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Synthetic method and application of low-temperature environmentally friendly type flame retardant silicone acrylic electrostatic flocking adhesive

A technology of electrostatic flocking and synthesis method, applied in the direction of adhesive type, ester copolymer adhesive, device for coating liquid on the surface, etc. The problem of poor combustion effect, etc., achieves the effect of good softness and wear resistance

Inactive Publication Date: 2019-02-26
DONGHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the flame retardant effect of the adhesive obtained by mechanical blending is not good, and a large amount of flame retardant is blended into the flocking fabric, causing the fabric to feel hard and the flocking fastness to become poor

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] Step 1: Preparation of Adhesive

[0043] Preparation of core-shell emulsion: the core layer emulsifier fatty alcohol polyoxyethylene ether (AEO-9), deionized water and methyl methacrylate (MMA), ethyl acrylate (EA) and n-butyl acrylate (BA) Add it into a 500mL four-neck flask, ultrasonicate at 55°C for 15min, then raise the temperature to 58°C, stir at 580r / min for 45min to disperse evenly, and obtain the core layer pre-emulsion; the shell layer emulsifier (AEO- 9), deionized water, methyl methacrylate (MMA), ethyl acrylate (EA) and n-butyl acrylate (BA) were added to a 500mL four-necked flask, ultrasonicated at 55°C for 15min, and then heated to 58°C , stirred at 580r / min for 45min to disperse evenly to obtain a shell pre-emulsion.

[0044] Add 0.4 g of ammonium persulfate (APS) to 10 mL of water to configure the initiator solution, separate 5 mL into the syringe pump, and add the core layer pre-emulsion to the dropping funnel (reserve about 1 / 4 in the original flask). ...

Embodiment 2

[0050] Step 1: Preparation of Adhesive

[0051] Preparation of core-shell emulsion: the core layer emulsifier fatty alcohol polyoxyethylene ether (AEO-9), deionized water and methyl methacrylate (MMA), ethyl acrylate (EA) and n-butyl acrylate (BA) Add it into a 500mL four-neck flask, ultrasonicate at 55°C for 15min, then raise the temperature to 58°C, stir at 580r / min for 45min to disperse evenly, and obtain the core layer pre-emulsion; the shell layer emulsifier (AEO- 9), deionized water, methyl methacrylate (MMA), ethyl acrylate (EA) and n-butyl acrylate (BA) were added to a 500mL four-necked flask, ultrasonicated at 55°C for 15min, and then heated to 58°C , stirred at 580r / min for 45min to disperse evenly to obtain a shell pre-emulsion.

[0052] Add 0.4 g of ammonium persulfate (APS) to 10 mL of water to configure the initiator solution, separate 5 mL into the syringe pump, and add the core layer pre-emulsion to the dropping funnel (reserve about 1 / 4 in the original flask)...

Embodiment 3

[0058] Step 1: Preparation of Adhesive

[0059] Preparation of core-shell emulsion: the core layer emulsifier fatty alcohol polyoxyethylene ether (AEO-9), deionized water and methyl methacrylate (MMA), ethyl acrylate (EA) and n-butyl acrylate (BA) Add it into a 500mL four-neck flask, ultrasonicate at 55°C for 15min, then raise the temperature to 58°C, stir at 580r / min for 45min to disperse evenly, and obtain the core layer pre-emulsion; the shell layer emulsifier (AEO- 9), deionized water, methyl methacrylate (MMA), ethyl acrylate (EA) and n-butyl acrylate (BA) were added to a 500mL four-necked flask, ultrasonicated at 55°C for 15min, and then heated to 58°C , stirred at 580r / min for 45min to disperse evenly to obtain a shell pre-emulsion.

[0060] Add 0.4 g of ammonium persulfate (APS) to 10 mL of water to configure the initiator solution, separate 5 mL into the syringe pump, and add the core layer pre-emulsion to the dropping funnel (reserve about 1 / 4 in the original flask)...

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Abstract

A synthetic method of a low-temperature environmentally friendly type flame retardant silicone acrylic electrostatic flocking adhesive is disclosed. The method is characterized by including preparinga core-layer pre-emulsification liquid and a shell-layer pre-emulsification liquid separately; adding dropwise the core-layer pre-emulsification liquid and an initiator solution into a container at the same time to obtain a seed emulsion; then adding dropwise the shell-layer pre-emulsification liquid and an initiator solution into the seed emulsion at the same time; maintaining the temperature after material addition is finished; taking the product out of a reactor; naturally cooling the product to room temperature; performing filtration to obtain a milk-white emulsion through which blue lightcan penetrate; adding adipic dihydrazide into the milk-white emulsion; and stirring the mixture to obtain the uniform and stable adhesive. An in-situ polymerization method, introduction of new functional monomers and multi-component copolymerization are adopted to prepare the phosphorus-containing silicone acrylic emulsion stable to store and silicone acrylic latex having intrinsic flame retardant performance, so that a polyacrylate emulsion after complete polymerization has certain flame retardant performance, the dosage of a blending flame retardant is reduced and flocking effects are improved.

Description

technical field [0001] The invention relates to a synthesis method and application of a low-temperature environment-friendly flame-retardant silicon-acrylic electrostatic flocking adhesive, which belongs to the technical fields of textile, textile chemistry and dyeing and finishing engineering. Background technique [0002] Electrostatic flocking as a surface processing technology, because of its bright colors, soft touch, warmth and comfort, unique style, and the technology has strong adaptability, simple process and low cost. In recent years, my country's flocking industry has developed rapidly, but there are still many problems, such as single product variety, low grade, low added value of products, and insufficient development of new varieties. In recent years, the frequent occurrence of fire incidents caused by textile fabrics has made people realize that the flame retardant modification of electrostatic flocking products has become a major subject to be studied urgentl...

Claims

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Application Information

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IPC IPC(8): C09J133/08C08F220/18C08F220/14B05C19/00D06N3/04D06N7/00
CPCB05C19/002C08F220/18C08F220/1804C09J133/08D06N3/042D06N7/0097D06N2209/067D06N2209/1664C08F220/14
Inventor 蔡再生宋甜甜吴海婷
Owner DONGHUA UNIV
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