Insulating and heat conduction material for power battery of new-energy vehicle and preparation method of insulating and heat conduction material
A new energy vehicle and power battery technology, applied in the field of composite materials, can solve the problems of poor material performance stability, unenvironmental use, safety hazards, etc., to achieve excellent mechanical properties, better thermal conductivity, and avoid oxidation effects.
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Embodiment 1
[0031] A method for preparing an insulating and heat-conducting material for a power battery of a new energy vehicle, comprising the following preparation method:
[0032] Preparation of the intermediate product in step S1: under a nitrogen atmosphere, add 100 g of tetrahydrophthalimide and 113 g of dienestrol into a three-necked flask equipped with a reflux condenser and an electric stirrer, and then add dimethyl ethylene Sulfone 1000g, reflux and stir reaction at 120°C for 10 hours, then spin evaporate to remove the solvent to obtain an intermediate product;
[0033] Step S2 Fluorine-containing fluorene polycondensate based on phthalimide: add 150 g of 2,7-dibromo-9,9-difluorofluorene, 100 g of intermediate product, and 40 g of cesium carbonate into a three-necked flask connected with a water separator , add 1000g of dimethyl sulfoxide and 400g of toluene, heat the reaction system to 110°C, stir and react for 3 hours under the protection of nitrogen, remove the water and tol...
Embodiment 2
[0039] A method for preparing an insulating and heat-conducting material for a power battery of a new energy vehicle, comprising the following preparation method:
[0040] Preparation of the intermediate product in step S1: under a helium atmosphere, add 100 g of tetrahydrophthalimide and 113 g of dienestrol into a three-necked flask equipped with a reflux condenser and an electric stirrer, and then add N, 1100 g of N-dimethylformamide was reacted under reflux and stirring at 122°C for 10.5 hours, and then the solvent was removed by rotary evaporation to obtain an intermediate product;
[0041] Step S2 Phthalimide-based fluorine-containing fluorene condensation polymer: Add 150 g of 2,7-dibromo-9,9-difluorofluorene, 100 g of intermediate product, and 43 g of sodium hydride into a three-necked flask connected with a water separator , add 1100g of dimethyl sulfoxide and 450g of toluene, heat the reaction system to 113°C, stir and react for 3.5 hours under the protection of nitro...
Embodiment 3
[0047] A method for preparing an insulating and heat-conducting material for a power battery of a new energy vehicle, comprising the following preparation method:
[0048] Preparation of the intermediate product in step S1: under a neon gas atmosphere, add 100 g of tetrahydrophthalimide and 113 g of dienestrol into a three-necked flask equipped with a reflux condenser and an electric stirrer, and then add N- Methylpyrrolidone 1300g, refluxed and stirred at 125°C for 11 hours, then rotary evaporated to remove the solvent to obtain an intermediate product;
[0049] Step S2 fluorine-containing fluorene polycondensate based on phthalimide: Add 150 g of 2,7-dibromo-9,9-difluorofluorene, 100 g of intermediate product, and 50 g of potassium tert-butyl alkoxide to the In the three-necked flask, add 1300g of dimethyl sulfoxide and 500g of toluene, heat the reaction system to 115°C, stir and react for 4 hours under the protection of nitrogen, remove the water and toluene generated durin...
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