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Layered polymer-based composite thermoelectric material

A technology of thermoelectric materials and polymers, applied in the direction of liquid material additive processing, processing and manufacturing, additive processing, etc., can solve the problems of poor thermoelectric properties of polymer-based composite materials, achieve good thermoelectric properties, huge application prospects, and preparation The effect of simple process

Inactive Publication Date: 2019-08-27
SHANGHAI INST OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, so far, the research on the preparation of polymer-based composite thermoelectric materials by solution 3D printing technology has basically not been reported. The only research report so far is that our team prepared single-layer tungsten carbide / polylactic acid composite thermoelectric materials by solution 3D printing technology in 2018. (Du Y, et al. Flexible n-type tungsten carbide / polylactic acid thermoelectric composites fabricated by additive manufacturing. Coatings, 2018, 8:25), but the thermoelectric properties of the prepared polymer-based composites are poor, and it is urgent to improve the polymerization Thermoelectric properties of material-based composites to meet the production needs of flexible thermoelectric devices

Method used

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  • Layered polymer-based composite thermoelectric material
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  • Layered polymer-based composite thermoelectric material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] (1) Ingredients: Add polylactic acid to the chloroform solution, the mass-volume ratio of polylactic acid to chloroform is 0.1g / mL, stir for 2h at a rate of 100-400 rpm, and wait until it is fully dissolved, Then add bismuth telluride powder, the mass ratio of polylactic acid to bismuth telluride powder is 0.25, continue to stir at the original rate for 1h, until the bismuth telluride powder is evenly dispersed in the solution, to obtain solution A; add polylactic acid to the chloroform In the solution, the mass-volume ratio of polylactic acid to chloroform is 0.1g / mL. Stir at a rate of 100-400 rpm for 2h. After it is fully dissolved, add silver powder. The mass ratio of polylactic acid to silver powder is 0.2 , Continue to stir at the original rate for 1 hour, until the silver powder is evenly dispersed in the solution to obtain solution B;

[0027] (2) Sample loading and printing: Load solution A into the solution 3D printer for printing;

[0028] (3) Print the second lay...

Embodiment 2

[0031] (1) Ingredients: Add natural rubber to the chloroform solution, the mass-volume ratio of natural rubber to chloroform is 0.02g / mL, stir for 2h at a rate of 100-400 revolutions / min, and after it is fully dissolved, Then add carbon black, the mass ratio of natural rubber to carbon black is 0.1, continue to stir at the original rate for 1h, until the carbon black powder is evenly dispersed in the solution to obtain solution A; add polylactic acid to the chloroform solution, polylactic acid The mass-volume ratio with chloroform is 0.1g / mL, stirring at a rate of 100-400 revolutions / min for 2h, after it is fully dissolved, then add nickel powder, the mass ratio of polylactic acid to nickel powder is 0.05, continue to Stir at the original rate for 1 hour until the silver powder is evenly dispersed in the solution to obtain solution B;

[0032] (2) Load solution A into the machine, adjust the parameters, and print out the first layer of material;

[0033] (3) Load solution B into t...

Embodiment 3

[0038] (1) Ingredients: Add natural rubber to the chloroform solution, the mass-volume ratio of natural rubber to chloroform is 0.02g / mL, stir for 2h at a rate of 100-400 revolutions / min, and after it is fully dissolved, Then add carbon black, the mass ratio of natural rubber to carbon black is 0.01, continue to stir at the original rate for 1h, until the carbon black powder is evenly dispersed in the solution to obtain solution A; add polylactic acid to the chloroform solution, polylactic acid The mass-volume ratio with chloroform is 0.1g / mL, stirring at a rate of 100-400 revolutions / min for 2h, after it is fully dissolved, then add nickel powder, the mass ratio of polylactic acid to nickel powder is 0.05, continue to Stir at the original rate for 1 hour until the nickel powder is evenly dispersed in the solution to obtain solution B; add the acrylonitrile-butadiene-styrene copolymer to the chloroform solution, the acrylonitrile-butadiene-styrene copolymer and The mass-to-volu...

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Abstract

The invention relates to a preparation method of a multilayer-layer layered polymer-based composite thermoelectric material. The multilayer-layer layered polymer-based composite thermoelectric material is prepared through a solution 3D printing technology for the first time. The preparation method comprises the following steps that firstly, a polymer is added into a solvent, stirring is conductedafter the solvent is fully dissolved, then an inorganic material is added, continuously stirring is conducted until the inorganic material is uniformly dispersed in a solution dissolved with the polymer, then the first-layer polymer-based composite thermoelectric material is printed through the solution 3D printing technology, then a second layer and a third layer until a N-layer polymer-based composite thermoelectric material are printed on the basis of the first layer, and finally the multi-layer polymer-based composite thermoelectric material is formed; the composition of the printed firstlayer, the second layer until the third layer of the N-layer polymer-based composite thermoelectric material can be the same or different as well. The method has the advantages of being simple in process, convenient to operate, suitable for mass production and the like; and the prepared multilayer-layer layered polymer-based composite material has excellent thermoelectric properties and has a wideapplication prospect and a wide market value in the fields of thermoelectric power generation and refrigeration devices.

Description

Technical field [0001] The invention belongs to the technical field of thermoelectric materials, and mainly relates to a preparation method of a multilayer layered polymer-based composite thermoelectric material. Background technique [0002] Electricity is closely related to the lives of modern people. At present, the supply of electric energy in my country is mainly from thermal power generation, which accelerates the depletion of fossil energy sources and also causes serious environmental pollution. Thermoelectric materials can achieve mutual direct conversion between thermal energy and electrical energy through the transport of carriers (electrons or holes) inside the solid, and are environmentally friendly functional materials. [0003] Thermoelectric devices made with traditional inorganic thermoelectric materials (such as bismuth telluride-based alloys, lead telluride-based alloys, etc.) have the disadvantages of being hard and difficult to bend, and can only be applied to h...

Claims

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Application Information

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IPC IPC(8): B29C64/106B33Y10/00B33Y70/00
CPCB29C64/106B33Y10/00B33Y70/00
Inventor 杜永陈甲庚
Owner SHANGHAI INST OF TECH