Film with high tensile strength and production method

A high-tensile, thin-film technology, used in chemical instruments and methods, layered products, synthetic resin layered products, etc., can solve problems such as irregularities in items, mechanical properties, film breakage, and inability to use normally. Tensile effect, increased tensile strength, good tensile effect

Active Publication Date: 2019-01-11
NINGBO HONGYAN PACKING MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

For example, the Chinese patent application number CN201310637906.X discloses a high-tensile plastic film, which adopts a three-layer structure, in which the middle grid-like reinforcement layer is made of carbon fibers and cotton fibers interwoven through warp and weft threads, so as to achieve high tensile strength. For the purpose of tensile strength, this patent uses carbon fiber and cotton fiber as the reinforcing layer material. When it is applied to special occasions such as irregular objects and many water chestnuts, it is easy to cause problems such as local fiber breakage and puncture, and because the materials of the fiber and the film layer are different. , resulting in insufficient bonding force, and the difference in mechanical properties will cause the film to break and cannot be used normally
The Chinese patent application number CN201110367058.6 discloses a barrier biaxially stretched polylactic acid composite film and its preparation method. The patented film consists of two polylactic acid layers and a barrier layer between the two polylactic acid layers. , good biodegradability, but the tensile film made of this material has a brittle texture and poor processing performance, and it also cannot meet the packaging needs of special occasions such as irregular items and many water chestnuts.

Method used

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  • Film with high tensile strength and production method

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Starting from the film cross section and going from outside to inside include:

[0036] The first layer is A layer, its composition is metallocene linear low density polyethylene and ethylene modified PET blend modified resin, the melt index is 3.3g / 10min, and the density is 0.93g / cm 3 ; The amount of metallocene polyethylene accounts for 35wt% of the total amount of the blended modified resin; the thickness of the A layer is 10 μm;

[0037] The second layer is B layer, its composition is graphene oxide modified low-density polyethylene, the melt index is 3.0g / 10min, and the density is 0.91g / cm 3 ; The thickness of the B layer is 5 μm; the graphene oxide is hydroxylated graphene, and the hydroxyl content is 15at%;

[0038] The third layer is C layer, its composition is maleic anhydride grafted low-density polyethylene, the melt index is 1.5g / 10min, and the density is 0.89g / cm 3 ; The graft ratio of the maleic anhydride grafted polyethylene is 2.5%; the thickness of th...

Embodiment 2

[0051] Starting from the film cross section and going from outside to inside include:

[0052] The first layer is A layer, its composition is metallocene linear low density polyethylene and ethylene modified PET blend modified resin, the melt index is 3.8g / 10min, and the density is 0.9337g / cm 3 ; The amount of metallocene polyethylene accounts for 40wt% of the total amount of the blended modified resin; the thickness of the A layer is 20 μm;

[0053] The second layer is B layer, its composition is graphene oxide modified low-density polyethylene, the melt index is 3.6g / 10min, and the density is 0.9124g / cm 3 ; The thickness of the B layer is 8 μm; the graphene oxide is hydroxylated graphene, and the hydroxyl content is 20at%;

[0054] The third layer is C layer, its composition is maleic anhydride grafted low-density polyethylene, the melt index is 1.8g / 10min, and the density is 0.8927g / cm 3 ; The graft ratio of the maleic anhydride grafted polyethylene is 4%; the thickness o...

Embodiment 3

[0067] Starting from the film cross section and going from outside to inside include:

[0068] The first layer is layer A, which is composed of metallocene linear low density polyethylene and ethylene-modified PET blend modified resin, with a melt index of 4.6g / 10min and a density of 0.94g / cm 3 ; The amount of metallocene polyethylene accounts for 45wt% of the total amount of the blended modified resin; the thickness of the A layer is 30 μm;

[0069] The second layer is B layer, its composition is graphene oxide modified low-density polyethylene, the melt index is 4.4g / 10min, and the density is 0.92g / cm 3 ; The thickness of the B layer is 10 μm; the graphene oxide is hydroxylated graphene, and the hydroxyl content is 16at%;

[0070] The third layer is C layer, its composition is maleic anhydride grafted low-density polyethylene, the melt index is 2.1g / 10min, and the density is 0.90g / cm 3 The graft ratio of the maleic anhydride grafted polyethylene is 5%; the thickness of the...

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Abstract

The invention relates to a film with high tensile strength. The film is a seven-layer compound film. The film comprises a layer A, a layer B, a layer C, a layer D, a layer E, a layer F and a layer G from outer to inner starting from the cross section of the film, wherein the layer A is composed of a blending modified resin of metallocene polyethylene and ethylene modified PET; the layer B is madefrom graphene oxide modified low-density polyethylene; the layer C is made from maleic anhydride grafted low-density polyethylene; the layer D is made from ultra-high molecular weight polyethylene; the layer E is made from maleic anhydride grafted low-density polyethylene; the layer F is made from graphene oxide modified low-density polyethylene; the layer G is made from polyvinylidene fluoride. Compared with a common film, the film with high tensile strength provided by the invention has higher strength, no spreading of damaged holes, higher surface viscosity and higher tensile strength, so that the film with high tensile strength can be applied to special occasions.

Description

technical field [0001] The invention relates to the field of film technology, in particular to a high tensile film and a production method. Background technique [0002] The types of film include single-layer film, composite film and co-extrusion film. The disadvantages of single-layer film such as low mechanical strength and surface hardness, flammability and poor heat resistance limit its application range, and the market for co-extrusion film is relatively broad. Among them, the multi-layer co-extrusion technology is to use more than 3 extruders to melt and extrude resin materials with different functions, such as PA, PE, PP, etc. Bulge forming, cooling and compounding to make multi-layer composite film. [0003] The film produced by the multi-layer co-extrusion method can well meet the needs of various industrial packaging, and has the incomparable advantages of the dry composite film. By adjusting the thickness of each layer and using a variety of different materials, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B32B27/08B32B27/18B32B27/28B32B27/30B32B27/32B32B27/36B29C69/02B29C48/18B29C48/08B29L7/00B29L9/00B29K23/00B29K27/00
CPCB29K2023/0633B29K2023/0683B29K2027/16B29L2007/00B29L2009/00B32B27/08B32B27/18B32B27/28B32B27/304B32B27/32B32B27/36B32B2250/05B32B2250/24B32B2270/00B32B2307/412B32B2307/54B32B2307/544B32B2307/5825
Inventor 李玉斌
Owner NINGBO HONGYAN PACKING MATERIAL
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