Flexible electromagnetic wave shielding material, electromagnetic wave shielding type circuit module comprising same and electronic device furnished with same
A shielding material and electromagnetic wave technology, applied in shielding materials, magnetic field/electric field shielding, electrical equipment structural parts, etc., can solve the problems of difficult heat release, low durability, low component function, etc., and achieve excellent heat dissipation performance and flexibility. and excellent wrinkle/recovery properties, preventing deterioration of electromagnetic wave shielding performance
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Embodiment 1
[0105] In 85 g of dimethylacetamide and acetone at a weight ratio of 70:30, 12 g of polyvinylidene fluoride was dissolved at a temperature of 80° C. for 6 hours using a magnetic bar to prepare a spinning solution. Put the spinning solution into the solution box of the electrospinning device, and spit it out at a speed of 20 μl / min / hole. At this time, the temperature in the spinning section is kept at 30°C, the humidity is kept at 50%, and the distance between the collector and the tip of the spinning nozzle is 20cm. A high voltage generator is used on the collector to give the spinning nozzle assembly (SpinNozzle Pack) A voltage of 40kV and an air pressure of 0.03MPa were applied to the nozzles of each spinning group to produce a PVDF fiber web with an average diameter of 400nm. Then, in order to dry the solvent and moisture present in the fiber web, at a temperature of 140° C. and 1 kgf / cm 2 Heat and pressure are applied to carry out the calendering process.
[0106] Then, ...
Embodiment 2
[0109] In 88 g of dimethylacetamide and acetone mixed at a weight ratio of 70:30, 12 g of polyvinylidene fluoride was dissolved at a temperature of 80° C. for 6 hours using a magnetic bar to prepare a spinning solution. In the spinning solution, as a conductive filler, spherical silver particles with an average particle diameter of 1.3 μm are mixed so that the volume ratio of polyvinylidene fluoride to silver particles is 1:0.2, accounting for 16.7% of the total volume of the final fiber part, Then, it was dispersed for 12 hours using an ultrasonic disperser. Put the spinning solution into the solution tank of the electrospinning device, stir the solution with an impeller, and spit it out at a speed of 20 μl / min / hole. At this time, the temperature in the spinning section is kept at 30°C, the humidity is kept at 50%, the distance between the collector and the tip of the spinning nozzle is 20cm, and a high voltage generator is used to apply a voltage of 40kV to the spinning nozz...
Embodiment 3~12
[0112] It carried out and produced similarly to Example 2, but as shown in Table 1 or Table 2 below, the content and particle diameter of a conductive filler were changed, and the conductive fiber web shown in Table 1 or Table 2 below was manufactured.
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