Treatment method for waste water containing fluorine
A treatment method and technology for wastewater, which are applied in energy wastewater treatment, water/sludge/sewage treatment, ion-exchanged water/sewage treatment, etc., can solve the problems of complex resin loading modification process, difficult industrial application, poor adsorption effect, etc. , to achieve the effect of closed loop treatment, low cost and easy operation
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[0062] Example 1
[0063] according to figure 1 The process flow chart shown for treating fluorine-containing wastewater, figure 1 It is a flow chart of the fluorine-containing wastewater treatment process provided by the embodiment of the present invention. The specific treatment steps include:
[0064] Add 17.5g AlCl to 10L fluorine-containing wastewater (fluoride ion concentration 250mg / L, pH value 5.0) 3 , Stir and mix for 10 minutes to obtain 10L of adsorbed liquid. Load 40g of chelating resin of formula (i) structure (n=1000) into the ion exchange column, and pass the adsorbed liquid through the exchange column at a flow rate of 5 mL / min. The residence time of the adsorbed liquid in the exchange column is 10 min. Outflow curve like figure 2 As shown, figure 2 It is the adsorption outflow curve of Example 1 of the present invention.
[0065] After the resin is saturated with adsorption, add 0.5 mol / L sodium hydroxide solution to the ion exchange column at a flow rate of 1 m...
Example Embodiment
[0067] Example 2
[0068] The difference from Example 1 is that the ion exchange column in Example 2 is a chelating resin (m=1200) of formula (ii). The experimental results show that when the fluoride ion concentration in the effluent penetrates (that is, the fluoride ion concentration is higher than 6 mg / L), the fluorine adsorption capacity of the chelating resin can reach 45.8 mg / g (dry resin).
Example Embodiment
[0069] Example 3
[0070] The difference from Example 1 is that AlCl is added to 10L of fluorine-containing wastewater 3 The mass of sodium hydroxide is 2.9g. During the adsorption step, the adsorption solution passes through the exchange column at a flow rate of 1 mL / min; during the desorption step, the concentration of sodium hydroxide solution passes through the exchange column at a flow rate of 0.5 mL / min. Experimental results show that the adsorption capacity of chelating resin for fluorine can reach 54.8 mg / g (dry resin).
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