A kind of thermal interface composite material and its preparation method and application

A composite material and thermal interface technology, which is applied in the field of thermal interface composite materials and its preparation, can solve problems such as difficult processing, poor toughness, and reduced mechanical properties, and achieve excellent thermal conductivity and mechanical properties, high glass transition temperature, and improved surface area. The effect of external thermal conductivity

Active Publication Date: 2022-03-11
SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] However, in the prior art, thermal interface materials based on compound powder-type thermally conductive fillers have problems such as difficult processing and high cost, and materials with a high proportion of compound powder and good thermal conductivity often have reduced mechanical properties, poor toughness, and are not durable Corrosion; the thermal interface material with carbon nanotubes has excellent performance, but the preparation process of carbon nanotubes is complicated and the cost is high, which is not suitable for industrial application; graphene, as a two-dimensional thermal conductivity material, has anisotropic thermal conductivity, so based on Graphene thermal interface materials exhibit good in-plane thermal conductivity, but low out-of-plane thermal conductivity, making it difficult to achieve good out-of-plane heat dissipation performance

Method used

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  • A kind of thermal interface composite material and its preparation method and application
  • A kind of thermal interface composite material and its preparation method and application
  • A kind of thermal interface composite material and its preparation method and application

Examples

Experimental program
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Effect test

Embodiment 1

[0067] This embodiment provides a thermal interface composite material, and the specific preparation method includes the following steps:

[0068](1) Preparation of carbon fiber skeleton: Mix 0.8 g of carbon fiber powder after surface hydrophilic treatment with an aqueous solution of binder, add appropriate amount of water to make a 3 mL suspension, first stir with a magnet, and then vacuum mix at a speed of 2000 rpm. Feed for 20 minutes to obtain a carbon fiber suspension with a volume percentage of carbon fibers of 12%; then freeze the carbon fiber suspension with liquid nitrogen and dry it in vacuum for 24 hours to obtain the carbon fiber skeleton in which the carbon fibers are arranged in a single orientation;

[0069] (2) Preparation of thermal interface composite material: The carbon fiber skeleton obtained in step (1) is completely immersed in epoxy resin, then placed in a vacuum drying oven, and vacuum filtered at 40°C for 3 hours; then gradient temperature rises and so...

Embodiment 2

[0073] This embodiment provides a thermal interface composite material, and the specific preparation method includes the following steps:

[0074] (1) Preparation of carbon fiber skeleton: Mix 0.8 g of carbon fiber powder after surface hydrophilic treatment with an aqueous solution of binder, add appropriate amount of water to make a 3 mL suspension, first stir with a magnet, and then vacuum mix at a speed of 1500 rpm. 10 min, the volume percentage of carbon fiber obtained was 12% of the carbon fiber suspension; then the carbon fiber suspension was frozen with liquid nitrogen and vacuum-dried for 12 hours to obtain the carbon fiber skeleton in which the carbon fibers were arranged in a single orientation;

[0075] (2) Preparation of thermal interface composite material: The carbon fiber skeleton obtained in step (1) is completely immersed in epoxy resin, then placed in a vacuum drying oven, and vacuum filtered at 30°C for 2 hours; then gradient temperature rises and solidifies ...

Embodiment 3

[0077] This embodiment provides a thermal interface composite material, and the specific preparation method includes the following steps:

[0078] (1) Preparation of carbon fiber skeleton: Mix 0.8 g of carbon fiber powder after surface hydrophilic treatment with an aqueous solution of binder, add appropriate amount of water to make a 3 mL suspension, first stir with a magnet, and then vacuum mix at a speed of 1800 rpm. 15min, the volume percentage of carbon fiber obtained was 12% of the carbon fiber suspension; then the carbon fiber suspension was frozen with liquid nitrogen and vacuum-dried for 20h to obtain the carbon fiber skeleton in which the carbon fibers were arranged in a single orientation;

[0079] (2) Preparation of thermal interface composite material: The carbon fiber skeleton obtained in step (1) is completely immersed in epoxy resin, then placed in a vacuum drying oven, and vacuum filtered at 35°C for 2.5h; then the temperature is gradually increased After curin...

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Abstract

The invention provides a thermal interface composite material and its preparation method and application. The thermal interface composite material includes a carbon fiber skeleton, and a polymer matrix filling and covering the carbon fiber skeleton; the carbon fibers in the carbon fiber skeleton are in a single orientation arrangement. In the present invention, the oriented carbon fibers establish a thermal conduction channel in the vertical direction of the thermal interface composite material, and the carbon fibers contact and connect with each other in this direction, which reduces the overall interface thermal resistance of the material and greatly improves the thermal interface composite material. Thermal conductivity; and the synergy between the carbon fiber skeleton and the polymer matrix makes the thermal interface composite material have a high glass transition temperature and good mechanical properties such as strength and toughness. The thermal interface composite material provided by the invention has excellent thermal conductivity and mechanical properties, and the preparation method is simple and easy to operate, and is a new type of thermal conductive material with large-scale industrial production prospects.

Description

technical field [0001] The invention belongs to the technical field of polymer composite materials, and in particular relates to a thermal interface composite material and its preparation method and application. Background technique [0002] The miniaturization and high integration of electronic components not only endow electronic products with more functions and higher efficiency, but also greatly increase the working power per unit volume in electronic products, which brings serious heat dissipation problems. The dissipation and heat generation of electronic components will directly lead to an increase in the temperature and thermal stress of electronic equipment, which poses a serious threat to the reliability of microelectronic equipment. The most important heat dissipation design of electronic components is to rely on thermal interface materials to connect chips with substrates and substrate heat dissipation systems. The industry generally believes that the bottleneck ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L63/00C08K9/00C08K7/06C08J5/24
CPCC08J5/24C08J2363/00C08K9/00C08K7/06
Inventor 孙蓉马加珂曾小亮么依民许建斌
Owner SHENZHEN INST OF ADVANCED TECH CHINESE ACAD OF SCI
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