A kind of starch-grafted polyurethane polymer and its preparation method and application in biodegradable condom
A technique of grafting polyurethane and starch, which is applied in the direction of male contraceptives, etc., can solve the problems of poor oil resistance and solvent resistance, discomfort reaction, easy oxidation, etc., and achieve stable performance, comfortable use experience, and good stretch The effect of intensity
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Embodiment 1
[0022] a, a grafting reaction
[0023]Disperse and dissolve 10 grams of completely dry amylose with an average molecular weight of 50,000 in 500ml of dimethylformamide, and keep stirring at 30°C for 0.5 hours; Weigh 32.2 grams of toluene diisocyanate based on the polymer degree of the repeating unit, and dissolve it in 644 ml of dimethylformamide; slowly add the toluene diisocyanate solution dropwise into the amylose solution, and raise the temperature of the reaction system to 60°C. Reflux reaction for 4 hours under continuous stirring; after the reaction, the organic solvent was removed by rotary evaporation, and the product was washed with hot water and ethanol for at least 3 times; finally, the product of starch grafted polyurethane polymer containing isocyanic acid structure was obtained .
[0024] b. Secondary grafting reaction
[0025] The starch-grafted polyurethane polymer containing isocyanic acid structure obtained by step a reaction is completely dehydrated and d...
Embodiment 2
[0029] This example is basically the same as Example 1, except that the average molecular weight of the amylose added is 80,000 in the step a of the grafting reaction step.
Embodiment 3
[0031] This example is basically the same as Example 1, except that in step a of the grafting reaction step, the average molecular weight of the amylose added is 150,000.
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