Organic light-emitting device
A technology of organic light-emitting devices and light-emitting layers, which is applied in the manufacturing of electric solid-state devices, semiconductor devices, and semiconductor/solid-state devices, etc., can solve the problems of unbalanced carrier injection, low luminous efficiency of light-emitting devices, and offset of recombination area. To achieve the effect of improving the generation rate and utilization rate
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Embodiment 1
[0095] Embodiment 1: the synthesis of compound 1
[0096]
[0097] Synthesis of Intermediate A1
[0098] Tri-tert-butylphosphine (4.4 mL of a 1.0 M solution in toluene, 1.48 g, 0.05 mmol), palladium acetate (0.4 g, 1.83 mmol) and sodium tert-butoxide (52.6 g, 549 mmol) were added to 2-bromotriphenylene (56.0 g, 183 mmol) and 2-amino-9,9-spirobifluorene (60.6 g, 183 mmol) in degassed toluene (1 L), and the mixture was heated at reflux for 2 hours. The reaction mixture was cooled to room temperature, diluted with toluene and filtered through celite. The filtrate was diluted with water and extracted with toluene, and the combined organic phases were evaporated under vacuum. The residue was filtered through silica gel and recrystallized. Intermediate A1 (81.6 g, 80% yield) was obtained. Mass Spectrum m / z: 557.63 (calculated: 557.68). Theoretical element content (%)C 43 h 27 N: C, 92.61; H, 4.88; N, 2.51 Measured element content (%): C, 92.62; H, 4.86; N, 2.52. The above...
Embodiment 2
[0100] Embodiment 2: the synthesis of compound 1-25
[0101] Replace the 2-amino-9,9-spirobifluorene in Example 1 with equimolar 9-amino-7,7-dimethyl-7H-indolo[1,2-f]quinoline, other The steps were all the same as the synthesis of Example 1 to obtain the target product compound 1-25. Mass Spectrum m / z: 729.83 (calculated: 729.91). Theoretical element content (%)C 54 h 39 N 3 : C, 88.86; H, 5.39; N, 5.76 The measured element content (%): C, 88.88; H, 5.37; N, 5.75. The above results confirmed that the obtained product was the target product.
Embodiment 3
[0102] Embodiment 3: the synthesis of compound 1-26
[0103] Replace the 2-amino-9,9-spirobifluorene in Example 1 with equimolar 2-amino-11,11-dimethyl-11H-benzo[b]fluorene, 9-bromo-7,7 -Dimethyl-7H-indolo[1,2-f]quinoline was replaced by equimolar 2-bromo-11,11-dimethyl-11H-benzo[b]fluorene, and other steps were carried out with The synthesis of Example 1 was the same, and the target product compound 1-26 was obtained. Mass Spectrum m / z: 727.26 (calculated: 727.93). Theoretical element content (%)C 56 h 41 N: C, 92.40; H, 5.68; N, 1.92 Measured element content (%): C, 92.42; H, 5.67; N, 1.92. The above results confirmed that the obtained product was the target product.
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