A multi-stage reforming power generation system using liquid fuel as hydrogen source for fuel cells

A fuel cell and power generation system technology, which is applied in fuel cells, fuel cell additives, fuel cell heat exchange, etc., can solve the problems of easy poisoning and decay of catalysts, clogging of reaction pipelines, complex composition, etc., to reduce difficulty and achieve dynamic Coupling, good thermal stability

Active Publication Date: 2021-10-22
NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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Problems solved by technology

And the controllability of gasoline combustion is poor)
The carbon number distribution of diesel is wider than that of kerosene, and the composition is more complex, and the catalyst is more likely to be poisoned and attenuated during the hydrogen production process of steam reforming
Moreover, the combustibility of diesel oil is also lower than that of kerosene, and it is easy to generate a large amount of black smoke particles during combustion, which will block the reaction pipeline.

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  • A multi-stage reforming power generation system using liquid fuel as hydrogen source for fuel cells
  • A multi-stage reforming power generation system using liquid fuel as hydrogen source for fuel cells
  • A multi-stage reforming power generation system using liquid fuel as hydrogen source for fuel cells

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[0022] In order to make the purpose, technical solutions and advantages of the present invention clearer, the technical solutions in the invention are clearly and completely described in conjunction with the accompanying drawings in the present invention. The specific examples described here are only used to explain the present invention, not to limit the present invention.

[0023] figure 1It is a schematic structural diagram of a multi-stage reforming system in which liquid kerosene is used as a hydrogen source for a fuel cell. Equipped with liquid fuel oil (gasoline is mainly composed of C5-C12 aliphatic hydrocarbons and cycloalkanes, and its distillation range is 30-220°C; kerosene is mainly composed of C11-C17 saturated hydrocarbons, unsaturated hydrocarbons and aromatic hydrocarbons, Its boiling range is 180-310°C; while diesel oil is a light petroleum product, mainly a complex hydrocarbon mixture of C10-C22, and its boiling range is 180-370°C) the storage tank is conne...

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Abstract

The invention discloses a multi-stage reforming power generation system using liquid fuel as a fuel cell hydrogen source, and belongs to the technical fields of energy, reforming hydrogen production and high-efficiency power generation. The system includes a liquid fuel hydrogen production unit, a fuel cell unit and a waste heat recovery unit, the liquid fuel hydrogen production unit is connected to the intake pipe of the fuel cell unit through an outlet pipe, and the outlet pipe of the fuel cell unit is connected to the intake pipe of the waste heat recovery unit , the outlet pipe of the waste heat recovery unit is connected to the inlet pipe of the liquid fuel hydrogen production unit, and the closed loop structure constitutes energy recycling. The invention proposes the technology of multi-stage reforming liquid fuel oil as a hydrogen source, and develops an anode material resistant to carbon deposition, which solves the technical difficulty of easy carbon deposition in the anode of the fuel cell, and makes the traditional fuel cell with hydrogen as the working medium additional structural weight Problems such as high energy consumption and high safety hazards have been solved, laying the foundation for the substantial application of fuel cells in the field of power generation.

Description

technical field [0001] The invention relates to a multi-stage reforming power generation system using liquid fuel as a fuel cell hydrogen source, and belongs to the technical fields of energy, reforming hydrogen production and high-efficiency power generation. Background technique [0002] SOFC (Solid Oxide Fuel Cell) is a fuel cell that uses oxygen ion / proton conductor as the electrolyte and works at a relatively high temperature (450-1000°C). The by-product is high-quality water vapor, and the waste heat has high value. Its conversion efficiency can be increased to 80%, and almost no nitrogen oxides and sulfur oxides are emitted. SOFC has the characteristics of large technical power level and modular power generation. SOFC modules can be configured according to the actual load capacity to meet the needs of different power levels. Compared with the traditional electricity method based on combustion, SOFC technology greatly reduces the energy loss of fossil fuels and the da...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M8/0612H01M8/04007H01M8/04014
CPCH01M8/04022H01M8/04074H01M8/0618Y02E60/50
Inventor 梁凤丽束莉楠毛军逵
Owner NANJING UNIV OF AERONAUTICS & ASTRONAUTICS
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