Heat sensitive nanofiber as well as preparation method, drug carrying heat sensitive nanofiber and preparation method
A nanofiber, heat-sensitive technology, applied in fiber types, fiber treatment, pharmaceutical formulations, etc., to achieve the effects of simple process, reduced preparation cost, and convenient operation
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[0032] According to a second aspect of the present invention, the present invention provides a method for preparing heat-sensitive nanofibers, comprising the steps of:
[0033] Firstly, the photoinitiator is adsorbed on the surface of the PCL nanofiber to obtain the PCL nanofiber with the photoinitiator adsorbed on the surface, and then the PCL nanofiber with the photoinitiator adsorbed on the surface is immersed in the mixed solution of PEGDMA oligomer and NIPAAm, and finally the ultraviolet Under light irradiation, the PEGDMA oligomer and NIPAAm are in-situ polymerized on the surface of the PCL nanofibers to obtain thermosensitive nanofibers with the PCL nanofibers as the core and the PEG-PNIPAAm as the shell.
[0034] In the present invention, PEGDMA refers to polyethylene glycol dimethacrylate, and NIPAAm refers to N-isopropylamide.
[0035] The preparation method of heat-sensitive nanofiber provided by the invention, by absorbing photoinitiator on the surface of PCL nanof...
Embodiment 1
[0076] This embodiment provides a drug-loaded thermosensitive nanofiber, which is prepared according to the following steps:
[0077] (1) Configure the mixed solution of salicylic acid (SA) and PCL, wherein the solvent is a mixed solution of DCM and DMF, the mass ratio of the two is 7:3, the volume concentration of SA is 3%, and the mass concentration of PCL 10%;
[0078] (2) The mixed solution of SA and PCL is obtained drug-loaded PCL nanofiber by electrospinning;
[0079] (3) Immerse the drug-loaded PCL nanofibers in a benzophenone solution with a mass concentration of 20%, take them out after 5 minutes, and dry them in vacuum to obtain drug-loaded PCL nanofibers adsorbed with benzophenone;
[0080] (4) The drug-loaded PCL nanofibers adsorbed with benzophenone are immersed in a mixed solution of PEGDMA oligomers and NIPAAm, wherein the mass ratio of PEGDMA oligomers and NIPAAm is 3:5, and under ultraviolet light irradiation, PEGDMA oligomers and NIPAAm were in-situ polymer...
Embodiment 2
[0082] This example provides a drug-loaded thermosensitive nanofiber. The difference between this example and the preparation method of Example 1 is that in step (3), the mass concentration of the benzophenone solution is 10%.
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