Foaming agent containing polyamine salt and ethanolamine salt and application to polyurethane intermittent board foam material
A technology of ethanolamine salt and foaming agent, which is applied in the field of polyurethane foaming agent, and can solve problems affecting the strength and heat insulation properties of foaming materials, uneven cell size, and uneven cell distribution.
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preparation example 1
[0069] Add 3kg of 40% ethylenediamine aqueous solution (molecular weight 60) into a transparent quartz glass reactor, stir to dissolve, seal the reactor, then, under constant stirring, control the temperature between 40-65°C, and pass carbon dioxide into In the reactor, control the pressure not to be higher than 0.3MPa, control the temperature and react for 10 hours, release the pressure and release the product after the temperature is lowered to below 40°C. Compound 1 was obtained. pH≥7.5, decomposition temperature is 42°C-70°C.
preparation example 2
[0071] The 50% diethylenetriamine aqueous solution (molecular weight 103) of 3kg is joined in the transparent quartz glass reactor, stirs to dissolve, seals the reactor, then under constant stirring, controls the temperature between 40-65 ℃, will Pass carbon dioxide into the reactor, control the pressure not to be higher than 0.3 MPa, and control the temperature for 10 hours to react. After cooling down to below 40°C, release the pressure and release the product. Compound 2 was obtained. pH≥7.5, decomposition temperature is 42°C-70°C.
preparation example 3
[0073] Add 3kg of triethylenetetramine (molecular weight 146) and 1.8kg of water into a transparent quartz glass reactor, stir to dissolve, seal the reactor, and then control the temperature between 40-65°C under constant stirring, Pass carbon dioxide into the reactor, control the pressure not higher than 0.3MPa, control the temperature and react for 10 hours, release the pressure and release the product after cooling down to below 40°C. Compound 3 was obtained. pH≥7.5, decomposition temperature is 42°C-70°C.
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