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Explosion-proof energy absorption sandwich material and preparation method thereof

A sandwich and foam plastic technology, applied in the preparation of explosion-proof and energy-absorbing sandwich materials, in the field of explosion-proof and energy-absorbing sandwich materials

Inactive Publication Date: 2019-09-13
QINGDAO AIR NEW MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] At present, the use of rigid isocyanate-based polyimide foam plastics for ballistic and explosion-proof energy-absorbing composite materials has not yet been reported.

Method used

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  • Explosion-proof energy absorption sandwich material and preparation method thereof
  • Explosion-proof energy absorption sandwich material and preparation method thereof
  • Explosion-proof energy absorption sandwich material and preparation method thereof

Examples

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preparation example Construction

[0043] see figure 1 , a flow chart of steps for a preparation method of an explosion-proof energy-absorbing sandwich material provided by the present invention, comprising the following steps:

[0044] Step S110: preparing an explosion-proof polyurea elastomer;

[0045] In some preferred embodiments, in the step of preparing the explosion-proof polyurea elastomer, the following steps are specifically included:

[0046] Step S111: In an inert gas environment, heat the polyether polyol to 95°C-100°C under stirring, dehydrate it under a vacuum of -0.1MPa for 1-15 hours, release the vacuum and cool down to below 40°C, add polyisocyanate, and React at 80°C for 2 hours, then lower the temperature to below 60°C, add propylene carbonate, stir to measure the NCO value, discharge the material, and filter to obtain the isocyanate-terminated semi-prepolymer component A: wherein, the polyether polyol and the The mass ratio of polyisocyanate is 100:(660~15);

[0047] Specifically, put th...

Embodiment 1

[0089] Preparation of explosion-proof polyurea elastomer:

[0090] The formula of explosion-proof polyurea elastomer is composed of A component and B component. A component is a prepolymer of polytetrahydrofuran ether glycol PTMG1000 and HMDI diisocyanate; B component is composed of amino polyether, aromatic amine chain extender and color pulp composition.

[0091] The composition and mass parts of A component and B component are as shown in Table 1:

[0092] Table 1 Example 1 spray polyurea explosion-proof elastomer components

[0093] A component parts by mass PTMG1000 100 HMDI 155 PC 12 B component parts by mass Jeffamine D-2000 30 THF-170 30 Jeffamine T-5000 5 E-100 20 Unilink 4200) 13 color paste 215

[0094] Among them, the -NCO content of the prepared prepolymer of component A is 16.55%, the solid content is ≥ 95%, the viscosity (25°C) is 800mPa·s, and the density (25°C) is 1.08-1.12g / mL; The...

Embodiment 2

[0106] Preparation of explosion-proof polyurea elastomer:

[0107] The formula of explosion-proof polyurea elastomer is composed of A component and B component. A component is a prepolymer of polytetrahydrofuran ether glycol PTMG1000 and IPDI diisocyanate; B component is composed of diamino polyether P-1000, polytetrahydrofuran ether Diol PTMG1000, aliphatic diamine and color paste composition.

[0108] The composition and mass parts of A component and B component are as shown in Table 3:

[0109] The performance parameter of table 3 embodiment 2 polyurea elastomers

[0110] A component parts by mass PTMG1000 100 IPDI 655 B component parts by mass PTMG-1000 45 P-1000 30 Aliphatic diamine Clearlink1000 20 color paste 5 catalyst 0.25

[0111] Among them, the -NCO content of the prepared prepolymer of component A is 10%, the solid content is ≥ 98%, the viscosity (25°C) is 800mPa·s, and the density (25°C) is 1.08-1....

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Abstract

A preparation method of an explosion-proof energy absorption sandwich material, provided by the invention, comprises the following steps: preparing an explosion-proof polyurea elastomer, preparing anisocyanate-based rigid polyimide foam, and spraying the explosion-proof polyurea elastomer on the surface of the isocyanate-based rigid polyimide foam to obtain the explosion-proof energy absorption sandwich material. The explosion-proof energy absorption sandwich material provided by the invention adopts the high-density polyimide rigid foam as a core material and the explosion-proof polyurea elastomer as a surface material, the high-density polyimide foam has the characteristics of light weight, low smoke density, temperature resistance, flame retardation, sound insulation and vibration damping, and is a high-performance energy absorption material, and the explosion-proof polyurea elastomer is both rigid and flexible, has the characteristics of explosion resistance, wear resistance, impact resistance and fatigue resistance, and is a novel antiballistic and explosion-proof material, so the explosion-proof energy absorption sandwich material obtained by compounding the core material with the surface material integrates various functions such as explosion proofing, energy absorption, sound insulation, vibration damping and noise reduction, has practical values in police equipment and explosion-proof energy absorption protective equipment, and can resist shock waves and debris generated by explosion.

Description

technical field [0001] The present invention relates to the technical field of special protective materials, in particular to a preparation method of an explosion-proof energy-absorbing sandwich material and an explosion-proof energy-absorbing sandwich material prepared by the preparation method of the explosion-proof energy-absorbing sandwich material. Background technique [0002] Explosion-proof energy-absorbing materials are usually composed of porous energy-absorbing materials coated with explosion-proof coatings. In the 1980s, the American LINE-X company first invented the explosion-proof elastic coating, and its material was sprayed polyurea elastomer. After the 9 / 11 incident in 2001, the bulletproof vests and helmets of the U.S. military stationed in Afghanistan and the Hummer vehicles of the Marine Corps were sprayed with LINE-X explosion-proof polyurea coating, which effectively improved the impact of the explosion. Porous energy-absorbing material is a kind of fo...

Claims

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Application Information

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IPC IPC(8): C08J9/36C08J9/08C08L79/08C08K3/34C08G73/10C09D175/02C08G18/75C08G18/48C08G18/66C08G18/32C08G18/50C08G18/10
CPCC08G18/10C08G18/4854C08G18/755C08G18/758C08G73/1035C08J9/08C08J9/365C08J2379/08C08K3/346C09D175/02C08G18/5024C08G18/3237C08G18/3228C08G18/5027
Inventor 王宝柱李永岗王伟温喜梅苏坤赵成文
Owner QINGDAO AIR NEW MATERIALS