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Cement-based composite material used for 3D printing technology as well as preparation method and application thereof

The invention provides a cement-based composite material used for a 3D printing technology as well as a preparation method and application thereof. The cement-based composite material is prepared from the following raw materials based on the total weight of the composite material: 33%-40% of cement, 0%-8% of inorganic powder, 32%-38% of tailing machine-made sand, 2.5%-3% of a high-molecular polymer, 0.1%-0.5% of a water reducing agent and 16.7%-20% of mixing water; a composite thickening time control agent, a thixotropic agent, a volume stabilizer and the like are added into a mixture to prepare an inorganic composite material; and then the inorganic composite material can be directly pumped into a 3D printer for building to be applied to construction. The cement-based composite material is an inorganic material and the materials are easily available; a lot of industrial waste materials can be used; therefore, the cement-based composite material is low in cost, energy-saving and environment-friendly; the condensation time can be flexibly controlled, and the material has super early strength, good caking property and strong stability; the requirements of 3D printing construction continuity of the building and the building strength are met so that the house building has good global stability and use safety; and the application and popularization of 3D printing technology can be greatly promoted.
Owner:CHINA STATE CONSTRUCTION ENGINEERING CORPORATION

Bi-component cement based composite material for 3D printing as well as preparation method and application thereof

The invention discloses a bi-component cement based composite material for 3D (three dimensional) printing as well as a preparation method and application thereof. The bi-component cement based composite material for 3D printing comprises a component A and a component B, wherein the component A is prepared from 34 to 40 percent of sulphate aluminium cement, 0 to 6 percent of inorganic powder, 40 to 44 percent of tailing machine-made sand, 2.5 to 3 percent of high-molecular polymer and the balance of a retarder, a water reducer, a size stabilizer, a defoaming agent and water, the pumping performance can be well kept for a long time, an industrialized process of pre-stirring production in a mixing plant, transportation, and using in a construction site can be realized; the B component is prepared from a coagulate promoting agent, a thixotropic agent, a defoaming agent and water, the component is stable in form and can be stored for a long time or produced in a concentrated manner. After A and B are respectively pumped in a 3D printer, through high-speed stirring and being mixed by an extrusion head, the composite printing material can be extruded out, the time of coagulation is short, the strength is high, the adhesion is good, the stability is strong, the constructive continuity and building strength requirements of building 3D printing can be met, the industrial production and promotion of the cement based 3D printing material are facilitated, and the application of a 3D printing technology in buildings can be effectively promoted.
Owner:CHINA STATE CONSTRUCTION ENGINEERING CORPORATION

Air fryer

The invention relates to an air fryer which comprises a machine body, wherein a cooking cavity with an opening is formed in the machine body, and a pot body for accommodating food is arranged in the cooking cavity body. The air fryer is characterized in that a driving mechanism capable of driving the pot body to enter the cooking cavity body from the opening of the cooking cavity body and drivingthe pot body to move out of the cooking cavity body from the opening of the cooking cavity body is arranged in the machine body, an instruction input component connected with the driving mechanism isarranged on the machine body, a tray or a dragging basket fixedly connected with the driving mechanism is arranged in the cooking cavity body, and the pot body is detachably arranged on the tray or detachably arranged in the dragging basket. Compared with the prior art, the air fryer disclosed by the invention has the advantages that the pot body is automatically driven by the driving mechanism toenter the cooking cavity body from the opening of the cooking cavity body or the pot body is automatically driven by the driving mechanism to move out of the cooking cavity body from the opening of the cooking cavity body, so that safety and convenience in use are achieved; the driving mechanism is fixedly connected with the tray or the dragging basket, and the pot body is detachably arranged onthe tray or detachably arranged in the dragging basket; thus, the pot body can be conveniently taken out of the machine body to be cleaned.
Owner:YUEDA ELECTRONICS TECH

Preparation method for chitosan natural polymer modified crude oil desalting demulsifier

ActiveCN106188552ALimited demulsibilityIntensify the degree of emulsificationDewatering/demulsification with chemical meansQuaternary ammonium cationNon toxicity
The invention relates to a preparation method for a chitosan natural polymer modified crude oil desalting demulsifier. The method comprises the following steps: 1) modifying polyethylene glycol monomethyl ether by halogenating; 2) preparing glycidyl dimethyl alkyl ammonium chloride; 3) preparing quaternized carboxy alkyl chitosan; 4) causing the modified polyethylene glycol monomethyl ether to react with the quaternized carboxy alkyl chitosan, thereby obtaining a target product, polyethylene glycol monomethyl ether grafted quaternized carboxy alkyl chitosan. According to the invention, the chitosan natural high-molecular compound is taken as the raw material and has the advantages of wide resource, naturality, non-toxicity, sustainability, excellent biological compatibility of products, degradability, and the like. The demulsifier prepared according to the invention has excellent demulsification dewatering effect; the molecule of the demulsifier contains a large amount of carboxy alkyl groups and quaternary ammonium salt groups and the electronegative ions, including metal cation, naphthene acid radicals, and surfaces are electronegative grains and have strong combining capacity, so that the demulsifier has the capacities of demulsifying while removing oil-soluble salt.
Owner:WUHAN INSTITUTE OF TECHNOLOGY

Preparation method of polyether-grafted chitosan derivative crude oil desalting demulsifier

The invention relates to a preparation method of a polyether-grafted chitosan derivative crude oil desalting demulsifier. The preparation method comprises the following specific steps: firstly, performing formylation modification on polyethylene glycol monoethylether; secondly, preparing glycidyl dimethyl alkyl ammonium chloride; thirdly, preparing quaternarization carboxyalkyl chitosan; fourthly, enabling formylation modified polyethylene glycol monoethylether to react with carboxy alkyl chitosan to obtain the polyether-grafted chitosan derivative crude oil desalting demulsifier. The polyether-grafted chitosan derivative crude oil desalting demulsifier disclosed by the invention is prepared by taking chitosannatural polymeric compounds as raw materials, and has the advantages of wide sources, naturalness, no toxicity, sustainability, good biocompatibility of a product, degradability and the like. The prepared demulsifier is good in demulsifying and dehydrating effect; meanwhile, a demulsifying molecule contains a large amount of carboxyalkyl groups and quaternary ammonium salt groups which have strong combining capacity to metal cation, ions with negative electricity such as naphthenic acid radicals as well as particles of which the surfaces are electronegative, so the polyether-grafted chitosan derivative crude oil desalting demulsifier has capacity of removing oil-soluble salts while demulsifying.
Owner:WUHAN INSTITUTE OF TECHNOLOGY

Synthesis method of crude oil desalting demulsifying agent

ActiveCN106279707ALimited demulsibilityIntensify the degree of emulsificationDewatering/demulsification with chemical meansHydrocarbon oils treatmentQuaternary ammonium cationSynthesis methods
The invention relates to a synthesis method of a crude oil desalting demulsifying agent. The method specifically includes the steps of firstly, conducting p-nitrophenyl ester modification on methoxypolyethylene glycol; secondly, preparing glycidyl dimethyl alkyl ammonium chloride; thirdly, preparing quaternized carboxy alkyl chitosan; fourthly, making the modified methoxypolyethylene glycol react with quaternized carboxy alkyl chitosan to obtain a product, namely polyethylene glycol questin grafted quaternized carboxy alkyl chitosan. A chitosan type natural high-molecular compound serves as the raw material and has the advantages of being wide in resource, natural, free of toxin, sustainable, good in product biocompatibility, degradable and the like; The prepared demulsifying agent is good in demulsifying dewatering effect; meanwhile, due to the fact that lots of carboxy alkyl groups and quaternary ammonium salt groups are contained in demulsifying agent molecules and have strong binding capacity with metal cations, naphthenic acid radicals and other ions with negative charges and particles with surface electronegativity, the oil-soluble salt removing capacity is achieved during demulsifying.
Owner:WUHAN INSTITUTE OF TECHNOLOGY

Preparation method of double-ion type crude oil desalting demulsifier

The invention relates to a preparation method of a double-ion type crude oil desalting demulsifier. The preparation method specifically comprises the following steps: (1) carrying out esterification modification on polyethylene glycol monomethyl ether; (2) preparing glycidyl dimethyl alkyl ammonium chloride; (3) preparing quaternary ammonium carboxymethyl chitosan; (4) making the modified polyethylene glycol monomethyl ether react with the quaternary ammonium carboxymethyl chitosan to obtain a polyethylene glycol monomethyl ether grafted quaternary ammonium carboxymethyl chitosan. The double-ion type crude oil desalting demulsifier takes natural macromolecular compounds of chitosan as raw materials, thereby having many advantages of wide sources, naturalness, no toxicity, sustainability, good product bio-compatibility and degradation and the like. The prepared demulsifier is good in demulsification and dehydration effects, furthermore, demulsifier molecules contain a large number of carboxyl alkyl groups and quaternary ammonium salt groups, so that the demulsifier has a very strong binding capacity for negatively charged ions such as metal cations, naphthenic acid radicals and particles of which the surfaces are electronegative, thereby further having the removal ability for oil soluble salts while performing demulsification.
Owner:WUHAN INSTITUTE OF TECHNOLOGY

Preparation method of polyelectrolyte-type crude oil-desalting demulsifier

The invention relates to a preparation method of a polyelectrolyte-type crude oil-desalting demulsifier. The preparation method comprises the following specific steps: (1) performing amination modification on methoxypolyethylene glycol; (2) preparing glycidyl dimethyl alkyl ammonium chloride; (3) preparing quaternized carboxyalkyl chitosan; (4) carrying out a reaction between the modified methoxypolyethylene glycol and the quaternized carboxyalkyl chitosan to obtain a target product methoxypolyethylene glycol-grafted quaternized carboxyalkyl chitosan. The polyelectrolyte-type crude oil-desalting demulsifier takes a natural macromolecule chitosan compound as a raw material, and has the advantages of wide sources, naturalness, non-toxicity, sustainability, good product biocompatibility, biodegradability and the like. The prepared demulsifier has good demulsifying and dehydrating effects; a demulsifier molecule contains a large number of carboxyalkyl groups and quaternary ammonium groups, which have very strong capacity of bonding metal cations, negatively-charged ions such as naphthenic acid radicals, and particles with negative charges on the surfaces, so that besides the demulsifying capability, the demulsifier also has the capability of removing oil-soluble salts.
Owner:WUHAN INSTITUTE OF TECHNOLOGY

Escape automatic window breaking system for passenger vehicle and control method thereof

The invention discloses an escape automatic window-breaking system for a passenger vehicle and a control method thereof and belongs to the technical field of safety control of passenger vehicles. Glass embedded with electric heating wires is mounted on a vehicle window of the escape automatic window breaking system for the passenger vehicle, the electric heating wires are connected to a power supply of the passenger vehicle through a power supply main line, and an automatic control system is arranged on the power supply main line. The control method of the escape automatic window breaking system for the passenger vehicle, disclosed by the invention, comprises the following steps: respectively comparing a temperature value T in the vehicle, a smoke fog concentration value Sm and an external impact force P with preset critical values and processing through a controller according to all the values. The escape automatic window-breaking system for the passenger vehicle, disclosed by the invention, can be used for increasing the safety coefficient of the passenger vehicle and protecting the life safety of passengers to the greatest extent, and has important significance in reducing casualties and is wide in application range; and according to the control method of the escape automatic window breaking system for the passenger vehicle, disclosed by the invention, both an automatic control window breaking way and a manual switching way can be realized, and the safety and reliability of the window breaking system can be fully ensured.
Owner:SICHUAN AGRI UNIV
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