20C09D7/61C09D133/08C14C11/003C08K3/22C08F220/1808C08F220/14
Inventor 马峰代春梅王德勇柯有智丁承先
Owner 广州麦吉高分子新材料科技有限公司
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