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Preparing method of polysulfide rubber sealing ring

A technology of polysulfide rubber and liquid polysulfide rubber, which is applied in the field of sealing materials, can solve the problems of shortening the service life of sealing rings, low strength, and poor flame retardancy, so as to avoid flammability, good flame retardancy, and sealing effect Good results

Inactive Publication Date: 2019-08-09
苏州松之叶精密机械配件有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] The sealing ring is a material or part that prevents fluid or solid particles from leaking from adjacent joint surfaces and prevents impurities such as external dust or water from intruding into the internal parts of the machine equipment. The sealing ring generally works under certain pressure and temperature conditions. Sealing rings with different structures and materials have different sealing effects under different conditions. Although they have excellent bonding, sealing, aging resistance and mechanical properties, the current two-component polysulfide sealing materials are not convenient for construction. It is easy to burn and has poor flame retardancy; once the seal of the sealing ring fails, it will directly affect the use of the equipment
Polysulfide rubber is a synthetic rubber obtained by polycondensation of dihalogenated alkanes and polysulfides of alkali metals or alkaline earth metals. It has excellent oil resistance and solvent resistance, but its strength is not high, its aging resistance is not good, and its processing performance is not good.
[0003] At present, due to the poor aging resistance of the rubber sealing ring, the service life of the sealing ring will be shortened. At the same time, the aging sealing ring will bond with the metal, the mechanical properties will deteriorate, and the thermal stability will drop sharply. Therefore, a kind of Preparation method of rubber sealing ring capable of flame retardancy, aging resistance and good sealing effect

Method used

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  • Preparing method of polysulfide rubber sealing ring

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A preparation method of polysulfide rubber sealing ring, comprising:

[0039] Step 1, weighing raw materials: weighing each raw material component according to the following parts by mass: 50 parts of liquid polysulfide rubber; 3 parts of propionate; 6 parts of epoxy group; 12 parts of bisphenol A epoxy resin; 15 parts of plasticizer; 2 parts of rosin resin; 2 parts of softener; 5 parts of carbon black; 10 parts of mixture of antimony trioxide and flame-retardant graphite; 1 part of manganese dioxide; 5 parts of filler; average particle size of flame-retardant graphite It is 1800 mesh, and the average particle size of antimony trioxide is 1 micron.

[0040] Step 2, modification of liquid polysulfide rubber: under inert gas (nitrogen) conditions, polysulfide rubber is capped and modified with propionate and epoxy groups, and then mixed with bisphenol A epoxy resin to obtain modified polysulfide rubber. sulfur rubber;

[0041] Step 3, pretreatment of raw materials: Afte...

Embodiment 2

[0046] A preparation method of polysulfide rubber sealing ring, comprising:

[0047] Step 1, weighing of raw materials: weighing of each raw material component according to the following parts by mass: 50 parts of liquid polysulfide rubber; 4 parts of propionate; 6 parts of epoxy group; 10 parts of bisphenol A epoxy resin; 15 parts of plasticizer; 10 parts of terpene resin; 10 parts of softener; 15 parts of carbon black; 10 parts of a mixture of antimony trioxide and flame-retardant graphite; 10 parts of lead dioxide; 20 parts of filler; The particle size is 3000 mesh, and the average particle size of antimony trioxide is 0.3 micron.

[0048] Step 2, modification of liquid polysulfide rubber: under inert gas (nitrogen) conditions, polysulfide rubber is capped and modified with propionate and epoxy groups, and then mixed with bisphenol A epoxy resin to obtain modified polysulfide rubber. sulfur rubber;

[0049] Step 3, pretreatment of raw materials: After adding a plasticizer...

Embodiment 3

[0054] A preparation method of polysulfide rubber sealing ring, comprising:

[0055]Step 1, weighing of raw materials: weighing of each raw material component according to the following parts by mass: 60 parts of liquid polysulfide rubber; 4 parts of propionate; 6 parts of epoxy group; 10 parts of bisphenol A epoxy resin; 5-15 parts of plasticizer; 7 parts of mixture of rosin resin and terpene resin; 8 parts of softener; 6 parts of carbon black; 8 parts of mixture of antimony trioxide and flame-retardant graphite; 8 parts of zinc peroxide; 17 parts of filler parts; the average particle size of flame-retardant graphite is 3000 mesh, and the average particle size of antimony trioxide is 0.7 microns.

[0056] Step 2, modification of liquid polysulfide rubber: under inert gas (nitrogen) conditions, polysulfide rubber is capped and modified with propionate and epoxy groups, and then mixed with bisphenol A epoxy resin to obtain modified polysulfide rubber. sulfur rubber;

[0057] ...

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Abstract

The invention discloses a preparing method of a polysulfide rubber sealing ring. The preparing method comprises the steps of 1, weighing raw materials, wherein liquid polysulfide rubber, propionate, epoxy groups, bisphenol-A epoxy resin, a plasticizer, a tackifier, a softener, a reinforcing agent, a flame retardant, a vulcanizing agent and a filler are weighed according to the following mass fraction; 2, modifying the liquid polysulfide rubber, wherein after the polysulfide rubber is subjected to end-capped modification through the propionate and the epoxy groups, modified polysulfide rubber is obtained; 3, pretreating the raw materials, wherein after the plasticizer is added into the liquid modified polysulfide rubber, plastifying is conducted on an open mill; 4, preparing a premix material, wherein the tackifier, the softener, the reinforcing agent, the flame retardant and a sizing material are uniformly mixed in a mixing mill, and then the filler and the vulcanizing agent are addedto continue mixing; 5, conducting vulcanization molding, wherein a mixed rubber compound is added into a mold of vulcanization equipment for vulcanization to obtain a vulcanized sealing ring green body; 6, conducting ageing resistance and trimming treatment.

Description

technical field [0001] The invention relates to the field of sealing materials, in particular to a preparation method of a polysulfide rubber sealing ring. Background technique [0002] The sealing ring is a material or part that prevents fluid or solid particles from leaking from adjacent joint surfaces and prevents impurities such as external dust or water from intruding into the internal parts of the machine equipment. The sealing ring generally works under certain pressure and temperature conditions. Sealing rings with different structures and materials have different sealing effects under different conditions. Although they have excellent bonding, sealing, aging resistance and mechanical properties, the current two-component polysulfide sealing materials are not convenient for construction. It is easy to burn and has poor flame retardancy; once the seal of the sealing ring fails, it will directly affect the use of the equipment. Polysulfide rubber is a synthetic rubber...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L81/04C08L63/00C08K13/02C08K3/04C08K3/22C08K3/18
CPCC08K2003/2234C08K2003/2262C08L81/04C08L2201/02C08L2201/08C08L63/00C08K13/02C08K3/04C08K3/22C08K3/2279C08K3/18
Inventor 林佳佳雷振天
Owner 苏州松之叶精密机械配件有限公司
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