Energy-saving insulated flame-retardant water-proof corrosion-proof functional coating and preparation method thereof
A functional coating and coating technology, applied in anti-corrosion coatings, polyurea/polyurethane coatings, coatings, etc., can solve the problems of polluted environment, poor chemical resistance, single function, etc., achieve good compatibility, excellent performance, increase The effect of thermal insulation
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Embodiment 1
[0023] In a reactor equipped with a stirrer, a thermometer, and a reflux condenser, add 40 g of polyether polyol (molecular weight: 2300), vacuumize and dehydrate at 110°C for 1 hour, cool down to below 50°C, and add 18g of isophorone diisocyanate , heated to 80°C, reacted for 2 hours, added 3 g of dimethylol propionic acid, 1.2 g of 1,4-butanediol, 0.3 g of trimethylol propane, and 0.12 g of stannous octoate, and continued to react for 2 hours under stirring , during the reaction process, the viscosity of the reactant is controlled below 4000mPa.s by adding acetone to obtain a prepolymer, and then the temperature is lowered to about 40°C, and 2g of triethylamine is added to neutralize the prepolymer to form a salt to obtain a prepolymer; prepolymer The material is discharged into a disperser, 117 g of deionized water is added under high-speed shearing, and 90% of the volume of acetone is evaporated to obtain an aqueous polyurethane dispersion. Its properties are as follows: s...
Embodiment 2
[0025] In a reactor equipped with a stirrer, a thermometer, and a reflux condenser, add 40 g of polyether polyol (molecular weight: 2100), vacuumize and dehydrate at 105°C for 1 hour, cool down to below 50°C, and add isophorone diisocyanate 12.5 g, 6.2g of 1,6-hexamethylene diisocyanate, heat up to 80°C, react for 1 hour, add 2.3g of dimethylol propionic acid, 2.3g of 1,4-butanediol, 0.3g of glycerin, dibutyltin dilaurate 0.13g, continue to react for 3 hours under stirring, during the reaction, add acetone to control the viscosity of the reactant below 4000mPa. Neutralize and form a salt to obtain a prepolymer; the prepolymer is discharged into a disperser, and 125 g of deionized water is added under high-speed shearing, and 90% of the volume of acetone is evaporated to obtain an aqueous polyurethane dispersion. Its properties are as follows: solid content: 32.3%; pH value: 7.1; viscosity (coating -4 cups / 25°C): 17 seconds.
Embodiment 3
[0027] In a reactor equipped with a stirrer, a thermometer and a reflux condenser, add 40g of polyether polyol (molecular weight: 1800), dehydrate under vacuum at 105°C for 1 hour, cool down to below 50°C and add 18g of dicyclohexylmethane diisocyanate , heated to 75°C, reacted for 1 hour, added 3.5g of dimethylolpropionic acid, 1.7g of 1,4-butanediol, 0.2g of stannous octoate, and continued to react for 3 hours under stirring to obtain a prepolymer. During the reaction process, the viscosity of the reactant is controlled below 4000mPa.s by adding acetone, then the temperature is lowered to about 35°C, and 3.2g of triethylamine is added to neutralize the prepolymer to form a salt; 101 g of deionized water was added, and 90% volume of acetone was distilled off to obtain an aqueous polyurethane dispersion. Its properties are as follows: solid content: 37.3%; PH value: 7.2; viscosity (coating -4 cups / 25°C): 18 seconds.
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