High-performance resin for electrophoretic paint and synthesis method of resin

A high-performance, electrophoretic paint technology, applied in the field of resins, can solve the problems of lack of oleophobicity, lack of film hardness and wear resistance, and lack of large-scale industrialization, so as to improve hydrophobicity and chemical resistance. quality, excellent anti-corrosion properties, improved longevity and durability

Active Publication Date: 2019-07-05
GUANGZHOU SYSMYK NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

After the resin emulsion of the present invention is formulated into a cathodic electrophoretic coating varnish to form a film, the contact angle between the coating film and water is 100-120°, which greatly improves the hydrophobicity, weather resistance and decorative properties of the water-based cathodic electrophoretic coating; but the patent The provided resin emulsion has a hydrophobic angle of 100-120°, does not have oleophobic properties, and does not involve the hardness and wear resistance of the paint film, and does not have the value of large-scale industrial promotion

Method used

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  • High-performance resin for electrophoretic paint and synthesis method of resin
  • High-performance resin for electrophoretic paint and synthesis method of resin
  • High-performance resin for electrophoretic paint and synthesis method of resin

Examples

Experimental program
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Effect test

Embodiment 1

[0046] A kind of resin provided by the present invention, named as F11 resin, comprises the following components by weight: butyl acrylate 673g, silicone oil 590g, diethylene glycol hexyl ether 145g, peroxy-2-ethylhexanoic acid tert-butyl ester 50g , methyl methacrylate 940g, hexafluorobutyl methacrylate 84g, hydroxyethyl methacrylate 1000g, dimethylaminoethyl methacrylate 470g, ethylene glycol butyl ether 565g, ethylene glycol hexyl ether 105g, acetyl Acetylated modified acrylic acid self-crosslinking monomer 175g, isopropanol 1135g.

[0047] The resin is prepared by the following method:

[0048] 1) Weigh 1135g of isopropanol and 226g of ethylene glycol butyl ether, mix them evenly, add them into the reaction kettle, and heat up to 82-84°C;

[0049] 2) Weigh 27.5g of tert-butyl peroxy-2-ethylhexanoate and place it in a beaker, and add 658g of methyl methacrylate, 700g of hydroxyethyl methacrylate, and 329g of dimethylaminoethyl methacrylate , 122.5g acetoacetylated modifie...

Embodiment 2

[0055] A kind of resin provided by the present invention, named as F22 resin, comprises the following components by weight: butyl acrylate 713g, silicone oil 620g, diethylene glycol hexyl ether 139g, peroxy-2-ethylhexanoic acid tert-butyl ester 45g , methyl methacrylate 980g, hexafluorobutyl methacrylate 78g, hydroxyethyl methacrylate 1060g, dimethylaminoethyl methacrylate 490g, ethylene glycol butyl ether 540g, ethylene glycol hexyl ether 95g, acetyl Acetylation-modified acrylic acid self-crosslinking monomer 186g, isopropanol 795g.

[0056] The resin is prepared by the following method:

[0057] 1) Weigh 795g of isopropanol and 270g of ethylene glycol butyl ether, mix them evenly, add them to the reaction kettle, and heat up to 82-84°C;

[0058] 2) Weigh 29.25 g of tert-butyl peroxy-2-ethylhexanoate and place it in a beaker, and add 784 g of methyl methacrylate, 848 g of hydroxyethyl methacrylate, and 392 g of dimethylaminoethyl methacrylate, 148.8g acetoacetylated modifie...

Embodiment 3

[0064] Another kind of resin provided by the present invention is called F33 resin, and this resin is made of the following components by weight: butyl acrylate 693g, silicone oil 606g, diethylene glycol hexyl ether 142.2g, peroxide-2-ethyl tert-butyl caproate 47.52g, methyl methacrylate 964.8g, hexafluorobutyl methacrylate 81g, hydroxyethyl methacrylate 1033.2g, dimethylaminoethyl methacrylate 481.2g, butyl glycol ether 553.2g, 100.8g of ethylene glycol hexyl ether, 181.8g of acrylic acid self-crosslinking monomer modified by acetoacetylation, and 1115.28g of isopropanol.

[0065] The resin is prepared by the following method:

[0066] 1) Use a 2000ml plastic cup to weigh 1115.28g of isopropanol and 282.6g of ethylene glycol butyl ether. After mixing evenly, add it to a 10L single-layer glass reactor, turn on the heating button, raise the temperature to 82-84°C, and adjust the speed at About 200r / min.

[0067] 2) Weigh 28.224g of the medium-temperature initiator tert-butyl ...

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Abstract

The invention discloses a high-performance resin for electrophoretic paint and a synthesis method of the resin, and is aimed at providing the high-hardness and high-wear-resistance resin with lastinghydrophoby and lipophobicity for the electrophoretic paint. The resin is technically characterized by being mainly prepared from, by weight, 673-713 parts of butyl acrylate, 590-620 parts of siliconeoil, 139-145 parts of ethylene glycol monohexyl ether, 45-50 parts of tert-butylperoxy-2-ethylhecanoat, 940-980 parts of methyl methacrylate, 78-84 parts of hexafluorobutyl methacrylate, 1000-1060 parts of hydroxyethyl methylacrylate, 470-490 parts of ethyl methacrylate, 540-565 parts of butyl cellosolve, 95-105 parts of hexyl cellosolve, 175-186 parts of an acrylic acid self-crosslinking monomeracetylated and modified by acetyl and 795-1135 parts of isopropanol. The invention belongs to the technical field of resin.

Description

technical field [0001] The invention discloses a resin, specifically a high-performance resin for electrophoretic paint, and belongs to the technical field of resins. Background technique [0002] With the continuous progress of society, people's environmental protection requirements for materials are getting higher and higher. At present, in the application field of traditional industrial coatings in our country, most of them use solvent-based coatings. During the construction and curing process, the volatilization of solvents is easy to cause environmental pollution, and it is flammable and explosive, which brings a lot to transportation, storage, especially construction. insecure. Water-based coatings have many distinctive features and advantages. They do not contain or contain only a small amount of solvents, are non-toxic, environmentally friendly, and safe. Especially after the emergence of electrophoretic coating technology, water-based electrophoretic coatings have ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F283/12C08F292/00C08F220/28C08F2/06C09D5/44C09D5/08C09D151/08C09D151/10
CPCC08F283/12C08F292/00C09D5/08C09D5/4411C09D151/085C09D151/10C08F220/281
Inventor 蒋卫中
Owner GUANGZHOU SYSMYK NEW MATERIAL TECH CO LTD
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