High-strength, high-electrical-conductivity and high-heat-conductivity copper-silver series alloy wire material and preparation method thereof

An alloy wire, high electrical conductivity technology, applied in the field of high strength, high electrical conductivity and high thermal conductivity copper-silver alloy wire and its preparation, can solve the problems of disordered grain orientation, reduced electrical conductivity, large difference in solid solubility, etc. Enhanced cooling effect

Active Publication Date: 2019-08-20
HENAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

It has the following limitations: due to the traditional copper-silver alloy bar preparation process, it is necessary to melt and cast the ingot first, then perform machining on the ingot such as peeling and removing the riser, and then carry out secondary heating plastic deformation, and finally through multiple Improvement of microstructure and properties of rod after drawing and heat treatment in one pass
Different from other copper-based materials, silver itself has excellent electrical conductivity, and the electrical conductivity is less reduced after being added to copper. At the same time, other microalloying elements such as Cr, Zr, and Nb can also be added to copper-based materials. Under these conditions, the solid solubility of microalloying elements in copper has a large difference, which can play a significant effect of aging precipitation strengthening. Casting, hot-cold combined continuous casting process, it is difficult to form a stable and almost parallel crystallization solidification trend along the horizontal continuous casting direction at the front of the liquid-solid interface, so that it is impossible to achieve a directional solidification structure with few grain boundaries, or even a single crystal structure. Microstructure plays an important role in improving the electrical and thermal conductivity of alloys
In addition, after the copper-silver alloy is continuously casted by hot-cold combination, solution treatment, drawing treatment and aging treatment are carried out in sequence. The front of the liquid-solid interface is easy to form a V-shaped interface due to the existence of excessive undercooling, and the solidification structure cannot be realized. Oriented growth, resulting in subsequent solid solution, drawing, and aging treatments, but the final performance will be due to the inhomogeneous structure and performance, disordered grain orientation and other problems caused by the inheritance of the congenital cast structure
The copper-silver alloys in the prior art do not undergo the steps of solid solution treatment, drawing treatment and aging treatment in sequence after hot-type continuous casting

Method used

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  • High-strength, high-electrical-conductivity and high-heat-conductivity copper-silver series alloy wire material and preparation method thereof

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Effect test

Embodiment 1

[0036] The preparation method of the high-strength, high-conductivity and high-thermal-conductivity copper-silver alloy wire rod of this embodiment comprises the following steps:

[0037] (1) Batching and smelting: Select No. 1 electrolytic copper and high-purity silver particles as raw materials, and carry out batching according to the mass ratio of copper to silver in the copper-silver alloy wire rod as 96:4; the purity of No. 1 electrolytic copper is 99.95%, and the high-purity silver The purity of the particles is 99.99%; the prepared raw materials are put into a high-purity graphite crucible for heating and melting, and the melting temperature is controlled at 1100°C; the melting process is carried out in a thermal crystallizer horizontal continuous solidification device;

[0038] (2) Hot-type horizontal continuous casting: hot-type horizontal continuous casting is carried out in a hot-type crystallizer horizontal continuous solidification device, and the melt is heated an...

Embodiment 2

[0041] The preparation method of the high-strength, high-conductivity and high-thermal-conductivity copper-silver alloy wire rod of this embodiment comprises the following steps:

[0042] (1) Batching and smelting: use No. 1 electrolytic copper, high-purity silver particles and high-purity chromium particles as raw materials, and carry out batching according to the mass ratio of copper, silver and chromium in the copper-silver alloy wire rod as 96.5:2.0:1.5; among them, No. 1 The purity of electrolytic copper is 99.95%, the purity of high-purity silver particles is 99.99%, and the purity of high-purity chromium particles is 99.95%. Put the prepared raw materials into a high-purity graphite crucible for heating and melting, and the melting temperature is controlled at 1200°C; The process is carried out in a thermal crystallizer horizontal continuous solidification device;

[0043] (2) Hot-type horizontal continuous casting: hot-type horizontal continuous casting is carried out ...

Embodiment 3

[0046] The preparation method of the high-strength, high-conductivity and high-thermal-conductivity copper-silver alloy wire rod of this embodiment comprises the following steps:

[0047] (1) Ingredients and smelting: use No. 1 electrolytic copper, high-purity silver particles, high-purity chromium particles, zirconium particles and niobium particles as raw materials, and the mass ratio of copper to silver in copper-silver alloy wire is 99.86:0.1:0.02:0.01 : 0.01 for batching; wherein the purity of No. 1 electrolytic copper is 99.95%, the purity of high-purity silver particles is 99.99%, the purity of high-purity chromium particles is 99.95%, the purity of zirconium particles is 99.5%, and the purity of niobium particles is 99.95%; Put the prepared raw materials into a high-purity graphite crucible for heating and melting, and the melting temperature is controlled at 1300°C; the melting process is carried out in a thermal crystallizer horizontal continuous solidification device...

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Abstract

The invention relates to a high-strength, high-electrical-conductivity and high-heat-conductivity copper-silver series alloy wire material and a preparation method thereof and belongs to the technicalfield of metal material preparation. The preparation method for the high-strength, high-electrical-conductivity and high-heat-conductivity copper-silver series alloy wire material comprises the following steps of (1), batching and smelting; (2), hot type horizontal continuous casting, specifically, a melt adopts the hot type horizontal continuous casting to obtain a blank material, a crystallizerof the hot type horizontal continuous casting is a hot type crystallizer, the temperature of the melt inside the hot type crystallizer is maintained above the melting point of the copper-silver series alloy wire material, and a cooling method of the hot type horizontal continuous casting is twice cooling and is water cooling; and (3), combined thermomechanical treatment, specifically, solid solution treatment, drawing plastic deformation treatment and aging heat treatment are performed on the blank material in sequence, and the high-strength, high-electrical-conductivity and high-heat-conductivity copper-silver series alloy wire material is obtained. By means of the preparation method for the high-strength, high-electrical-conductivity and high-heat-conductivity copper-silver series alloywire material, improvement of casting-state structures is facilitated, the electrical conductivity, the heat conductivity and the tensile strength of copper-silver alloy are improved, and continuousproduction can be realized.

Description

technical field [0001] The invention belongs to the technical field of metal material preparation, and in particular relates to a high-strength, high-conductivity and high-heat-conduction copper-silver alloy wire and a preparation method thereof. Background technique [0002] Copper-silver alloys are often used as key materials for signal transmission in electronic communication equipment. With the development of copper alloy profiles in the direction of high transmission rate, high-fidelity, and high-definition, the strength, electrical conductivity, thermal conductivity, and organizational consistency of materials And uniformity, etc. put forward higher requirements. The traditional copper-silver alloy bar preparation methods are: melting, semi-continuous casting, extrusion or forging, multi-pass drawing, heat treatment, etc. It has the following limitations: due to the traditional copper-silver alloy bar preparation process, it is necessary to melt and cast the ingot fir...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/00C22C1/02C22F1/08B22D11/00
CPCB22D11/004B22D11/005C22C1/02C22C9/00C22F1/002C22F1/08
Inventor 周延军宋克兴郭保江张彦敏孔令宝国秀花康军伟杨冉张学宾刘海涛李韶林程楚
Owner HENAN UNIV OF SCI & TECH
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