Mononuclear fluorine-substituted bimetal phthalocyanine complex/activated carbon lithium thionyl chloride battery catalytic material and preparation method thereof

A technology for lithium thionyl chloride batteries and catalytic materials, which is applied to battery electrodes, non-aqueous electrolyte batteries, circuits, etc., can solve the problems of small size, low cost and high purity, and achieves good uniformity, low cost and simple preparation method. Effect

Active Publication Date: 2019-05-31
SHAANXI UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, these methods have certain shortcomings, and cannot meet the requirements of small size, high purity, easy transfer to other substrates, and low cost at the same time.

Method used

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  • Mononuclear fluorine-substituted bimetal phthalocyanine complex/activated carbon lithium thionyl chloride battery catalytic material and preparation method thereof
  • Mononuclear fluorine-substituted bimetal phthalocyanine complex/activated carbon lithium thionyl chloride battery catalytic material and preparation method thereof
  • Mononuclear fluorine-substituted bimetal phthalocyanine complex/activated carbon lithium thionyl chloride battery catalytic material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] 1) Take 0.46g of 4-fluorophthalic anhydride and 0.06g of specific surface area of ​​1200m 2 / g of pitch coke activated carbon was mixed evenly in a glass mortar;

[0025] 2) Take 0.6g of urea, 0.08g of ammonium molybdate, 0.35g of cobalt chloride hexahydrate and 0.092g of copper chloride dihydrate and add them to the above-mentioned glass mortar and grind them thoroughly and put them into a crucible in a muffle furnace Sintering, muffle furnace at 10°C min -1 Heat up at a speed of 130°C from room temperature and keep warm for 0.2h; then at 5°C min -1 The temperature was raised to 240°C at a certain speed, and the temperature was kept for 2 hours;

[0026] 3) Naturally cool to room temperature, wash the prepared product with ultrapure water for 10 hours, change the water and wash 8 times, then use water and ethanol to filter, wash several times, and dry to obtain the mononuclear fluorine-substituted bimetallic phthalocyanine complex / Activated carbon lithium thionyl c...

Embodiment 2

[0028] 1) Take 0.819g of 4-fluorophthalic anhydride and 0.1g of specific surface area of ​​1200m 2 / g of pitch coke activated carbon was mixed evenly in a glass mortar;

[0029] 2) Take 0.6g of urea, 0.08g of ammonium molybdate, 0.2g of cobalt chloride hexahydrate and 0.1g of copper chloride dihydrate and add them to the above-mentioned glass mortar and grind them thoroughly, then put them into a crucible in a muffle furnace Sintering, muffle furnace at 10°C min -1 The temperature is raised at a speed of 140°C from room temperature, and kept for 0.5h; then at 5°C min -1 The temperature is raised to 250°C at a certain speed, and the temperature is kept for 1.5h;

[0030] 3) Naturally cool to room temperature, wash the obtained product with ultrapure water for 24 hours, change the water and wash 8 times, then use water and ethanol to filter, wash several times, and dry to obtain the mononuclear fluorine-substituted bimetallic phthalocyanine complex / Activated carbon lithium t...

Embodiment 3

[0032] 1) Take 0.92g of 4-fluorophthalic anhydride and 0.1g of specific surface area of ​​1200m 2 / g of pitch coke activated carbon was mixed evenly in a glass mortar;

[0033] 2) Take 1.2g of urea, 0.12g of ammonium molybdate, 0.458g of cobalt chloride hexahydrate and 0.06g of copper chloride dihydrate and add them to the above-mentioned glass mortar and grind them thoroughly and put them into a crucible in a muffle furnace Sintering, muffle furnace at 10°C min -1 The temperature is raised at a speed of 150°C from room temperature, and kept for 0.5h; then at 5°C min -1 The temperature is raised to 270°C at a certain speed, and the temperature is kept for 2 hours;

[0034] 3) Naturally cool to room temperature, wash the obtained product with ultrapure water for 24 hours, change the water and wash 9 times, then use water and ethanol to filter, wash several times, and dry to obtain the mononuclear fluorine-substituted bimetallic phthalocyanine complex / Activated carbon lithiu...

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Abstract

The invention discloses a mononuclear fluorine-substituted bimetal phthalocyanine complex/activated carbon lithium thionyl chloride battery catalytic material and a preparation method thereof. 4-fluorophthalic anhydride, cobalt chloride hexahydrate, copper chloride dehydrate, pitch coke activated carbon and urea which are as raw materials and ammonium molybdate which is used as a catalyst are uniformly ground in a glass mortar and then are placed in a muffle furnace for solid phase sintering to obtain a target product. The method has a simple preparation process, low cost, easily controlled preparation conditions, a short synthesis cycle and uniform compositions. The composite material prepared by the method can increase the ion activation surface area and accelerate electron transport. The high specific surface area of the pitch coke activated carbon, the certain catalytic properties of a pore structure and a microcrystalline structure and the mutual competition and synergistic effects of the bimetal affect the catalytic performance of the composite material together, improve the electrochemical performance of the lithium thionyl chloride electrode material, and reduce contact resistance between interfaces.

Description

technical field [0001] The invention relates to the technical field of lithium batteries, in particular to a mononuclear fluorine-substituted bimetallic phthalocyanine complex / activated carbon lithium thionyl chloride battery catalytic material and a preparation method thereof. Background technique [0002] The use of energy marks the development and progress of human civilization, which has also become an indispensable material condition for social development. According to relevant reports, 70% of the energy consumption in the world today comes from fossil fuels and some non-renewable resources. However, unrestrained exploitation and use have caused an energy crisis. At the same time, the gases harmful to the environment produced during the combustion of fossil fuels have seriously affected human development. People have paid more and more attention to the idea of ​​changing the unreasonable energy structure and seeking an energy path suitable for the sustainable developm...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/90H01M4/88H01M6/14
CPCY02E60/50
Inventor 许占位关伟伟李康孔硌马冲黄剑锋沈学涛杨军
Owner SHAANXI UNIV OF SCI & TECH
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