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Metal material containing vanadium carbide coating as well as preparation method and application thereof

A technology of vanadium carbide cladding and metal materials, which is applied in the field of metal materials containing vanadium carbide cladding and its preparation, and can solve the problems of tensile damage resistance, high wear resistance, mold manufacturing cost and manufacturing cost of carbide cladding. Increased difficulty, peeling and other problems, to achieve the effect of solving the problem of surface strain, improving service life, and high resistance to strain

Inactive Publication Date: 2019-01-04
CHANGSHA TOPWELLWEAR METAL MATERIAL SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the ever-increasing number of occasions where the use conditions are more severe, such as the high-strength steel plates with increasingly higher sheet strength in the automotive industry and the forming dies of high-strength thick sheets in the heavy-duty truck industry, the TD method is used for vanadium carbide coating treatment. Unable to achieve a satisfactory use effect, the specific performance is that the vanadium carbide coating is easy to peel off when it is used for less than 2000 strokes, and some even only a few tens of strokes, and the carbide coating cannot exert the tensile and high wear resistance. Advantage
Deep drawing mold materials are generally made of high-chromium cold-working die steel. The hardness after heat treatment is generally only about HRC60, which is difficult to further improve. If high-speed steel with higher hardness is used, although the hardness can be increased to HRC63-67, However, the mold manufacturing cost and manufacturing difficulty will increase significantly

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] This embodiment provides a method for preparing a metal material containing a vanadium carbide coating, which specifically includes the following steps:

[0031] (1) Polish the working surface of the Cr12MoV mold insert so that the surface roughness Ra is lower than 0.4, and wipe the entire surface of the workpiece with alcohol;

[0032] (2) Carry out single-phase salt-bath boronizing treatment to the mold insert surface after step (1) polishing, contain 80% borax and 20% silicon carbide in the salt bath, treatment temperature 960 ℃, heat preservation 10h, come out of the furnace and air-cool, After cleaning the residual salt on the workpiece, grind and polish the working surface to make the metal surface roughness less than 0.4;

[0033] (3) Carry out molten salt vanadium infiltration on the boronizing surface after step (2), the used salt of molten salt vanadium infiltration is borax molten salt, comprising: borax 85%, vanadium pentoxide 10%, aluminum powder 5%, The ...

Embodiment 2

[0036] This embodiment provides a method for preparing a metal material containing a vanadium carbide coating, which specifically includes the following steps:

[0037] (1) Polish the working surface of the Cr12MoV mold insert so that the surface roughness Ra is lower than 0.4, and wipe the entire surface of the workpiece with alcohol;

[0038] (2) Carry out single-phase powder boxing boronizing treatment on the surface of the mold insert after step (1) polishing, the powder formula is: 95% silicon carbide, 2% potassium fluoroborate, 3% boron carbide, and the treatment temperature is 900 ° C. Keep warm for 8 hours, cool down to room temperature with the furnace, and polish the working surface after leaving the furnace to make the metal surface roughness less than 0.4;

[0039] (3) Carry out molten salt vanadium infiltration on the boronizing surface after step (2), the used salt of molten salt vanadium infiltration is borax molten salt, comprising: borax 85%, vanadium pentoxid...

Embodiment 3

[0042] This embodiment provides a method for preparing a metal material containing a vanadium carbide coating, which specifically includes the following steps:

[0043] (1) Polish the working surface of the Cr12MoV mold insert so that the surface roughness Ra is lower than 0.4, and wipe the entire surface of the workpiece with alcohol;

[0044] (2) Carry out single-phase salt bath boronizing treatment to the mold insert surface after step (1) polishing, contain 80% borax and 20% silicon carbide in the salt bath, treatment temperature 1050 ℃, insulation 10h, take out the furnace and air-cool, After cleaning the residual salt on the workpiece, grind and polish the working surface so that the metal surface roughness Ra is lower than 0.4;

[0045] (3) Carry out molten salt vanadium infiltration on the boronizing surface after step (2), the used salt of molten salt vanadium infiltration is borax molten salt, comprising: borax 85%, vanadium pentoxide 10%, aluminum powder 5%, The trea...

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PUM

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Abstract

The invention provides a metal material containing a vanadium carbide coating which comprises a base metal, a vanadium carbide coating and a boronizing layer located between the base metal and the vanadium carbide coating, wherein the vanadium carbide coating has the thickness of 5-15 [mu]m, the boronizing layer is single-phase iron boride, the boronizing layer has the thickness of 30-200 [mu]m, and the base metal is steel with the carbon content being 0.3% or more than 0.3%. The invention further provides a preparation method of the metal material containing the vanadium carbide coating. Thesurface hardened layer of an alloy prepared with the method provided by the invention has an outmost surface layer being the vanadium carbide coating which is extremely high in tensile strength and high in wear resistance, a subsurface hardened layer is relatively thick and the hardness of the subsurface hardened layer is much higher than that of a base material; the surface hardened layer structure enables the outermost surface layer of the vanadium carbide coating to withstand greater compressive stress without being damaged or peeled off, thereby exerting the performance characteristics ofthe vanadium carbide coating, effectively solving the problem of surface strain of heavy load pull-down deep forming molds or mechanical parts, and greatly prolonging the service life of the heavy load pull-down deep forming molds or the mechanical parts.

Description

technical field [0001] The invention belongs to the technical field of metal materials, and in particular relates to a metal material containing a vanadium carbide coating and a preparation method and application thereof. Background technique [0002] When steel materials are drawn, bent, flanged and rolled, it is easy for the mold to scratch the surface of the workpiece. There are many ways to solve this problem, such as changing the mold material, using hard alloy, and using beryllium copper alloy as the mold ; Add suitable drawing oil or plastic film between the mold and the forming sheet; or carry out phosphating treatment on the forming sheet; carry out surface treatment on the mold. The above methods are applied in different occasions, especially the surface treatment of the mold is economical and effective. [0003] Chemical heat treatment of steel parts is an effective method to greatly improve their properties such as wear resistance, corrosion resistance and fatig...

Claims

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Application Information

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IPC IPC(8): C23C12/00C21D1/18C23F17/00
CPCC21D1/18C23C12/00C23F17/00
Inventor 彭智虎
Owner CHANGSHA TOPWELLWEAR METAL MATERIAL SCI
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