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High temperature resistant optical fiber temperature sensor

An optical fiber temperature and high temperature resistance technology, applied in thermometers, clad optical fibers, and thermometers with physical/chemical changes, etc., can solve the problems of complex manufacturing process of semiconductor diaphragms, high requirements for signal transmission optical fibers, and low measurement accuracy. Achieve excellent up-conversion strength, improve application range, and achieve accurate results

Inactive Publication Date: 2019-01-18
NANJING TONGLI CRYSTAL MATERIALS RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the semiconductor absorption type high temperature resistant optical fiber temperature sensor has high requirements on the signal transmission optical fiber, and usually requires a special large-aperture optical fiber; and because the optical fiber and the semiconductor thin film are indirectly coupled, the optical coupling efficiency is much lower than the direct fusion coupling between the optical fiber and the optical fiber; semiconductor diaphragm production The process is also more complicated, and the process requirements are higher; since the semiconductor absorption is the electronic transition absorption between the conduction band and the valence band, the absorption band is in the short band of the ultraviolet and visible light bands.
Therefore, ultraviolet broadband light sources are required, which are expensive, have high requirements for optical fibers, and have low measurement accuracy, usually only ±1°C

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Multi-doped sapphire laser crystal material Eu 4+ / Lu 3+ / Tb 3+ / Ti 3+ :Al 2 o 3 .

[0026] Among multi-doped sapphire laser crystal materials, Eu 4+ 、Lu 3+ , Tb 3+ The molar ratio of Eu is 3:2:1; the Eu 4+ 、Lu 3+ , Tb 3+ The total number of moles and Ti 3+ :Al 2 o 3 The molar ratio is 3:100.

[0027] The preparation method of described multi-doped sapphire laser crystal material comprises the following steps:

[0028] (1) place the crystal growth mold that the middle part is provided with capillary in the crucible middle part, the raw material Al 2 o 3 、Ti 2 o 3 、Eu 2 o 3 、Lu 2 o 3 , Tb 2 o 3 Placed in a crucible, heating the crucible to melt the raw materials to form a melt;

[0029] (2) Connect the seed crystal to the top of the mold to pull the melt, so that the seed crystal continuously rearranges atoms or molecules at the interface of the melt, and gradually solidifies as the temperature drops to grow a single crystal with the same shape a...

Embodiment 2

[0031] Multi-doped sapphire laser crystal material Eu 4+ / Lu 3+ / Tb 3+ / Ti 3+ :Al 2 o 3 .

[0032] Among multi-doped sapphire laser crystal materials, Eu 4+ 、Lu 3+ , Tb 3+ The molar ratio of Eu is 2:3:1; the Eu 4+ 、Lu 3+ , Tb 3+ The total number of moles and Ti 3+ :Al 2 o 3 The molar ratio is 1:100.

[0033] The preparation method of described multi-doped sapphire laser crystal material comprises the following steps:

[0034](1) place the crystal growth mold that the middle part is provided with capillary in the crucible middle part, the raw material Al 2 O 3 , Ti 2 O 3 , Eu 2 O 3 、Lu 2 O 3 , Tb 2 O 3 Placed in a crucible, heating the crucible to melt the raw materials to form a melt;

[0035] (2) Connect the seed crystal to the top of the mold to pull the melt, so that the seed crystal continuously rearranges atoms or molecules at the interface of the melt, and gradually solidifies as the temperature drops to grow a single crystal with the same shape ...

Embodiment 3

[0037] Multi-doped sapphire laser crystal material Eu 4+ / Lu 3+ / Tb 3+ / Ti 3+ :Al 2 O 3 .

[0038] Among multi-doped sapphire laser crystal materials, Eu 4+ 、Lu 3+ , Tb 3+ The molar ratio of Eu is 4:1:1; the Eu 4+ 、Lu 3+ , Tb 3+ The total number of moles and Ti 3+ :Al 2 O 3 The molar ratio is 5:100.

[0039] The preparation method of described multi-doped sapphire laser crystal material comprises the following steps:

[0040] (1) place the crystal growth mold that the middle part is provided with capillary in the crucible middle part, the raw material Al 2 O 3 , Ti 2 O 3 , Eu 2 O 3 、Lu 2 O 3 , Tb 2 O 3 Placed in a crucible, heating the crucible to melt the raw materials to form a melt;

[0041] (2) Connect the seed crystal to the top of the mold to pull the melt, so that the seed crystal continuously rearranges atoms or molecules at the interface of the melt, and gradually solidifies as the temperature drops to grow a single crystal with the same shape...

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PUM

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Abstract

The invention provides a high temperature resistant optical fiber temperature sensor. The high temperature resistant optical fiber temperature sensor comprises a light source, a light splitter, a reference light path, a sensitive light path, a light power meter and a data processing and storage device, wherein the reference light path and the sensitive light path are connected in parallel, one endof the reference light and one end of the sensitive light path are connected with the light splitter and the light source in sequence, and the other end of the reference light path and the other endof the sensitive light path are connected with the light power meter and the data processing and storage device in sequence; and the reference light path and the sensitive light path are sensitive optical fibers respectively. According to the optical fiber temperature sensor, a multi-doped sapphire crystal material is taken as the sensitive optical fibers, the optical fiber temperature sensor comprises an optical fiber core and a cladding material coated outside the optical fiber core, the preparation technology of the optical fiber core is simple, the optical fiber temperature sensor has excellent absorption characteristic and up-conversion strength, and the application range of the sapphire optical fiber is greatly improved; the cladding material uses doped poly-crystal aluminum oxide and Er3+ multi-component phosphate glass, the cost is low, and the requirement of total reflection can be met; and the sensor is high in detection sensitivity and accurate in result.

Description

technical field [0001] The invention relates to the field of temperature detection equipment, in particular to a high temperature resistant optical fiber temperature sensor. Background technique [0002] Since the advent of optical fiber in the 1970s, with the development of science and technology, many high temperature resistant optical fiber temperature sensors have emerged. Optical fiber has the advantages of small size, light weight, flexible structure, anti-electromagnetic interference, and electrical insulation. At present, high temperature resistant optical fiber temperature sensors mainly include fiber Bragg grating (FBG) temperature sensor, semiconductor absorption high temperature resistant optical fiber temperature sensor and optical fiber Fabry-Perot cavity interferometric temperature sensor, etc. [0003] Among them, the fiber Bragg grating temperature sensor is engraved in the optical fiber through a precise process, so that the refractive index in the optical...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G01K11/32C03C3/17G02B6/02
CPCG01K11/32G01K11/3206G02B6/02C03C3/17
Inventor 沈荣存
Owner NANJING TONGLI CRYSTAL MATERIALS RES INST CO LTD
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