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Acrylate pressure-sensitive adhesive adhesive containing nano-siloxane condensate, adhesive sheet and preparation method thereof

A pressure-sensitive adhesive and siloxane condensate technology, applied in the direction of ester copolymer adhesives, adhesives, adhesive types, etc., can solve the problems of low surface energy and difficult bonding

Inactive Publication Date: 2020-12-08
3M INNOVATIVE PROPERTIES CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, this also poses a great challenge to the traditional bonding technology, because these materials often have low surface energy and are relatively difficult to bond

Method used

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  • Acrylate pressure-sensitive adhesive adhesive containing nano-siloxane condensate, adhesive sheet and preparation method thereof
  • Acrylate pressure-sensitive adhesive adhesive containing nano-siloxane condensate, adhesive sheet and preparation method thereof
  • Acrylate pressure-sensitive adhesive adhesive containing nano-siloxane condensate, adhesive sheet and preparation method thereof

Examples

Experimental program
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preparation example Construction

[0021] The method for preparing pressure-sensitive adhesive sheet provided by the invention comprises the following steps:

[0022] Apply the pressure-sensitive adhesive provided by the present invention to the surface of the substrate, form a wet pressure-sensitive adhesive liquid film on the surface of the substrate, and dry the wet pressure-sensitive adhesive liquid film Curing results in a dry coating that adheres to the substrate surface. The introduction of the pressure-sensitive adhesive is detailed in the " pressure sensitive adhesive bonding agent " section. The pressure-sensitive adhesive can be applied to the surface of the substrate by methods known in the prior art, which can preferably be one or more of the following group: roll coating, flow coating, dip coating method, spin coating method, spray coating method, knife coating method and die coating method.Described pressure-sensitive adhesive coating completely or partly does not contain solvent, and prefera...

Embodiment approach 1

[0026] Preferred Embodiment 1 is a pressure sensitive adhesive comprising the reaction product of the following reaction components:

[0027] 1) 90-99 parts by weight of the acrylate copolymer A, the total weight of the acrylate copolymer A and the nano-siloxane condensate B is 100 parts by weight, and the acrylate copolymer A is composed of acrylate monomers The acrylate monomer mixture contains at least one carboxyl group-containing monomer P, based on 100 parts by weight of the acrylate monomer mixture, the number of parts by weight of the carboxyl group-containing monomer P is 1 servings to 10 servings;

[0028] 2) 1-10 parts by weight of the nano-siloxane condensate B, with the total weight of the acrylate copolymer A and the nano-siloxane condensate B being 100 parts by weight, the nano-siloxane condensate B Partial or total co-condensation products including siloxane compound B1, siloxane compound B2 and siloxane compound B3 having the general formula I:

[0029] (RO)...

Embodiment approach 11

[0048] Preferred Embodiment 11 A pressure-sensitive adhesive as described in Preferred Embodiment 1, further comprising a solvent, the solvent comprising one or more of the following solvents: ethyl acetate, butyl acetate, toluene, xylene , butanone, acetone, ethanol, isopropanol.

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Abstract

The invention provides a pressure-sensitive adhesive binder. The pressure-sensitive adhesive binder comprises, by weight, 90-99 parts of acrylate copolymer A, 1-10 parts of nano siloxane condensate B,5-15 parts of petroleum carbon hydrogen type tackifying resin and 0.02-2 parts of crosslinking agent, total amount of the acrylate copolymer A and the nano siloxane condensate is 100 parts in weight,the acrylate copolymer A is formed by copolymerizing acrylate monomer mixtures at least containing carboxyl-containing monomer P, the nano siloxane condensate B is a co-condensation product comprising part of or all of a siloxane compound B1, a siloxane compound B2 and a siloxane compound B3, the B1 contains carboxylic functional group, the B2 contains alkyl functional group, the B3 is orthosilicate, and a weight ratio of the siloxane compound B1 to the siloxane compound B2 is 1:10-20.

Description

technical field [0001] The invention relates to the field of pressure-sensitive adhesives, in particular to an acrylate pressure-sensitive adhesive, an adhesive sheet and a preparation method thereof. Background technique [0002] With the development of manufacturing industry, plastics and recycled plastics, especially thermoplastic polyolefins, have lower cost and stronger processability than metal materials used in the past, so they are widely used in automobile manufacturing, commercial signs and electronic equipment, etc. The field of application is getting wider and wider. However, this also poses a huge challenge to traditional bonding techniques, because these materials often have low surface energy and are relatively difficult to bond. Although rubber adhesives generally have good adhesion to low-energy surfaces, the low aging resistance of rubber often causes people to worry about their use. Due to the moderate cost and superior aging resistance of acrylate adhes...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09J133/08C09J183/04C09J11/08C09J11/06
Inventor 张云舒银龙张丽晶金舟
Owner 3M INNOVATIVE PROPERTIES CO
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